CAS 7681-82-5 MFCD00003532-Sodium Iodide 碘化钠 TAO{mole}

Sodium Iodide 碘化钠

CAS 7681-82-5 MFCD00003532

化学结构图

SMILES: [I-].[Na+]

化学属性

Mol. Formula	INa
Mol. Weight	149.89
Density	3.67
Vapor Density	>;1 (vs air)
Melting Point	661°C
Refractive index	1.7745
TSCA	Yes
Boiling Point	1300°C at 760 mmHg
Solubility	Soluble in water (1840 mg/ml at 25 °C), alcohol, glycerol, and acetone. Insoluble in ether
Stability	对光敏感
Flash Point	1300-1304°C
Appearance	无色立方晶体或白色结晶性粉末。无臭、味咸苦。易溶于水，溶于甲醇、乙醇、丙酮、甘油、液氨和液体二氧化硫。水溶液呈微碱性。 beads

别名和识别编码

Chemical Name	Sodium iodide
MDL Number	MFCD00003532
CAS Number	7681-82-5
Synonym	Sodium Iodide,99% {LY} Sodium Iodide,99% {} {LY} Sodium Iodide,99% {} {} {LY} Sodium Iodide,99% {} {} {} {LY} Sodium Iodide,99% {} {} {} {} {LY} Sodium Iodide,99% {} {} {} {} {} {LY} Sodium Iodide,99% {} {} {} {} {} {} {LY} Sodium Iodide,99% {} {} {} {} {} {} {} {LY} Sodium Iodide,99% {} {} {} {} {} {} {} {} {LY} Sodium Iodide,99% {} {} {} {} {} {} {} {} {} {LY} Sodium Iodide,99% {} {} {} {} {} {} {} {} {} {} {LY} Sodium Iodide,99% {} {} {} {} {} {} {} {} {} {} {} {LY} Sodium Iodide,99% {} {} {} {} {} {} {} {} {} {} {} {} {LY} Sodium Iodide,99% {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Sodium Iodide,99% {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Sodium Iodide,99% {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Sodium Iodide,99% {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Sodium Iodide,99% {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Sodiu
PubChem Substance ID	5238
EC Number	231-679-3
Merck Number	8631
Chemical Name Translation	碘化钠
Wiswesser Line Notation	NA I
LabNetwork Molecule ID	LN00194237
InChI	InChI=1S/HI.Na/h1H;/q;+1/p-1
Canonical SMILES	[Na]I

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产品应用

化学工业用作制备无机和有机碘化物的重要原料，也用作碘的助溶剂和用于配制碘乳剂。医药工业用于生产祛痰剂和利尿剂等药物。感光工业用作胶片的感光剂，分析化学中用作点滴分析及其他分析试剂。化学反应中用作氧化剂。
当温度低于65．6℃，碘化钠在水溶液中形成含水数目不定的各种水合物。室温下由溶液析出二水物，为无色棱形晶体，-13．5～31．5℃内可析出五水物。与二氧化硫作用，生成相应的稳定化合物。有还原性，可被氧化别氧化，游离出碘。

安全信息

GHS Symbol

WGK Germany1

Precautionary statements

P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P264+P265
P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
P273 Avoid release to the environment. 避免释放到环境中。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P302+P350
P302+P352
P302+P352+P332+P313+P362+P364
P304+P340
P305+P351+P338
P305+P351+P338+P337+P313
P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医，如果你觉得不舒服
P319
P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
P332+P313
P332+P317
P337+P313
P337+P317
P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
P362+P364
P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
P403+P233
P405 Store locked up. 上锁保管。
P501 Dispose of contents/container to..… 处理内容物/容器.....

Hazard statements

H303 May be harmfully swallowed 吞食可能有害
H315 Causes skin irritation 会刺激皮肤
H319 Causes serious eye irritation 严重刺激眼睛
H335 May cause respiratory irritation 可能导致呼吸道刺激
H372 Causes damage to organs through prolonged or repeated exposure 长期或频繁接触会损伤器官
H400 Verytoxictoaquaticlife 对水生生物毒性非常大。

Signal word

Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves

RTECSWB6475000

Risk Statements

R63 Possible risk of harm to the unborn child 可能危害未出生婴儿
R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
R50 Very toxic to aquatic organisms 对水生生物极毒

Safety Statements

S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；

Storage condition RT, protect from light, stored under nitrogen {LY} RT, protect from light, stored under nitrogen Store at RT. {} {LY} RT, protect from light, stored under nitrogen {} {} {LY} RT, protect from light, stored under nitrogen {} {} {} {LY} RT, protect from light, stored under nitrogen {} {} {} {} {LY} RT, protect from light, stored under nitrogen {} {} {} {} {} {LY} RT, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} RT, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} RT, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} RT, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} RT, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} RT, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} RT, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, protect from light, stored under nitrogen {} {} {

Hazard Codes Xi,N Xi

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 4340 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   28ZPAK "Sbornik Vysledku Toxixologickeho Vysetreni Latek A Pripravku,"
   Marhold, J.V., Institut Pro Vychovu Vedoucicn Pracovniku Chemickeho Prumyclu
   Praha, Czechoslovakia, 1972  Volume(issue)/page/year: -,21,1972

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 2362 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JPETAB Journal of Pharmacology and Experimental Therapeutics.  (Williams &
   Wilkins Co., 428 E. Preston St., Baltimore, MD 21202)  V.1-    1909/10-
   Volume(issue)/page/year: 30,407,1927

