CAS 60-10-6 MFCD00003025-Dithizone 双硫腙 TAO{mole}

Dithizone 双硫腙

CAS 60-10-6 MFCD00003025

化学结构图

SMILES: S=C(/N=N/c1ccccc1)NNc1ccccc1

化学属性

Mol. Formula	C13H12N4S
Mol. Weight	256.33
Melting Point	168
TSCA	Yes
Stability	对光敏感
Solubility	Soluble in ethanol (30 mg/ml), chloroform, DMSO, and pyridine (10 mg/ml). Insoluble in water

别名和识别编码

Chemical Name	Dithizone
Synonym	(phenylazo)thio-formicaci2-phenylhydrazide DIPHENYLTHIOCARBAZONE DITHIZONE DITHIZONE STANDARD SOLUTION DITHIZONE, Diazenecarbothioicacid,phenyl-,2-phenylhydraz Diphenylthiocarbazone Dithizone, for analysis (1,5-diphenylthiocarbazone) Reag. {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {Chemicalbook} dithizon {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {hazard_com} USAF EK-3092 二苯基硫卡巴腙二苯基硫卡巴腙; 双硫腙; 苯肼硫代羰偶氮苯; 打萨宗; 二苯磺卡贝松; 苯肼硫碳酰偶氮苯; 二苯基硫代卡巴腙; 二苯基硫巴腙; 二苯硫代偶氮碳酰肼; 二苯硫代缩(对称)二氨基脲二苯基硫醯二胺二苯硫代偶氮碳酰肼二苯硫卡巴腙双硫腙双硫腙,苯肼硫代羰偶氮苯,打萨宗,二苯磺卡贝松,苯肼硫碳酰偶氮苯,二苯基硫代卡巴腙,二苯基硫巴腙,二苯硫代偶氮碳酰肼,二苯硫代缩(对称)二氨基脲打萨宗打萨腙
MDL Number	MFCD00003025
CAS Number	60-10-6
PubChem Substance ID	87567540
EC Number	200-454-1
Beilstein Registry Number	16,26
Merck Number	3377
Reaxys-RN	1119574
Chemical Name Translation	双硫腙
Wiswesser Line Notation	RNUNYUS&MMR
InChIKey	UOFGSWVZMUXXIY-BMRADRMJSA-N
InChI	InChI=1S/C13H12N4S/c18-13(16-14-11-7-3-1-4-8-11)17-15-12-9-5-2-6-10-12/h1-10,14H,(H,16,18)
Canonical SMILES	S=C(/N=N/C1=CC=CC=C1)NNC2=CC=CC=C2

信息真实价格透明资金保障专业采购外包团队在线服务

品牌质保精细包装现货库存一流品牌服务

产品应用

A titrant in the quantitative determination of heavy metals

安全信息

GHS Symbol

WGK Germany3

Hazard statements

H315 Causes skin irritation 会刺激皮肤
H319 Causes serious eye irritation 严重刺激眼睛
H335 May cause respiratory irritation 可能导致呼吸道刺激

Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves

RTECSLQ9450000

Precautionary statements

P302+P352+P332+P313+P362+P364
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P501 Dispose of contents/container to..… 处理内容物/容器.....
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P305+P351+P338
P332+P313
P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P405 Store locked up. 上锁保管。
P305+P351+P338+P337+P313
P308+P311
P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。

Signal word

Safety Statements

S36 Wear suitable protective clothing 穿戴适当的防护服；
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S37 Wear suitable gloves 戴适当手套；
S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；

Risk Statements

R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

Hazard Codes Xi

Storage condition 2-8°C, stored under nitrogen 密封避光保存。

Packing GroupIII

Hazard Class6.1

UN Number 2811

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 56 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#07955

TYPE OF TEST            : LD - Lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : >500 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NCNSA6 National Academy of Sciences, National Research Council,
   Chemical-Biological Coordination Center, Review.  (Washington, DC)
   Volume(issue)/page/year: 5,44,1953

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 200 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: AD277-689

其他信息

TCI Shanghai:二苯基硫卡巴腙 Dithizone,>;85.0%(E)(60-10-6)
外观性质:蓝黑色结晶粉末。
方法一:按下述步骤制备。1.苯肼二硫代甲酸苯肼盐的制备。将13g苯肼溶于60ml乙醚中，滴加5.2ml二硫化碳。将生成的白色沉淀滤出，用乙醚洗涤，得约15g。2.二苯二氨基硫脲的制备。将上述生成物置于烧杯中，在96-98℃的水浴上加热，物料熔融后放出硫化氢而转为淡黄以的胶状物。若有氨气放出，则移出热浴，用水冷却。再用冰冷却。再用冰冷却，加入15ml水无水乙醇，自冰浴中取出，搅拌下稍热，这时胶状物变成结晶状产物，抽滤，用乙醇洗涤，得约7.5g。3.双硫腙的制备。将上述所得二苯二氨基硫脲加到苛性钾溶液（6g氢氧化钾溶于60ml无水甲醇）中，在沸水浴上回流5min，取出在冰浴中冷却。过滤，滤液用硫酸酸化至刚果红试纸变色，析出深蓝色沉淀。抽滤，将沉淀物再用苛性钾溶液、硫酸处理一遍，抽滤后用水洗至无硫酸根存在。在40℃烘干，得双硫腙约3g。
MOL 文件:60-10-6.mol
双硫腙价格(试剂级):更新日期产品编号产品名称包装价格 2014/06/02 D0949 双硫腙 Dithizone 25G 571元 2010/05/25 A17947 硫代卡巴腙, 98% Dithizone, 98% 5g 220元 2010/05/25 A17947 硫代卡巴腙, 98% Dithizone, 98% 50g 1526元
Sigma Aldrich:60-10-6(sigmaaldrich)
Alfa Aesar:硫代卡巴腙,ACS,85+% Dithizone, ACS, 85+%(60-10-6)
用途二:铅的灵敏试剂，并可用于某些微量重金属如钴、汞、铜、铅、锌、镉和银等的测定。络合指示剂。
MSDS 信息:双硫腙(60-10-6).msds
下游产品:硫酸博莱霉素
上游原料:甲醇 --> 氢氧化钾 --> 4-氯苯甲醛 --> 氢硫酸 --> 刚果红试纸 --> 二苯 --> 硫代卡巴肼
Dithizone can be used as a titrant in the quantitative determination of heavy metals.
易被空气氧化，可加入二氧化硫水溶液保护。易溶于四氯化碳和氯仿，其溶液不稳定，稍溶于醇，不溶于水，溶于有机溶剂呈绿色溶液。与金属盐的水溶液混合振摇，在水相中形成金属络盐，转入有机溶剂层，发生显著的颜色变化。可用一层二氧化硫保护。半数致死量(小鼠，腹腔)200mg/kg。有刺激性。
用途一:该品是测定微量沿的络合指示剂，并用于测定钴、铜、汞、锌和银等。