CAS 64-18-6 MFCD00003297-Formic acid 甲酸 TAO{mole}

Formic acid 甲酸

CAS 64-18-6 MFCD00003297

化学结构图

SMILES: O=[C]O

化学属性

Mol. Formula	CH2O2
Mol. Weight	46
Refractive index	1.3690 to 1.3730
Autoignition Point	1004 °F
Vapor Density	1.6 (vs air)
Boiling Point	100-101
Vapor Pressure	44.8 mmHg ( 20 °C)
Density	1.22
Melting Point	8
Flash Point	57°C(lit.)
TSCA	Yes
Solubility	MISCIBLE
Stability	对湿度敏感
pH	:A

别名和识别编码

Chemical Name	Formic acid
Synonym	Kwas metaniowy Kyselina mravenci Formylic acid 无水甲酸蚁酸 Ameisensaeure 甲酸溶液 Mierenzuur Methanoic acid 甲酸; Acido formico 甲酸 Acide formique 甲酸, 85% Formic acid Aminic acid RCRA waste number U123 甲酸根，用于离子色谱标准液 Hydrogen carboxylic acid
MDL Number	MFCD00003297
CAS Number	64-18-6
PubChem Substance ID	284
EC Number	200-579-1
Beilstein Registry Number	2(4)3
Merck Number	4241
Chemical Name Translation	甲酸
Reaxys-RN	1209246
InChIKey	BDAGIHXWWSANSR-UHFFFAOYSA-N
Wiswesser Line Notation	VHQ
LabNetwork Molecule ID	LN00193468
InChI	InChI=1S/CH2O2/c2-1-3/h1H,(H,2,3)

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产品应用

还原剂，测定砷、铋、铝、铜、金、铟、铁、铅、锰、汞、钼、银和锌等，检定铈，铼和钨，检验芳香族伯胺和仲胺，测定分子量及结晶的溶剂，测定甲氧基，显微分析中用作固定剂，制造甲酸盐类。

安全信息

GHS Symbol

WGK Germany1

Hazard statements

H226 Flammable liquid and vapour 易燃液体和蒸气
H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
H331 Toxic if inhaled 吸入中毒
H302 Harmful if swallowed 吞食有害
H315 Causes skin irritation 会刺激皮肤
H319 Causes serious eye irritation 严重刺激眼睛

Personal Protective Equipment Eyeshields, Gloves Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

RTECSLQ4900000

Precautionary statements

P201 Obtain special instructions before use. 使用前获取专门指示。
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P301+P312+P330
P303+P361+P353
P304+P340+P310
P305+P351+P338
P305+P351+P338+P310
P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
P403+P233
P501 Dispose of contents/container to..… 处理内容物/容器.....

Signal word Danger

Packing GroupII

UN Number 1779 UN1779

Risk Statements

R10 Flammable 易燃
R34 Causes burns 会导致灼伤
R35 Causes severe burns 会导致严重灼伤

Safety Statements

S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；

Storage condition 密封保存充氩保存 Hygroscopic

Hazard Codes 8 C

Hazard Class8/3

Warnings 危化品目录(2015)

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 15 gm/m3/15M
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Lungs, Thorax, or Respiration - dyspnea
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher

TYPE OF TEST            : TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Mammal - dog
DOSE/DURATION           : 3 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   HBTXAC "Handbook of Toxicology," 4 vols., Philadelphia, W.B. Saunders Co.,
   1956-59  Volume(issue)/page/year: 1,146,1955

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 15 gm/m3/15M
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Lungs, Thorax, or Respiration - dyspnea
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 23(12),49,1979

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 239 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   HBTXAC "Handbook of Toxicology," 4 vols., Philadelphia, W.B. Sa

TYPE OF TEST            : Sex chromosome loss and nondisjunction
ROUTE OF E

TYPE OF TEST            : Mutation test systems - not otherwise specified
TEST SYSTEM             : Non-mammalian species Cells - not otherwise specified
DOSE/DURATION           : 100 mmol/L
REFERENCE :
   CAANAT Comptes Rendus de l'Association des Anatomistes.  (Nancy, France)
   V.1-56, 1899-1972.  For publisher information, see ANOBAU.
   Volume(issue)/page/year: 56,712,1972

TYPE OF TEST            : Cytogenetic analysis
TEST SYSTEM             : Rodent - hamster Ovary
DOSE/DURATION           : 10 mmol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 240,195,1990

TYPE OF TEST            : Sex chromosome loss and nondisjunction
ROUTE OF EXPOSURE       : Inhalati

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Escherichia coli
DOSE/DURATION           : 70 ppm/3H
REFERENCE :
   AMNTA4 American Naturalist.  (Univ. of Chicago Press, Journals Div., POB
   37005, Chicago, IL 60637) V.1-    1867-  Volume(issue)/page/year:
   85,119,1951

TYPE OF TEST            : Phage inhibition capacity
TEST SYSTEM             : Bacteria - Escherichia coli
DOSE/DURATION           : 100 mmol/L
REFERENCE :
   MDMIAZ Medycyna Doswiadczalna i Mikrobiologia.  For English translation, see
   EXMMAV.  (Ars Polona, POB 1001, 00-068 Warsaw 1, Poland)  V.1-    1949-
   Volume(issue)/page/year: 31,11,1979

TYPE OF TEST            : Cytogenetic analysis
TEST SYSTEM             : Non-mammalian species Cells - not otherwise specified
DOSE/DURATION           : 100 mmol/L
REFERENCE :
   CAANAT Comptes Rendus de l'Association des Anatomistes.  (Nancy, France)
   V.1-56, 1899-1972.  For publisher information, see ANOBAU.
   Volume(issue)/page/year: 56,712,19

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