2-Chloro-2-methylpropane 氯代叔丁烷

CAS 507-20-0 MFCD00000816

化学结构图

507-20-0
SMILES: CC(C)(C)Cl

化学属性

Mol. FormulaC4H9Cl
Mol. Weight92.57
Refractive index1.3850 to 1.3870
Boiling Point51-52
Density0.851
Melting Point-25
Flash Point-18°C(lit.)
TSCAYes
Vapor Density3.2 (vs air)
Vapor Pressure4.82 psi ( 20 °C)
Solubility略溶于水
Stability对光敏感

别名和识别编码

Chemical Name2-Chloro-2-methylpropane
Synonym (CH3)3C-Cl (tertiary butyl chloride) 1,1-dimethylethyl chloride 1-Chloro-1,1-dimethylethane 2-Chloro-Tertbutane 2-Chloroisobutane 2-Methyl-2-propyl chloride 2-chloroisobutane 2-methyl-2-chloropropane 2-methyl-2-propyl chloride 2-methyl-2-propylchloride 2-氯异丁烷 tert-Butylchlorid tert-Butylchloride AKOS BBS-00004388 Chlorotrimethylmethane propane, 2-chloro-2-methyl- t-Butyl chloride t-Butylchloride tert-Butyl chloride tert-Butylchlorid tert-C4H9C tert.-Butylchlorid {} {} {Chemica 三甲基氯甲烷 叔丁基氯 氯代叔丁烷
CAS Number507-20-0
PubChem Substance ID10486
EC Number208-066-4
Beilstein Registry Number1730872
MDL NumberMFCD00000816
Reaxys-RN1730872
Merck Number1562
Chemical Name Translation氯代叔丁烷
Wiswesser Line NotationGX1&1&1
LabNetwork Molecule IDLN00194443
InChIInChI=1S/C4H9Cl/c1-4(2,3)5/h1-3H3
信息真实价格透明    资金保障    专业采购外包团队在线服务   
信息真实价格透明    资金保障    专业采购外包团队在线服务   
品牌质保精细包装    现货库存    一流品牌服务   

分类

  • Analytical Reagents, Analytical Reagents for General Use, Analytical/Chromatography, C-D, Puriss p.a., Puriss p.a.
  • {SNA} Alkyl, Building Blocks, Chemical Synthesis, Halogenated Hydrocarbons, Organic Building Blocks
  • {SNA} Analytical Reagents for General Use, C-D, Puriss p.a., Puriss p.a., 分析/色谱, 分析试剂
  • {uni_hamburg} no charge; 1fragment

产品应用

  • 溶剂。有机合成。

相关文献及参考

  • Merck: 14,1562 Beilstein:1,125
  • Alkylation of malonate esters with tertiary halides can be accomplished using AlCl3 in nitromethane, avoiding the competing elimination reaction: Liebigs Ann. Chem., 718, 101 (1968). For alkylation of malononitrile, see: Angew. Chem. Int. Ed., 5, 1044 (1966); Org. Synth. Coll., 6, 223 (1988). For high yield alkylation of TMS enol ethers of ketones by reaction with tert-alkyl halides in the presence of various Lewis acid catalysts, see: Angew. Chem. Int. Ed., 17, 48 (1978); Chem. Ber., 113, 3734 (1980).
  • Merck: 14,1562
  • Short: II/14a
  • Short: II/19a

安全信息

GHS Symbol
WGK Germany1
Hazard Codes 3 F
Hazard statements
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US)
RTECSTX5040000
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241+P242+P243
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P303+P361+P353
  • P305+P351+P338
  • P370+P378
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S29 Do not empty into drains 不要排入下水道；
  • S33 Take precautionary measures against static discharges 对静电采取预防措施；
  • S7/9 Keep container tightly closed and in a well-ventilated place 保持容器严格密闭，置于通风良好的场所；
Risk Statements
  • R11 Highly flammable 非常易燃
UN Number 1127 UN 1127 3/PG 2 UN1127
Packing GroupII
Hazard Class3
Storage condition Flammables area 密封阴凉避光保存。
Warnings 危化品目录(2015) 
TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 3000 mg/kg/8W-I
TOXIC EFFECTS :
   Tumorigenic - neoplastic by RTECS criteria
   Lungs, Thorax, or Respiration - tumors
REFERENCE :
   CNREA8 Cancer Research. (Public Ledger Building, Suit 816, 6th & Chestnut
   Sts., Philadelphia, PA 19106)  V.1-    1941-  Volume(issue)/page/year:
   35,1411,1975

