CAS 98-09-9 MFCD00007426-Benzenesulfonyl chloride 苯磺酰氯 TAO{mole}

Benzenesulfonyl chloride 苯磺酰氯

CAS 98-09-9 MFCD00007426

化学结构图

SMILES: O=S(=O)(Cl)C1CCCCC1

化学属性

Mol. Formula	C6H5ClO2S
Mol. Weight	176.92
Density	1.384
Refractive index	1.5510 to 1.5530
Boiling Point	251-252
Vapor Pressure	0.04 mmHg ( 20 °C)
Melting Point	13-15
Flash Point	132°C(lit.)
TSCA	Yes
Solubility	Soluble in alcohol, diethyl ether, ether, and benzene. Insoluble in cold water.
Stability	易吸潮

别名和识别编码

Chemical Name	Benzenesulfonyl chloride
MDL Number	MFCD00007426
CAS Number	98-09-9
Synonym	AKOS BBS-00004356 BENZENE SULFOCHLORIDE BENZENE SULFONE CHLORIDE BENZENESULPHONYL CHLORIDE Benzene sulfonyl chloride Benzenesulfochloride Benzenesulfonic(acid)chloride Benzenesulfonyl Chloride {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
EC Number	202-636-6
Beilstein Registry Number	606926
PubChem Substance ID	87563249
Merck Number	1072
Reaxys-RN	606926
Chemical Name Translation	苯磺酰氯
Wiswesser Line Notation	WSGR
LabNetwork Molecule ID	LN00195183
InChI	InChI=1S/C6H5ClO2S/c7-10(8,9)6-4-2-1-3-5-6/h1-5H

信息真实价格透明资金保障专业采购外包团队在线服务

品牌质保精细包装现货库存一流品牌服务

产品应用

农药；染料；医药的中间体。用于冰染染料色基的制造，如红色基B；红色基GL。用于磺胺药物的制造。苯磺酰氯是检定胶类的试剂。

安全信息

GHS Symbol

WGK Germany1

Hazard statements

H290 May be corrosive to metals 可能腐蚀金属。
H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
H317 May cause an allergic skin reaction 可能导致皮肤过敏
H302+H332
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled 吸入可能导致过敏或哮喘症状或呼吸困难
H332 Harmful if inhaled 吸入有害
H302 Harmful if swallowed 吞食有害

Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

RTECSDB8750000

Precautionary statements

P234 Keep only in original container. 只保留在原来的容器中。
P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P301+P330+P331+P310
P303+P361+P353
P303+P361+P353+P310+P363
P304+P340
P304+P340+P310
P305+P351+P338
P305+P351+P338+P310
P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
P390 Absorb spillage to prevent material damage. 吸收溢出物，防止重大损害。
P405 Store locked up. 上锁保管。
P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
P501 Dispose of contents/container to..… 处理内容物/容器.....

Signal word Danger

Packing GroupIII

UN Number 2225 UN 2225 8/PG 3

Risk Statements

R20/22 Harmful by inhalation and if swallowed 吸入和不慎吞咽有害
R34 Causes burns 会导致灼伤
R42/43

Safety Statements

S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；

Storage condition +4°C Moisture Sensitive 储存温度2-8℃,充氩保存易吸潮，密封保存。

Hazard Codes 8 C

Hazard Class8

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 828 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 36(6),19,1971

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 76 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Lungs, Thorax, or Respiration - respiratory depression
REFERENCE :
   MEPAAX Medycyna Pracy.  Industrial Medicine.  (Ars-Polona, POB 1001, 00-068
   Warsaw 1, Poland) V.1-    1950-  Volume(issue)/page/year: 20,513,1969

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1960 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Lungs, Thorax, or Respiration - respiratory depression
REFERENCE :
   MEPAAX Medycyna Pracy.  Industrial Medicine.  (Ars-Polona, POB 1001, 00-068
   Warsaw 1, Poland) V.1-    1950-  Volume(issue)/page/year: 20,513,1969

TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF E

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 828 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/

Warnings 危险化学品

其他信息

用途一:用于制磺胺药物等，也用于鉴定各种胺
可燃性危险特性:可燃; 遇水分解有毒氯化物气体; 燃烧产生有毒氯化物和硫氧化物烟雾
毒性分级:中毒
灭火剂:砂土、干石粉、二氧化碳
下游产品:4-甲苯磺酰氯 --> 4-硝基-2-甲苯胺 --> 4-甲基-2-硝基苯胺 --> 苯硫酚 --> (三氟甲基)三甲基硅烷 --> 亮丙瑞林 --> 颜料紫 23 --> 苯亚磺酸钠 --> 苯磺酰胺 --> 磺胺喹恶啉 --> 2,5-二氯吡啶 --> 2-(2-氯乙氧基)苯磺酰胺 --> 苯硫代磺酸钠 --> 柳氮磺吡啶 --> 克瘟散 --> N,N-二甲基,对十八烷基苯磺酰胺丙基铵基丙磺酸盐 --> 1-(苯磺酰)-1H-吲哚-2-甲醛 --> 2,4-二氯-5-磺酰胺基苯甲酸 --> 酸性黄79 --> 冰染重氮组分 34 --> 2-甲基-3-硝基苯胺 --> 苯磺酰肼 --> 双苯磺酰亚胺
MSDS 信息:苯磺酰氯(98-09-9).msds
用途三:苯磺酰氯是一种有机合成原料，在农药上用于合成沙蚕毒类杀虫剂杀虫磺的中间体硫代苯磺酸钠，另外也是医药和染料的中间体。
苯磺酰氯价格(试剂级):更新日期产品编号产品名称包装价格 2011/08/23 80015128 苯磺酰氯;氯化苯磺酰;氯磺苯 500ml 34.4元 2011/04/16 B0036 苯磺酰氯 Benzenesulfonyl Chloride 25G 165元 2011/04/16 B0036 苯磺酰氯 Benzenesulfonyl Chloride 500G 355元
对湿敏感。不溶于水，易溶于乙醇，溶于乙醚。有腐蚀性。
Benzenesulfonyl chloride is prepared by reaction of benzene and chlorosulfonic acid or from the sodium salt of benzenesulfonic acid and PCl5 or POCl3. It reacts with Grignard reagent from N-unsubstituted indoles to form oxindoles or substituted indoles. Benzenesulfonyl chloride is the derivatization reagent for the determination of various amines in waste water and surface water at the sub-ppb level by gas chromatography-mass spectrometry.
储运特性:库房通风低温干燥; 与氧化剂、H发孔剂、碱类、氰化物分开存放
Alfa Aesar:苯磺酰氯化物,98% Benzenesulfonyl chloride, 98%(98-09-9)
爆炸物危险特性:在密封瓶中可爆炸;与二甲基亚砜反应爆炸; 与甲基甲酰胺反应激烈
用途二
类别:腐蚀物品
职业标准:STEL 1 毫克/ 立方米
上游原料:苯 --> 氯磺酸
MOL 文件:98-09-9.mol
Sigma Aldrich:98-09-9(sigmaaldrich)
图谱信息:苯磺酰氯(98-09-9)核磁图( 1 HNMR) 苯磺酰氯(98-09-9)红外图谱(IR1) 苯磺酰氯(98-09-9)质谱(MS) 苯磺酰氯(98-09-9)核磁图( 13 CNMR)
蒸气压:0.04 mm Hg ( 20 °C)
F:21
急性毒性:口服- 大鼠 LD50: 1960 毫克/ 公斤; 口服- 小鼠 LD50: 828 毫克/ 公斤
Acros Organics:苯磺酰氯 Benzenesulfonyl chloride, 96%(98-09-9)