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single
   Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects,
   GKNT, 1982  Volume(issue)/page/year:

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Mammal - dog
DOSE/DURATION           : 760 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   HBAMAK "Abdernalden's Handbuch der Biologischen Arbeitsmethoden." (Leipzig,
   Ger. Dem. Rep.)  Volume(issue)/page/year: 4,1289,1935

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF E

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Human - woman
DOSE                    : 9240 mg/kg
SEX/DURATION            : female 1-43 week(s) after conception
TOXIC EFFECTS :
   Reproductive - Specific Developmental Abnormalities - endocrine system
   Reproductive - Effects on Newborn - other postnatal measures or effects
REFERENCE :
   ADCHAK Archives of Disease in Childhood.  (British Medical Journal, POB
   560B, Kennebunkport, ME 04046)  V.1-    1926-  Volume(issue)/page/year:
   38,526,1963

其他信息

防护措施:参见碘。
Sodium Iodide is a cry
Sigma Aldrich:7681-82-5(sigmaaldrich)
方法一:八碘化三铁法按碘：铁屑=3．3：1的质量比，先将洗净的铁屑加入反应器内，再加水，加水量与铁屑质量比为7：1。分批加入碘片，由于碘和铁反应时产生大量的热，在反应器外需用冷水冷却，使其温度低于65℃。加入碘片后溶液呈深红棕色，待溶液呈淡绿色后，加入第二批碘，过滤除去铁屑，再加入碘反应生成八碘化三铁。在容器中加入碳酸氢钠溶液，在搅拌下缓慢加入八碘化三铁进行反应，此时有二氧化碳气体逸出。反应溶液经静置，吸出上层清液，蒸发浓缩至70～72°Bé，趁热过滤，经冷却结晶、离心分离、干燥，制得碘化钠成品。其 Fe+I2→FeI2 3FeI2+I2→Fe3I8 Fe3I8+8NaHCO3→8NaI+Fe3O4+4H2O+8CO2↑ 铁屑还原法取理论量的：100%～103%烧碱，加水稀释成10%溶液，于反应器中加热至60～80℃，在搅拌下分次加入定量碘，于80～90℃保温搅拌反应约1h，反应液为棕色，Ph值为6～7，同时有碘酸钠的白色结晶析出。将反应液降温至30℃以下，加入2倍于理论量的铁屑使碘酸钠还原成碘化钠。开始反应较剧烈，待反应缓和后，加热煮沸，继续搅拌反应1～2h，然后用10%烧碱溶液调节Ph值为8，煮沸30min，经冷却、静置过
碘化钠价格(试剂级):更新日期产品编号产品名称包装价格 2011/08/23 20039818 碘化钠 500g 550元 2011/08/23 20039828 碘化钠 500g 535元 2011/08/23 51024360 碘化钠 5g 26.2元
MSDS 信息:Sodium iodide (7681-82-5).msds
Acros Organics:碘化钠 Sodium iodide, anhydrous, pure, 99+%(7681-82-5)
上游原料:碘 --> 铁屑 --> 碘 --> 碘酸钠
参考质量标准:参考标准指标名称指标碘化钠(NaI)/%≥ 99.0 硫酸盐(以SO4 2- 计)/%≤ 0.040 干燥失重/%≤ 3.0 重金属(以Pb计)/%≤ 0
蒸气密度:>;1 (vs air)
水中溶解度(g/100ml):不同温度(℃)时每100毫升水中的溶解克数: 159g/0℃;167g/10℃;178g/20℃;191g/30℃;205g/40℃ 257g/60℃;295g/80℃;302g/100℃
相关化学反应:碘化钠与氯或溴作用，均能生成单质碘，同时能生成卤化钠。 (1) 2NaI+Cl2＝2NaCl+I2 (2) 2NaI+Br2＝2NaBr+I2 碘化钠与酸作用，均能生成相应酸的钠盐，同时能生成碘化氢、氢碘酸或单质碘。 (3)NaI+H3PO4＝NaH2PO4+HI (4)2NaI+H3PO4＝NaH2PO4+2HI (5)3NaI+H3PO4＝Na3PO4+3HI (6)NaI+H3Sb4＝NaH2SbO4(白色)+HI (7)NaI+H2SO4(浓)＝NaHSO4+HI (8)2NaI+3H2SO4(浓)＝2NaHSO4+I2+SO2+2H2O (9) NaI+HCl=NaCl+HI 碘化钠与次氯酸作用，生成氯化钠、氢氧化钠和单质碘。 (10) 2NaI+HOCl=NaCl+NaOH+I2 碘化钠与下列盐或氧化物作用，能生成不同的钠盐。 (11) NaI+6Ce(SO4)2+3H2O=NaIO3+3Ce2(SO4)3+3H2SO4 (12) 2NaI+4Ce(SO4)2+2HCl=Na2SO4+2Ce2(SO4)2+2ICl+H2SO4 (13) NaI+3NaIO4＝4NaIO3 (14) 2NaI+3NaIO4+3H2O=NaIO3+2Na2H3IO6+I2 (15) 2NaI+2CO2+H2O2＝2NaHCO3+I2 (16) 2NaI+MnO2+3H2SO4＝2NaHSO4+MnSO4+I2+2H2O
Sodium Iodide is a crystalline salt commonly used in the Finkelstein reac