Restrict 危险品

其他信息

  • 灭火剂:干粉、二氧化碳、泡沫, 水雾
  • Acros Organics:2-氯-2-甲基丙烷 2-Chloro-2-methylpropane, 99%(507-20-0)
  • 用途二:溶剂，有机合成原料。
  • 氯代叔丁烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 80025126 氯代叔丁烷¤ 100ml 50元 2011/04/16 C0208 2-氯-2-甲基丙烷 2-Chloro-2-methylpropane 25ML 117元 2011/04/16 C0208 2-氯-2-甲基丙烷 2-Chloro-2-methylpropane 500ML 560元
  • 海关编码:29031980
  • 类别:易燃液体
  • 与水共沸时水解产生叔丁醇。能与乙醇和乙醚混溶，微溶于水。易燃。
  • 蒸气压:4.82 psi ( 20 °C)
  • 图谱信息:氯代叔丁烷(507-20-0)质谱(MS) 氯代叔丁烷(507-20-0)红外图谱(IR2) 氯代叔丁烷(507-20-0)核磁图( 13 CNMR) 氯代叔丁烷(507-20-0)红外图谱(IR1) 氯代叔丁烷(507-20-0)核磁图( 1 HNMR)
  • MOL 文件:507-20-0.mol
  • 可燃性危险特性:遇明火、高温、氧化剂易燃; 燃烧产生有毒氯化物烟雾;遇热产生有毒光气
  • 用途一:可用于合成香料二甲苯麝香，也可用于合成农药及其他精细化工产品
  • Sigma Aldrich:507-20-0(sigmaaldrich)
  • 常规方法:以250ml玻璃瓶包装，外用木箱或纸箱保护。应注明“易燃物品”字样，危规编号61050。贮存于阴凉、干燥、通风的库房中。最高库温不得超过30℃。不得与氧化物共放一处。包装要坚固、密封。
  • MSDS 信息:叔丁基氯(507-20-0).msds
  • 方法一:由叔丁醇与盐酸反应而得。将叔丁醇于30℃在搅拌下加入盐酸中反应1h，静置分层，取油层进行碱洗、水洗、干燥得粗品，再经精馏，收集50-54.5℃馏分得成品。
  • TCI Shanghai:2-氯-2-甲基丙烷 2-Chloro-2-methylpropane,>;98.0%(GC)(507-20-0)
  • Alfa Aesar:氯叔丁烷,98+% tert-Butyl chloride, 98+%(507-20-0)
  • 储运特性:库房通风低温干燥; 与氧化剂、酸类分开存放
  • 外观性质:无色透明液体。
  • 蒸气密度:3.2 (vs air)
  • 下游产品:三甲基乙酰氯 --> 叔丁胺 --> 哒螨灵 --> (R)-(+)-叔丁基亚磺酰胺 --> 叔丁基苯 --> 二氯[1,1'-双(耳叔丁基膦)二茂铁钯(II) ]PALLADIUM(II) --> 三甲基乙酸 --> 2-二-叔丁膦基-2',4',6'-三异丙基联苯 --> 1,1'-双(二叔丁基膦)二茂铁 --> (R)-(-)-1-[(S)-2-二苯基磷二茂铁乙基-二叔丁基磷 --> 二叔丁基氯化膦 --> 三叔丁基膦 --> 亚硝酸特丁酯 --> 盐酸特比萘芬 --> 四氟硼酸三叔丁基膦 --> 苄氯三唑醇 --> 二(三叔丁基膦)钯 --> 二甲苯麝香 --> 4-叔-丁基苄胺 --> 氯醚菊酯 --> 叔丁基氯化镁 --> 2,4,6-三叔丁基苯酚 --> 2,7-二叔丁基萘 --> 1-氯-4-苯基丁烷 --> 2,6-二叔丁基萘 --> 1,1-二氯-3,3-二甲基丁烷
  • 上游原料:盐酸 --> 叔丁醇

系列性分类

  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Analytical Reagents for General Use - Analytical Reagents
  4. Puriss p.a. - Analytical Reagents for General Use
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  5. Alkyl 烷基卤代烃
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Analytical Reagents for General Use - Analytical Reagents
  4. Puriss p.a. - Analytical Reagents for General Use
  5. C-D, Puriss p.a. - Puriss p.a.
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Chromatography - Analytical Standards
  4. Environmental Standards - Chromatography
  5. Volatiles/ Semivolatiles - Environmental Standards
  6. Alpha Sort - Volatiles/ Semivolatiles
  7. C - Alpha Sort
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  5. Alkenyl
  1. Analytical & Chromatography 分析化学与色谱
  2. Adsorbents, Filter Aids and Drying Agents
  3. Other Drying Agents