CAS 2916-68-9 MFCD00002825-2-(Trimethylsilyl)ethanol 2-三甲基硅基乙醇 TAO{mole}

2-(Trimethylsilyl)ethanol 2-三甲基硅基乙醇

CAS 2916-68-9 MFCD00002825

化学结构图

SMILES: C[Si](C)(C)CCO

化学属性

Mol. Formula	C5H14OSi
Mol. Weight	118.25
Boiling Point	145°C at 760 mmHg
Density	0.825
Refractive index	1.4230 to 1.4250
Flash Point	56°C
TSCA	No
Solubility	可溶

别名和识别编码

Chemical Name	2-(Trimethylsilyl)ethanol
CAS Number	2916-68-9
Alfabeta Name	TRIMETHYLSILYLETHANOL 2-
MDL Number	MFCD00002825
Synonym	(2-Hydroxyethyl)trimethylsilane {LY} (2-Hydroxyethyl)trimethylsilane {} {LY} (2-Hydroxyethyl)trimethylsilane {} {} {LY} (2-Hydroxyethyl)trimethylsilane {} {} {} {LY} (2-Hydroxyethyl)trimethylsilane {} {} {} {} {LY} (2-Hydroxyethyl)trimethylsilane {} {} {} {} {} {LY} (2-Hydroxyethyl)trimethylsilane {} {} {} {} {} {} {LY} (2-Hydroxyethyl)trimethylsilane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (2-Hydroxyethyl)trimethylsilane {} {} {} {} {} {} {} {} {LY} (2-Hydroxyethyl)trimethylsilane {} {} {} {} {} {} {} {} {} {LY} (2-Hydroxyethyl)trimethylsilane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (2-Hydroxyethyl)trimethylsilane {} {} {} {} {} {} {} {} {} {} {} {LY} (2-Hydroxyethyl)trimethylsilane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} (2-Hydroxyethyl)trimethylsilane {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (2-Hydroxyethyl)trimethylsilane {} {} {} {} {} {} {} {} {}
EC Number	220-844-5
Beilstein Registry Number	1732034
PubChem Substance ID	87577204
Reaxys-RN	1732034
Chemical Name Translation	2-三甲基硅基乙醇
InChIKey	ZNGINKJHQQQORD-UHFFFAOYSA-N
Wiswesser Line Notation	Q2-SI-1&1&1
LabNetwork Molecule ID	LN00009690
InChI	InChI=1S/C5H14OSi/c1-7(2,3)5-4-6/h6H,4-5H2,1-3H3
Canonical SMILES	C[Si](CCO)(C)C

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产品应用

经由相关异氰酸酯的醇解，合成Teoc-protected 胺。也是羧基和磷酸根基团的保护试剂。

安全信息

Warnings FLAMMABLE

Signal word Warning

GHS Symbol

WGK Germany3

Safety Statements

S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；

Risk Statements

R10 Flammable 易燃
R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

Precautionary statements

P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
P233 Keep container tightly closed. ?保持容器密闭。
P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
P241+P242+P243
P242 Use only non-sparking tools. 只能使用无火花工具。
P243 Take precautionary measures against static discharge. 采取预防措施，防止静电放电。
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛，皮肤或衣服。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P302+P352
P302+P352+P332+P313+P362+P364
P303+P361+P353
P305+P351+P338
P305+P351+P338+P337+P313
P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
P332+P313
P337+P313
P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
P370+P378
P403+P235
P501 Dispose of contents/container to..… 处理内容物/容器.....

RTECSKM5480000

Packing GroupIII

UN Number 1987 1993

Hazard statements

H226 Flammable liquid and vapour 易燃液体和蒸气
H315 Causes skin irritation 会刺激皮肤
H319 Causes serious eye irritation 严重刺激眼睛

Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

Hazard Codes 3

Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {

Hazard Class3

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1122 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   DANKAS Doklady Akademii Nauk SSSR.  Proceedings of the Academy of Sciences
   of the USSR.  For English translation, see DBIOAM and DKBSAS.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-    1933-
   Volume(issue)/page/year: 229,1011,1976

其他信息

MOL 文件:2916-68-9.mol
溶于水。
Hazard Note:Flammable
2-(三甲硅基)乙醇价格(试剂级):更新日期产品编号产品名称包装价格 2014/06/02 T1441 2-(三甲硅基)乙醇 2-(Trimethylsilyl)ethanol 5ML 559元 2014/06/02 T1441 2-(三甲硅基)乙醇 2-(Trimethylsilyl)ethanol 25ML 1710元 2010/06/21 210480500 2-(三甲硅基)乙醇 2-(Trimethylsilyl)ethanol 99% 50 ML 5354元
Alfa Aesar:2-(三甲基硅基)乙醇,98+% 2-(Trimethylsilyl)ethanol, 98+%(2916-68-9)
图谱信息:2-(三甲硅基)乙醇(2916-68-9)质谱(MS) 2-(三甲硅基)乙醇(2916-68-9)核磁图( 1 HNMR) 2-(三甲硅基)乙醇(2916-68-9)红外图谱(IR1) 2-(三甲硅基)乙醇(2916-68-9)核磁图( 13 CNMR)
MSDS 信息:2-(Trimethylsilyl)ethanol(2916-68-9).msds
TCI Shanghai:2-三甲基硅基乙醇 2-(Trimethylsilyl)ethanol,>;95.0%(GC)(2916-68-9)
TSCA:No
Acros Organics:2-(三甲硅基)乙醇 2-(Trimethylsilyl)ethanol, 99%(2916-68-9)
用途一:经由相关异氰酸酯的醇解，合成Teoc-protected 胺。也是羧基和磷酸根基团的保护试剂。
2-(三甲硅基)乙醇价格(试剂级):更新日期产品编号产品名称包装价格 2011/04/16 T1441 2-(三甲硅基)乙醇 2-(Trimethylsilyl)ethanol 5ML 862元 2011/04/16 T1441 2-(三甲硅基)乙醇 2-(Trimethylsilyl)ethanol 25ML 2630元 2010/06/21 210480500 2-(三甲硅基)乙醇 2-(Trimethylsilyl)ethanol 99% 50 ML 5354元
Sigma Aldrich:2916-68-9(sigmaaldrich)
海关编码:29310095