CAS 122-39-4 MFCD00003014-Diphenylamine 二苯胺 TAO{mole}

Diphenylamine 二苯胺

CAS 122-39-4 MFCD00003014

化学结构图

SMILES: c1ccc(NC2CCCCC2)cc1

化学属性

Mol. Formula	C12H11N
Mol. Weight	169
Density	1.16
Autoignition Point	1175 °F
Vapor Density	5.82 (vs air)
Boiling Point	302
Vapor Pressure	1 mmHg ( 108 °C)
Melting Point	50-53
Flash Point	152°(305°F)
Solubility	Soluble in benzene, ether, glacial acetic acid, CS2
TSCA	Yes
Stability	对光敏感;对空气敏感
Appearance	crystalline

别名和识别编码

Chemical Name	Diphenylamine
Synonym	DFA diphenylamine N,N-Diphenylamine Aniline, N-phenyl- Naugalube 428L Difenylamin 二苯基胺 DPA Diphenylamine redox NO SCALD 二苯胺 N-Phenylbenzeneamine bigdipper Diphenylamine N-PhenylanilineN-Phenylbenzenamine CORAZA ANILINOBENZENE LABOTEST-BB LTBB000505 N-Phenylaminobenzol N-phenylbenzenamine 苯胺苯 N-PHENYLANILINE Big Dipper 2-Biphenylyl-N-pyridylacetamide No-Scald Poly(diphenylamine) diphenyl-amine N-Phenylaniline diphenylamine redox DIPHENYLAMINE C.I. 10355 N-Fenylanilin Scaldip Benzenamine,N-phenyl- N-PHENYLBENZENENAMINE Benzene, anilino- 二苯胺 DIPHENYLAMINE N-PHENYLBENZENEAMINE DBA N-phenylaniline N,N-二苯胺 Acetamide, 2-biphenylyl-N-pyridyl- Anilinobenzene anilino-benzen 氨基二苯,N-苯基苯胺 N-苯基苯胺 Diphenpyramide 二苯胺, ACS Shield DPA (phenylamino)-benzen No scald Z-876 二苯胺, 98+% Benzenamine, N-phenyl- benzenamine, N-phenyl- 氨基二苯 Benzene, (phenylamino)- No-Scald DPA 283 Pyridyl-biphenylyl-acetamide DIPHENYLAMINE INDICATOR Deccoscald 282 N-Phenylbenzenamine
MDL Number	MFCD00003014
CAS Number	122-39-4
EC Number	204-539-4
Beilstein Registry Number	508755
Merck Number	3317
PubChem Substance ID	11487
Chemical Name Translation	二苯胺
Reaxys-RN	508755
Wiswesser Line Notation	RMR
LabNetwork Molecule ID	LN00196818
InChI	InChI=1S/C12H11N/c1-3-7-11(8-4-1)13-12-9-5-2-6-10-12/h1-10,13H

信息真实价格透明资金保障专业采购外包团队在线服务

品牌质保精细包装现货库存一流品牌服务

分类

{SNA} 76/768/EEC Annex VIII, All alphabetically sorted, Alphabetical Index of Analytical Standards, Analytical Standards, Analytical/Chromatography, Bioactive Small Molecules, Bridged diphenyls, Cell Biology, Chromatography, Cosmetics,
{SNA} 2009/48/
{SNA} 2009/48/EC (Directive on the Safety of Toys), 76/768/EEC Annex VIII, Alphabetical Index of Analytical Standards, Analytical Standards, Analytical/Chromatography, Bridged diphenyls, Chromatography, D, DIO - DIZ, Environmental Standards, European Community: ISO, DIN and DL 152, Food & Beverage Standards, Fungicides, Method and Regulation Specific,

产品应用

硝酸盐、氯酸盐和其他氧化性物质的检定。铱的催化测定。硝酸盐的光度测定。氧化还原指示剂。单倍体育种培养基。制造染料。是硝化纤维素、炸药、火棉的稳定剂。

安全信息

Signal word Danger

GHS Symbol

WGK Germany3

Safety Statements

S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；

Risk Statements

R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
R33 Danger of cumulative effects 有累积作用的危险
R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
R50/53

Precautionary statements

P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P273 Avoid release to the environment. 避免释放到环境中。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P301+P310
P301+P312+P330
P302+P350
P302+P352+P333+P313+P362+P364
P304+P340+P312
P305+P351+P338+
P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
P337+P313
P501 Dispose of contents/container to..… 处理内容物/容器.....

