Tetraethylammonium tetrafluoroborate 四氟硼酸四乙胺
CAS 429-06-1 MFCD00011827
化学结构图
SMILES: CC[N+](CC)(CC)CC.F[B-](F)(F)F
化学属性
| Mol. Formula | C8H20BF4N |
|---|---|
| Mol. Weight | 217 |
| Melting Point | 300 |
| TSCA | Yes |
| Appearance | 白色至类白色晶体 |
| Solubility | acetonitrile: 0.1 g/mL, clear, colorless |
| Density | 1.374 |
| Stability | 对湿度敏感 |
别名和识别编码
| Chemical Name | Tetraethylammonium tetrafluoroborate |
|---|---|
| MDL Number | MFCD00011827 |
| CAS Number | 429-06-1 |
| PubChem Substance ID | 2724277 |
| EC Number | 207-055-1 |
| Beilstein Registry Number | 3917638 |
| Synonym | TETRAETHYLAMMONIUM FLUOROBORATE 四乙基氟硼酸铵 TETRAETHYLAMMONIUM TETRAFLUOROBORATE, 99 % 四乙基四氟硼酸铵;四氟硼酸四乙铵 四乙基四氟硼酸铵 四氟硼酸四乙胺 Tetraethylazanium tetrafluoroborate Tetraethylammonium tetrafluoroborate 99% TETRAETHYLAMMONIUM TETRAFLUOROBORATE Tetraethylaminium·tetrafluoroboronanion Ethanaminium, N,N,N-triethyl-, tetrafluoroborate(1-) Tetraethylammonium·tetrafluoroboronanion TETRAETHYLAMMONIUM TETRAFLUOROBORATE, EL ECTROCHEM. GRADE |
| Chemical Name Translation | 四氟硼酸四乙胺 |
| Reaxys-RN | 3917638 |
| InChIKey | DERCYJCSMRCWEQ-UHFFFAOYSA-N |
| LabNetwork Molecule ID | LN00202425 |
| InChI | InChI=1S/C8H20N.BF4/c1-5-9(6-2,7-3)8-4;2-1(3,4)5/h5-8H2,1-4H3;/q+1;-1 |
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分类
- {SNA} Ammonium Salts, Chemical Synthesis,
- {SNA} Ammonium Salts, Chemical Synthesis, Materials Science, Metal and Ceramic Science, Phase Transfer Catalysts, Salts, Synthetic Reagents
- {SA} Ammonium Salts,
- {SNA} Ammonium Salts, Chemical Synthesis, Essential Chemicals, Metal and Ceramic Science, Phase Transfer Catalysts, Research Essentials, Salts, Synthetic Reagents, 材料科学
- {SNA} Ammonium Salts, Chemical Synthesis, Electrochemistry, Phase Transfer Catalysts, Supporting Electrolytes for Electrochemistry, Synthetic Reagents, 分析/色谱, 分析试剂
相关文献及参考
- Electrolyte for electro-organic synthesis, e.g. in the o- and p- hydroxylation of simple aromatic ketones, acids and esters by anodic oxidation in TFA: J. Chem. Soc., Chem. Commun., 262 (1975). In CH3CN, the products are the corresponding o- and p-acetamido compounds (cf Ritter reaction).
- Use as a supporting electrolyte and F- source for electrochemical fluorination has also been reported: J. Electroanal. Chem., 43, 318 (1973).
安全信息
GHS Symbol
- H315 Causes skin irritation 会刺激皮肤
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- H319 Causes serious eye irritation 严重刺激眼睛
- H302+H312+H332
- H302 Harmful if swallowed 吞食有害
- H332 Harmful if inhaled 吸入有害
- H312 Harmful in contact with skin 皮肤接触有害
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P330+P331
- P301+P330+P331+P310
- P303+P361+P353+P310+P363
- P304+P340+P310
- P305+P351+P338
- P305+P351+P338+P310
- P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
- P405 Store locked up. 上锁保管。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36 Wear suitable protective clothing 穿戴适当的防护服；
- R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
其他信息
- MOL 文件:429-06-1.mol
- Alfa Aesar:四乙基四氟硼酸铵,99% Tetraethylammonium tetrafluoroborate, 99%(429-06-1)
- TCI Shanghai:四乙基四氟硼酸铵 Tetraethylammonium Tetrafluoroborate,>;98.0%(T)(429-06-1)
- 海关编码:29239000
- 上游原料:氟硼酸钠 --> 四乙基溴化铵
- Acros Organics:四乙基四氟硼酸铵 Tetraethylammonium tetrafluoroborate, 99%(429-06-1)
- Hazard Note:Irritant/Hygroscopic
- 图谱信息:四乙基四氟硼酸铵(429-06-1)核磁图( 1 HNMR) 四乙基四氟硼酸铵(429-06-1)核磁图( 13 CNMR) 四乙基四氟硼酸铵(429-06-1)红外图谱(IR2) 四乙基四氟硼酸铵(429-06-1)红外图谱(IR1) 四乙基四氟硼酸铵(429-06-1)质谱(MS)
- MSDS 信息:Tetraethylammonium tetrafluoroborate(429-06-1).msds
- Sigma Aldrich:429-06-1(sigmaaldrich)
- 敏感性:Hygroscopic
- 四乙基四氟硼酸铵价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T0983 四乙基四氟硼酸铵 Tetraethylammonium Tetrafluoroborate 25G 636元 2010/06/21 221615000 四乙基四氟硼酸铵 Tetraethylammonium tetrafluoroborate 99% 500 GR 15479元 2010/06/21 221610250 四乙基四氟硼酸铵 Tetraethylammonium tetrafluoroborate 99% 25 GR 987元
