CAS 111-50-2 MFCD00000759-Adipoyl Chloride 己二酰氯 TAO{mole}

Adipoyl Chloride 己二酰氯

CAS 111-50-2 MFCD00000759

化学结构图

SMILES: O=C(Cl)CCCCC(=O)Cl

化学属性

Mol. Formula	C6 H8 Cl2 O2
Mol. Weight	183.03
Refractive index	1.4700 to 1.4740
Boiling Point	-
Density	1.259
Flash Point	-
TSCA	Yes
Solubility	可混溶于乙醚、苯。
Stability	对湿度敏感

别名和识别编码

Chemical Name	Adipoyl Chloride
MDL Number	-
CAS Number	111-50-2
Synonym	1,4-Bis(Chlorocarbonyl)butane 1,4-Bis(chlorocarbonyl)butane 1,4-Butanedicarbonyl chloride 1,4-Butanedicarbonyl chloride~Hexanedioyl dichloride 1,4-butanedicarbonyl chloride 1,4-butanedicarbonyl dichloride ADIPOYL CHLORIDE ADIPOYL DICHLORIDE ADIPYL CHLORIDE ADIPYLCHLORIDE,REAGENT Adipic acid dichloride Adipic dichloride Adipinsäuredichlorid Adipoyl Chloride {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
PubChem Substance ID	87561851
EC Number	203-876-4
Beilstein Registry Number	507709
Chemical Name Translation	己二酰氯
Reaxys-RN	507709
InChIKey	PWAXUOGZOSVGBO-UHFFFAOYSA-N
LabNetwork Molecule ID	LN00198705
Canonical SMILES	-

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产品应用

有机中间体，医药上用以合成胆影酸。

安全信息

GHS Symbol

WGK Germany3

Hazard statements

H290 May be corrosive to metals 可能腐蚀金属。
H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤

Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

Precautionary statements

P234 Keep only in original container. 只保留在原来的容器中。
P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P301+P330+P331
P303+P361+P353+P310+P363
P305+P351+P338
P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
P390 Absorb spillage to prevent material damage. 吸收溢出物，防止重大损害。
P405 Store locked up. 上锁保管。
P501 Dispose of contents/container to..… 处理内容物/容器.....

Signal word Danger

Packing GroupII

UN Number 3265 UN 3265 8/PG 2 UN3265

Risk Statements

R14 Reacts violently with water 遇水会猛烈反应
R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
R29 Contact with water liberates toxic gas. 遇水释放出有毒气体
R34 Causes burns 会导致灼伤

Safety Statements

S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
S8 Keep container dry 保持容器干燥；

Storage condition +4°C 0-10 0-10°C 4 4°C, Hygroscopic 4℃ Moisture Sensitive Refrigerator 储存温度 2-8°C

Hazard Codes 8 C

Hazard Class8

Warnings 危化品目录(2015)

Restrict 危险品

其他信息

TCI Shanghai:己二酰氯 Adipoyl Chloride,>;98.0%(GC)(T)(111-50-2)
Alfa Aesar:己二酰氯,98% Adipoyl chloride, 98%(111-50-2)
能与醚及苯混溶，在水及醇中分解。溶于其它溶剂形成盐酸
敏感性:Moisture Sensitive
MOL 文件:111-50-2.mol
F:10-21
己二酰氯价格(试剂级):更新日期产品编号产品名称包装价格 2014/06/02 A0169 己二酰氯 Adipoyl Chloride 25G 506元 2014/06/02 A0169 己二酰氯 Adipoyl Chloride 100G 1030元 2014/06/02 A0169 己二酰氯 Adipoyl Chloride 500G 3760元
下游产品:1,4-二苯甲酰丁烷 --> 多培沙明 --> 2,5-二溴己二酸二乙酯
方法一:由己二酸与氯化亚砜反应：将己二酸与氯化亚砜投入反应锅，在90-95℃回流氯化5h，放冷，减压除去剩余的氯化亚砜，得成品。原料消耗定额：己二酸830kg/t、氯化亚砜1660kg/t。
Sigma Aldrich:111-50-2(sigmaaldrich)
MSDS 信息:己二酰氯(111-50-2).msds
外观性质:无色或淡黄色液体，久存或见光变成蓝黑色。
用途二:有机中间体，医药上用以合成胆影酸。
用途一:有机中间体。医药上用以合成胆影酸。
上游原料:己二酸
图谱信息:己二酰氯(111-50-2)质谱(MS) 己二酰氯(111-50-2)核磁图( 13 CNMR) 己二酰氯(111-50-2)红外图谱(IR2) 己二酰氯(111-50-2)红外图谱(IR1) 己二酰氯(111-50-2)核磁图( 1 HNMR)
Acros Organics:己二酰二氯 Adipoyl chloride, 98%(111-50-2)