Bromoacetaldehyde dimethyl acetal 2-溴-1,1-二甲氧基乙烷

CAS 7252-83-7 MFCD00000213

化学结构图

7252-83-7
SMILES: COC(CBr)OC

化学属性

Mol. FormulaC4H9BrO2
Mol. Weight169.02
Density1.43
Refractive index1.4440 to 1.4470
Boiling Point148-150°C at 760 mmHg
Flash Point51°C
TSCAYes
Solubility不溶
Stability对光敏感

别名和识别编码

Chemical NameBromoacetaldehyde dimethyl acetal
CAS Number7252-83-7
Alfabeta NameBROMODIMETHOXYETHANE 211---,
MDL NumberMFCD00000213
Synonym Bromoacetoaldehyde dimethyl acetal {LY} Bromoacetoaldehyde dimethyl acetal {} {LY} Bromoacetoaldehyde dimethyl acetal {} {} {LY} Bromoacetoaldehyde dimethyl acetal {} {} {} {LY} Bromoacetoaldehyde dimethyl acetal {} {} {} {} {LY} Bromoacetoaldehyde dimethyl acetal {} {} {} {} {} {LY} Bromoacetoaldehyde dimethyl acetal {} {} {} {} {} {} {LY} Bromoacetoaldehyde dimethyl acetal {} {} {} {} {} {} {} {LY} Bromoacetoaldehyde dimethyl acetal {} {} {} {} {} {} {} {} {LY} Bromoacetoaldehyde dimethyl acetal {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {LY} Bromoacetoaldehyde dimethyl acetal {} {} {} {} {} {} {} {} {} {} {LY} Bromoacetoaldehyde dimethyl acetal {} {} {} {} {} {} {} {} {} {} {} {LY} Bromoacetoaldehyde dimethyl acetal {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bromoacetoaldehyde dimethyl acetal {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bromoacetoaldehyde dimethyl acetal {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {}
EC Number230-669-6
Beilstein Registry Number1280132
PubChem Substance ID81672
Chemical Name Translation2-溴-1,1-二甲氧基乙烷
Reaxys-RN1280132
InChIKeyFUSFWUFSEJXMRQ-UHFFFAOYSA-N
LabNetwork Molecule IDLN00174528
InChIInChI=1S/C4H9BrO2/c1-6-4(3-5)7-2/h4H,3H2,1-2H3
Canonical SMILESCOC(OC)CBr
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分类

  • {SNA} Acetals/Ketals/Ortho Esters, Building Blocks, Chemical Synthesis, Organic Building Blocks, Oxygen Compounds
  • {uni_hamburg} no charge; 1fragment

相关文献及参考

  • Short: EINECS
  • Beilstein:1,624
  • Short: III/38B

安全信息

Warnings IRRITANT
Signal word
GHS Symbol
WGK Germany3
Safety Statements
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后,立即用大量…(由生产厂家指定)冲洗;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S36/39 Wear suitable protective clothing and eye/face protection 穿戴适当的防护服和眼睛/面保护;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R10 Flammable 易燃
  • R36 Irritating to eyes 刺激眼睛
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P303+P361+P353
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P337+P313
  • P332+P313
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H319 Causes serious eye irritation 严重刺激眼睛
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Packing GroupIII
UN Number UN2929 1993
Storage condition 2-8°C {LY} 2-8°C Moisture Sensitive Refrigerator (+4°C) + Flammables area {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
Hazard Codes Xi
Hazard Class3

其他信息

  • 图谱信息:2-溴-1,1-二甲氧基乙烷(7252-83-7)质谱(MS) 2-溴-1,1-二甲氧基乙烷(7252-83-7)核磁图( 13 CNMR) 2-溴-1,1-二甲氧基乙烷(7252-83-7)核磁图( 1 HNMR) 2-溴-1,1-二甲氧基乙烷(7252-83-7)红外图谱(IR1)
  • 检测方法:GC
  • 下游产品:1-苯并噻吩-5-羧酸 --> 苯并呋喃-5-硼酸 --> 2-(1-苯并噻吩-5-基)-4,4,5,5-四甲基-1,3,2-二氧硼烷 --> (5-溴-3-苯并[B]噻吩)甲醇 --> (5-氯-1-苯并噻吩-3-基)甲醇 --> 5-溴苯并[B]噻吩-3-甲酸 --> 5-氯苯并[B]噻吩-3-羧酸 --> 1-苯并噻吩-5-羰酰氯 --> 1-(5-溴-1-苯并噻吩-3-基)乙酮 --> 3-乙酰硫茚 --> 5-氯苯并噻吩
  • Alfa Aesar:溴乙醛二甲基乙缩醛,97+%,碳酸钾做稳定剂 Bromoacetaldehyde dimethyl acetal, 97+%, stab. with potassium carbonate(7252-83-7)
  • 不溶于水。
  • F:8-9-21
  • 海关编码:29110000
  • 2-溴-1,1-二甲氧基乙烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B1097 溴乙醛缩二甲醇(含稳定剂碳酸钾) Bromoacetaldehyde Dimethyl Acetal (stabilized with K2CO3) 500G 2160元 2014/06/02 B1097 溴乙醛缩二甲醇(含稳定剂碳酸钾) Bromoacetaldehyde Dimethyl Acetal (stabilized with K2CO3) 25G 295元 2010/06/21 221870250 2-溴-1,1-二甲氧基乙烷 Bromoacetaldehyde dimethyl acetal 97%, stabilized 25 ML 412元
  • MOL 文件:7252-83-7.mol
  • TCI Shanghai:溴乙醛缩二甲醇(含稳定剂碳酸钾) Bromoacetaldehyde Dimethyl Acetal (stabilized with K2CO3),>;97.0%(GC)(7252-83-7)
  • 敏感性:Moisture Sensitive
  • MSDS 信息:2-Bromo-1,1-dimethoxyethane(7252-83-7).msds
  • Acros Organics:溴乙醛缩二甲醛 Bromoacetaldehyde dimethyl acetal, stabilized, 97%(7252-83-7)
  • Sigma Aldrich:7252-83-7(sigmaaldrich)

系列性分类


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