CAS 101-83-7 MFCD00011658-Dicyclohexylamine 二环己胺 TAO{mole}

Dicyclohexylamine 二环己胺

CAS 101-83-7 MFCD00011658

化学结构图

SMILES: c1ccc(NC2CCCCC2)cc1

化学属性

Mol. Formula	C12H23N
Mol. Weight	181
Refractive index	1.4830 to 1.4850
Boiling Point	117-120
Density	0.912
Melting Point	-2
Flash Point	105°C(lit.)
TSCA	Yes
Vapor Density	6 (vs air)
Vapor Pressure	12 mmHg ( 37.7 °C)
Solubility	微溶于水，可混溶于乙醇、乙醚、苯。

别名和识别编码

Chemical Name	Dicyclohexylamine
CAS Number	101-83-7
PubChem Substance ID	87567113
EC Number	202-980-7
Beilstein Registry Number	605923
MDL Number	MFCD00011658
Reaxys-RN	605923
Merck Number	3095
Synonym	DCH 全氢化二苯基胺 DicylohexylamineForSynthesis 二環己基胺 N,N-Dicyclohexylamine; Perhydrodiphenylamine; DCHA 二环己胺 Aminodicyclohexane 二环己胺(DCHA) N-Cyclohexyl-cyclohexylamine Bis(cyclohexyl)amine 十二氢二苯胺,N-环己基环己胺 DICYCLOHEXYLAMINE DCHA 联环己胺十二氢联苯胺 N-cyclohexyl-Cyclohexanamine Dodecahydrodiphenylamine Perhydrodiphenylamine Dicyklohexylamin 二環己胺 di-cha DODECAHYDRODIPHENYLAMINE dicyclohexyl-amine dicyclohexylamine AURORA KA-7610 N-Cyclohexylcyclohexanamine Dicha DICYCLOHEXYLAMINE, 1000MG,NEAT 十二氢二苯胺 Cyclohexanamine, N-cyclohexyl- N,N-Diclohexylamine n,n-dicyclohexylamine 二环己基胺 N,N-Dicyclohexylamine Cyclohexylcyclohexanamine n-cyclohexyl-cyclohexanamin N-环己基环己胺 dicyklohexylamin(czech)
Chemical Name Translation	二环己胺
Wiswesser Line Notation	L6TJ AM- AL6TJ
LabNetwork Molecule ID	LN00193093
InChI	InChI=1S/C12H23N/c1-3-7-11(8-4-1)13-12-9-5-2-6-10-12/h11-13H,1-10H2

信息真实价格透明资金保障专业采购外包团队在线服务

品牌质保精细包装现货库存一流品牌服务

产品应用

广泛用作有机合成中间体，可用于制取染料中间体、橡胶促进剂、硝化纤维漆、杀虫剂、催化剂、防腐剂、气相缓蚀剂及燃料抗氧化添加剂等。也用作萃取剂。二环己胺的脂肪酸盐和硫酸盐具有肥皂的去污性能，用于印染和纺织工业。其金属络合物用作油墨、油漆的催化剂。

安全信息

GHS Symbol

WGK Germany3

Hazard Codes 8 C,N

Hazard statements

H301+H311
H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
H302+H332
H302 Harmful if swallowed 吞食有害

Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

RTECSHY4025000

Precautionary statements

P201 Obtain special instructions before use. 使用前获取专门指示。
P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
P273 Avoid release to the environment. 避免释放到环境中。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P301+P330+P331+P310
P303+P361+P353
P303+P361+P353+P310+P363
P304+P340+P310
P305+P351+P338
P305+P351+P338+P310
P308+P313
P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
P405 Store locked up. 上锁保管。
P501 Dispose of contents/container to..… 处理内容物/容器.....

Signal word Danger

Safety Statements

S1/2 None 上锁保管并避免儿童触及；
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；

Risk Statements

R22 Harmful if swallowed 吞咽有害
R24/25 Toxic in contact with skin and if swallowed 皮肤接触及吞食都有毒
R34 Causes burns 会导致灼伤
R50/53

UN Number 2565

Storage condition Store at RT. Air Sensitive

Packing GroupIII

Hazard Class8

Warnings 危化品目录(2015)

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 2404 mg/kg/48W-I
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Tumorigenic - tumors at site of application
REFERENCE :
   VOONAW Voprosy Onkologii.  Problems of Oncology.  For English translation,
   see PONCAU. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-10,
   1928-37; V.1-    1955-  Volume(issue)/page/year: 4,659,1958

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 40 gm/kg/52W-I
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Gastrointestinal - tumors
   Liver - tumors
REFERENCE :
   VOONAW Voprosy Onkologii.  Problems of Oncology.  For English translation,
   see PONCAU. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-10,
   1928-37; V.1-    1955-  Volume(issue)/page/year: 4,659,1958

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 500 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J.,
   Prague, Czechoslovakia, Avicenum, 1986  Volume(issue)/page/year: -,468,1986

