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分类

• {uni_hamburg} no charge; ester; 1fragment
• Building Blocks, C2 to C5, Carbonyl Compounds, Chemical Synthesis, Esters, Organic Building Blocks
• {SNA} Building Blocks, C2 to C5, Carbonyl Compounds, Chemical Synthesis, Esters, Organic Building Blocks

产品应用

• Ethyl Nitroacetate is an ester of nitrocarboxylic acid used as an intermediate in the preparation of unsubstituted amino acids.

相关文献及参考

• Similarly, reaction with ɑ-bromo enones gives 5-acyl-3-(ethoxycarbonyl)-2-isoxazoline-2-oxides by a tandem conjugate addition - ring closure: J. Org. Chem., 60, 6624 (1995).
• Conjugate addition to various enones, followed by reductive cyclization with Formamidinesulfinic acid, A11885, provides a convenient new route to pyrroles: Tetrahedron Lett., 36, 9469 (1995). For examples with reaction schemes, see 2-Benzyl­idenecyclohexanone, L13434 and 3-Penten-2-one, L13031.
• Short: III/38B
• Beilstein:2(4)537
• Reacts with 2,3-epoxyaldehydes to give 3-ethoxycarbonyl-4-hydroxy-5-(1-hydroxyalkyl)-2-isoxazoline-2-oxides: J. Org. Chem., 55, 781 (1990):
• In the presence of the Mitsunobu reagent (PPh3/DEAD) oxidizes alcohols to carbonyl compounds: Tetrahedron Lett., 22, 2295 (1981).
• For a review of the use of nitroacetic acid and its esters in organic synthesis, see: Synthesis, 666 (1979).
• Sidorin, G.I.: Gig. Aspe. Okhr. Zdor. Nasel., 144 (1977);

安全信息

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 5250 mg/kg
TOXIC EFFECTS :
   Behavioral - convulsions or effect on seizure threshold
   Lungs, Thorax, or Respiration - acute pulmonary edema
   Nutritional and Gross Metabolic - body temperature decrease
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 24(7),49,1980

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1400 mg/kg
TOXIC EFFECTS :
   Behavioral - convulsions or effect on seizure threshold
   Lungs, Thorax, or Respiration - acute pulmonary edema
   Nutritional and Gross Metabolic - body temperature decrease
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 24(7),49,1980

TYPE OF TEST            : LC - Lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Mammal - species unspecified
DOSE/DURATION           : >728 mg/m3/2H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 24(7),49,1980

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitonea

其他信息

• 下游产品:间氟-DL-酪氨酸 --> 5-硝基-4-羟基嘧啶
• TCI Shanghai:硝基乙酸乙酯 Ethyl Nitroacetate,>;95.0%(GC)(626-35-7)
• 硝基乙酸乙酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 N0657 硝基乙酸乙酯 Ethyl Nitroacetate 5G 540元 2014/06/02 N0657 硝基乙酸乙酯 Ethyl Nitroacetate 25G 1680元 2010/06/21 185170250 硝基乙酸乙酯 Ethyl nitroacetate 98% 25 GR 2592元
• Sigma Aldrich:626-35-7(sigmaaldrich)
• Alfa Aesar:硝基乙酸乙酯,97% Ethyl nitroacetate, 97%(626-35-7)
• TSCA:T
• Acros Organics:硝基乙酸乙酯 Ethyl nitroacetate, 98%(626-35-7)
• Hazard Note:Irritant
• MOL 文件:626-35-7.mol
• MSDS 信息:Ethyl nitroacetate(626-35-7).msds
• 图谱信息:硝基乙酸乙酯(626-35-7)核磁图( 1 HNMR) 硝基乙酸乙酯(626-35-7)核磁图( 13 CNMR) 硝基乙酸乙酯(626-35-7)质谱(MS) 硝基乙酸乙酯(626-35-7)红外图谱(IR1)
• 外观性质:淡黄色透明液体。折光率n20/D：1.424沸点：105-107 °C/25 mmHg密度：1.199闪点：92 °C
• 海关编码:29159080