2-Bromoiodobenzene 邻碘溴苯

CAS 583-55-1 MFCD00001030

化学结构图

583-55-1
SMILES: Brc1ccccc1I

化学属性

Mol. FormulaC6H4BrI
Mol. Weight283
Boiling Point120-121
Melting Point9-10
TSCAT
Density2.203
Refractive index1.6600 to 1.6650
Flash Point>110°(230°F)
Stability对光敏感

别名和识别编码

Chemical Name2-Bromoiodobenzene
CAS Number583-55-1
Alfabeta NameBROMOIODOBENZENE 12---
MDL NumberMFCD00001030
Synonym -Bromo-2-iodobenzene 1-Brom-2-iodobenzene 1-Bromo-2-iodobenzene, 98+% 1-Bromo-2-iodobenzene, stabilized, 99% 1-bromo-2-iodo-benzen 1-溴-2-碘苯 1-碘-2-溴苯 2-Bromjodbenzol 2-Bromoiodobenzene o-Bromoiodobenzene o-Bromophenyl iodide o-Iodbrombenzol benzene, 1-bromo-2-iodo- 邻溴碘苯 邻碘溴苯 邻碘溴苯; 2-溴碘苯; 1-溴-2-碘苯
EC Number209-508-9
Beilstein Registry Number1855309
PubChem Substance ID11415
Reaxys-RN1855309
Chemical Name Translation邻碘溴苯
InChIKeyOIRHKGBNGGSCGS-UHFFFAOYSA-N
LabNetwork Molecule IDLN00007687
InChIInChI=1S/C6H4BrI/c7-5-3-1-2-4-6(5)8/h1-4H
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分类

  • {SNA} Aryl, Building Blocks, C6, Chemical Synthesis, Halogenated Hydrocarbons, Organic Building Blocks
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment

相关文献及参考

  • Regioselective Suzuki coupling with arylboronic acids has been achieved giving 2-bromobiphenyl derivatives: Synlett, 207 (1992).
  • Benzyne precursor. In the presence of excess of a Grignard reagent, the initially formed benzyne undergoes nucleophilic addition to give an ortho-substituted phenylmagnesium halide: Synth. Commun., 18, 1749 (1988).
  • Short: EINECS
  • Beilstein:5,223
  • Short: IV/1a
  • Short: IV/8A
  • Short: III/38B

安全信息

Warnings IRRITANT, LIGHT SENSITIVE
Signal word Warning
GHS Symbol
WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S37 Wear suitable gloves 戴适当手套;
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P350
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P332+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Storage condition 对光敏感,避光保存 Light Sensitive
Hazard Codes Xi

其他信息

  • Alfa Aesar:1-溴-2-碘苯,98+% 1-Bromo-2-iodobenzene, 98+%, stab. with copper(583-55-1)
  • 用途一:用于有机合成
  • Sigma Aldrich:583-55-1(sigmaaldrich)
  • 邻碘溴苯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 xw010306 邻溴碘苯 25g 245元 2011/04/16 B1126 1-溴-2-碘苯(含稳定剂铜屑) 1-Bromo-2-iodobenzene (stabilized with Copper chip) 250G 9050元 2011/04/16 B1126 1-溴-2-碘苯(含稳定剂铜屑) 1-Bromo-2-iodobenzene (stabilized with Copper chip) 25G 1480元
  • TSCA:T
  • MOL 文件:583-55-1.mol
  • Hazard Note:Irritant/Light Sensitive
  • TCI Shanghai:1-溴-2-碘苯(含稳定剂铜屑) 1-Bromo-2-iodobenzene (stabilized with Copper chip),>;98.0%(GC)(583-55-1)
  • MSDS 信息:1-Bromo-2-iodobenzene(583-55-1).msds
  • 敏感性:Light Sensitive
  • Acros Organics:1-溴-2-碘苯 1-Bromo-2-iodobenzene, stabilized, 99%(583-55-1)
  • 图谱信息:邻碘溴苯(583-55-1)质谱(MS) 邻碘溴苯(583-55-1)核磁图( 1 HNMR) 邻碘溴苯(583-55-1)核磁图( 13 CNMR) 邻碘溴苯(583-55-1)红外图谱(IR1)

系列性分类


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