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 500 mg/kg
TOXIC EFFECTS :
   Behavioral - convulsions or effect on seizure threshold
REFERENCE :
   IECHAD Industrial and Engineering Chemistry.  (Washington, DC)  V.15-62,
   1923-70.  For publisher information, see CHMTBL.  Volume(issue)/page/year:
   29,1247,1937

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 373 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J.,
   Prague, Czechoslovakia, Avicenum, 1986  Volume(issue)/page/year: -,468,1986

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 135 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   VOONAW Voprosy Onkologii.  Problems of Oncology.  For English translation,
   see PONCAU. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-10,
   1928-37; V.1-    1955-  Volume(issue)/page/year: 4,659,1958

TYPE OF TEST            : Cytogenetic analysis
TEST SYSTEM             : Human Leukocyte
DOSE/DURATION           : 200 ug/L
REFERENCE :
   INHEAO Industrial Health.  (National Institute of Industrial Health, 6-21-1
   Nagao, Tama-ku, Kawasaki, 213 Japan)  V.1-    1963- Volume(issue)/page/year:
   9,188,1971

Restrict 危险品

其他信息

蒸气压:12 mm Hg ( 37.7 °C)
F:8-9-23
用途一:用于有机合成，也用作杀虫剂、酸性气体吸收剂和钢铁防锈剂
用途二:用于制造橡胶硫化促进剂、杀虫剂、催化剂、防腐剂等
蒸气密度:6 (vs air)
刺激数据:皮肤- 兔子 2 毫克/ 24小时重度; 眼- 兔子 0.75 毫克/ 24小时重度
TCI Shanghai:二环己胺 Dicyclohexylamine,>;99.0%(GC)(101-83-7)
Alfa Aesar:二环己胺,98% Dicyclohexylamine, 98%(101-83-7)
MSDS 信息:二环己胺(101-83-7).msds
MOL 文件:101-83-7.mol
有刺激性氨味，易燃、高毒。凝固点：-2℃，与有机溶剂混溶，微溶于水。呈强碱性。
Acros Organics:二环己基胺 Dicyclohexylamine, 99+%(101-83-7)
方法一:以苯胺为原料，在催化剂存在下，高温高压加氢，制得二环己胺。
防护措施:本品高毒。具有较强的渗透性臭气，因此，较易被发现。小鼠LD50为2g/kg，大鼠LD50为3.49g/kg。二环己胺可经皮肤吸收，引起皮肤过敏和坏疽，蒸汽可引起恶心和麻醉，但不会引起血液中毒。据报道二环己胺可引起癌症。工作场所空气中最高容许浓度10mg/m3。生产设备应密闭，防止跑、冒、滴、漏。操作现场强制通风，操作人员戴防护用具。
急性毒性:口服- 大鼠 LD50: 373 毫克/ 公斤; 腹腔- 小鼠 LD50: 500 毫克/ 公斤
可燃性危险特性:可燃; 燃烧产生有毒氮氧化物烟雾
十二氢二苯胺价格(试剂级):更新日期产品编号产品名称包装价格 2011/08/23 80048728 二环己胺;十二氢二苯胺 500ml 51元 2011/08/23 30056180 二环己烷 100ml 48.8元 2011/04/16 D0435 二环己胺 Dicyclohexylamine 25ML 117元
类别:腐蚀物品
职业标准:STEL 1 毫克/ 立方米
二环己胺价格(试剂级):更新日期产品编号产品名称包装价格 2011/08/23 80048728 二环己胺;十二氢二苯胺 500ml 51元 2011/08/23 30056180 二环己烷 100ml 48.8元 2011/04/16 D0435 二环己胺 Dicyclohexylamine 25ML 117元
灭火剂:砂土、泡沫、二氧化碳、干粉
常规方法:用铁桶密闭包装，净重150kg。贮存于阴凉、通风、干燥处，隔绝火源，装卸运输应按易燃有毒化学品规定贮运。
储运特性:库房通风低温干燥; 与酸类分开存放。
用途三:广泛用作有机合成中间体，可用于制取染料
图谱信息:十二氢二苯胺(101-83-7)质谱(MS) 十二氢二苯胺(101-83-7)Raman光谱十二氢二苯胺(101-83-7)红外图谱(IR1) 十二氢二苯胺(101-83-7)核磁图( 1 HNMR) 十二氢二苯胺(101-83-7)核磁图( 13 CNMR) 十二氢二苯胺(101-83-7)红外图谱(IR2)
下游产品:二环己基碳二亚胺 --> N,N-二环己基-2-苯并噻唑次磺酰胺 --> 溶剂红30 --> 亚硝酸二环己胺
毒性分级:高毒
爆炸物危险特性:对皮肤和角膜有腐蚀性
上游原料:氨基苯
凝固点:-2℃
Sigma Aldrich:101-83-7(sigmaaldrich)
外观性质:无色液体，有鱼腥臭。