Hazard statements

H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
H331 Toxic if inhaled 吸入中毒
H311 Toxic in contact with skin 皮肤接触中毒
H301 Toxic if swallowed 吞食有毒
H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
H302 Harmful if swallowed 吞食有害

Personal Protective Equipment Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges

RTECSJJ7800000

Packing GroupIII

UN Number 3077 UN3077

Storage condition Air & Light Sensitive 0-6°C 密封避光保存。

Hazard Codes 9 T,N T,N,F

Hazard Class9

Warnings 危化品目录(2015)

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Mammal - species unspecified
DOSE/DURATION           : 3200 mg/kg
TOXIC EFFECTS :
   Lungs, Thorax, or Respiration - cyanosis
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 40(10),114,1975

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1750 mg/kg
TOXIC EFFECTS :
   Lungs, Thorax, or Respiration - cyanosis
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 41(5),21,1976

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - guinea pig
DOSE/DURATION           : 300 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   FMCHA2 Farm Chemicals Handbook.  (Meister Pub., 37841 Euclid Ave.,
   Willoughy, OH 44094)  Volume(issue)/page/year: -,C112,1991

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 2 gm/kg
TOXIC EFFECTS :
   Lungs, Thorax, or Respiration - cyanosis
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 41(5),21,1976

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 7500 mg/kg
SEX/DURATION            : female 17-22 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Specific Developmental Abnormalities - urogenital system
REFERENCE :
   PEREBL Pediatric Research.  (Williams & Wilkins Co., 428 E. Preston St.,
   Baltimore, MD 21202) V.1-    1967-  Volume(issue)/page/year: 4,448,1970

Restrict 危险品

其他信息

上游原料:乙醇 --> 氨基苯
可燃性危险特性:燃烧产生有毒氮氧化物气体
毒性分级:中毒
Alfa Aesar:二苯胺,ACS Diphenylamine, ACS(122-39-4)
用途一:主要用于制造橡胶防老剂、火药安定剂，也用作染料和农药的中间体
MOL 文
急性毒性:口服- 大鼠 LD50: 1120 毫克/ 公斤; 口服- 小鼠 LD50: 1230 毫克/ 公斤
灭火剂:干粉、泡沫、砂土
方法一:可由苯胺和苯胺盐酸盐在210-240℃、0.62MPa压力下缩合而得。如果使用催化剂，则不需苯胺盐酸盐，苯胺本身即可缩合得到二苯胺。
二苯胺价格(试剂级):更新日期产品编号产品名称包装价格 2011/08/23 30074416 二苯胺;氨基二苯 100g 8.9元 2011/04/16 D0872 二苯胺 Diphenylamine 500G 380元 2011/04/16 D0872 二苯胺 Diphenylamine 25G 70
color:tan
用途四:硝酸盐、氯酸盐和其他氧化性物质的检定。铱的催化测定。硝酸盐的光度测定。氧化还原指示剂。单倍体育种培养基。制造染料。是硝化纤维素、炸药、火棉的稳定剂
检测方法:GC
蒸气压:1 mm Hg ( 108 °C)
敏感性:Air & Light Sensitive
职业标准:TLV-TWA 10 毫克/ 立方米; STEL 20 毫克/立方米
TCI Shanghai:二苯胺(1mg/ml的乙酸乙酯溶液)[异味物质分析用内部标准品](1ml*5) Diphenylamine (1mg/ml in Ethyl Acetate) [Internal standard for Offensive Odors Analysis] (1ml*5)(122-39-4)
储运特性:库房通风低温干燥; 与食品原料分开储运
下游产品:beta-氨基丙酸 --> A,A二苯基Β苦基肼基游离基 --> 光敏聚酰亚胺光刻胶 --> N,N'-二苯基-N,N'-(1-萘基)-1,1'-联苯-4,4'-二胺 --> 硫化深蓝3R --> 甲位戊基桂醛 --> 锂基润滑脂 --> 9-甲基吖啶 --> N,N'-二苯基-N,N'-二(3-甲基苯基)-1,1'-联苯-4,4'-二胺 --> 吩噻嗪 --> 二硫化钼锂基润滑脂 --> 3-氨基丙腈 --> 2-氨基-5-硝基二苯甲酮 --> 硫化蓝7 --> 碱性蓝 11 --> N,N,N',N'-四苯基联苯胺 --> N,N'-二苯基联苯二胺 --> 7-氯-1,3-二氢-5-苯基-2H-1,4-苯并二氮杂-2-硫酮 --> 直接混纺蓝D-3GL --> 二苯胺-4-重氮盐 --> 去甲西泮 --> 酸性棕354 --> 直接黑168 --> 坦帕明 --> 4-亚硝基二苯基胺 --> C.I.酸性绿16 --> 二苯胺-4-磺酸钠盐 --> 防老剂DFC-34 --> N-亚硝基二苯胺 --> 丫啶黄 --> 酸性黄199 --> 直接混纺藏青D-R --> 直接元灰AB --> 4,4'-二(苯基异丙基)二苯胺
{Chemicalbook
类别:农药
MSDS 信息:二苯胺(122-39-4).msds
用途三:二苯胺的主要用途是在橡胶化学品领域，用于抗氧剂、抑制剂、促进剂的生产；作为染料中间体，可生产酸性黄G、酸性橙N、酸性墨水蓝A，分散蓝5R等产品；也是塑料稳定剂、兽药硫化二苯胺、吩噻嗪的中间体。二苯胺还用作硝化棉及无烟炸药的稳定剂、分析试剂、氧化还原指示剂和液体干燥剂。
图谱信息:二苯胺(122-39-4)质谱(MS)
Acros Organics:二苯胺 Diphenylamine, Redox-indicator, extra pure, 99+%(122-39-4)