乙酸汞 乙酸汞
CAS 1600-27-7 MFCD00012165
化学结构图
SMILES: CC(=O)O[Hg]OC(C)=O
化学属性
| Mol. Formula | C4 H6 Hg O4 |
|---|---|
| Mol. Weight | 318.68 |
| Melting Point | 179-182° |
| Density | 3.28 |
| TSCA | Yes |
| Solubility | 溶于水、乙醇。 |
| Boiling Point | - |
| Flash Point | - |
别名和识别编码
| Chemical Name | 乙酸汞 |
|---|---|
| Synonym | ACETIC ACID MERCURY SALT ACETIC ACID, MERCURIC SALT Acetic acid mercury(II) salt Acetic acid mercury(II) salt~Mercuric ace Acetic acid, mercuridi- Acetic acid, mercury(2+) salt Aceticacid,mercury(2+)salt Anthracene, 1,4-dihydro-, compd. with mercury diacetate (1:1) Bis(acetyloxy)mercury Bis(acetyloxy)mercury; Diacetoxymercury; Mercuric acetate; Mercuric diacetate; Mercuric(II) acetate; Acetic acid mercury(2+) salt Diacetoxymercury Essigsäure Quecksilber(II)-Salz MERCURIC ACETATE MERCURY ACETATE MERCURY(+2)ACETATE MERCURY(II) ACETATE Mercuriacetate Mercuric acetate Mercury acetate Mercury acetate (Hg(CH3CO2)2) Mercury acetate (Hg(O2C2H3)2) Mercury acetate, Hg(OAc)2, c |
| Beilstein Registry Number | 3563831 |
| PubChem Substance ID | 15337 |
| CAS Number | 1600-27-7 |
| EC Number | 216-491-1 |
| MDL Number | - |
| Merck Number | 14,5873 |
| Chemical Name Translation | 乙酸汞 |
| Wiswesser Line Notation | QV1 &QV1 &-HG- |
| InChI | InChI=1S/2C2H4O2.Hg/c2*1-2(3)4;/h2*1H3,(H,3,4);/q;;+2/p-2 |
| Canonical SMILES | - |
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分类
- {uni_hamburg} no charge; carboxylate; 3fragments; ionic
- {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Materials Science, Mercury, Mercury Salts, Metal and Ceramic Science, Salts
相关文献及参考
- Merck 14 ,5873
- Beil. 2 ,IV,114
- Fieser 1 ,644 / Fieser 2 ,264 / Fieser 3 ,194 / Fieser 4 ,319 / Fieser 5 ,424 / Fieser 6 ,358 / Fieser 10 ,252 / Fieser 15 ,198 / Fieser 17 ,176
- Corp MSDS 1 (2), 2214:B / FT-IR 1 (2), 1274:B / FT-IR 2 (1), 853:D / IR-Spectra (2), 292:F / IR-Spectra (3), 325:C / RegBook 1 (1), 607:F / Sax 6 , 1747 / Structure Index 1 , 87:A:4
- Short: III/5a Title: Structure Data of Organic Crystals: C ... C 13 Author: Schudt, E.; Weitz, G. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/5a Year: 1971 ISBN: 3-540-05177-5 ISBN: 978-3-540-05177-0 Internet Resource: DOI:10.1007/b19970 RefComment: XXI, 736 pages, and VII, 890 pages. Hardcover Abstract: Volume III/5 offers a compitation as complete as possible of the space groups and lattice con-stants of all crystals which have been studied by means of X-rays, neutron and electron diffraction.
- Short: EINECS Title: EINECS (Europ
- The solvomercuration of alkenes by Hg(OAc)2, with demercuration by NaBH4, is a useful method for the Markovnikov hydration of alkenes; reviews: Angew. Chem. Int. Ed., 17, 27 (1978); Tetrahedron, 38, 1713 (1982). See, e.g.: Org. Synth. Coll., 6, 766 (1988):
- Intramolecular oxy- or amino-mercuration is a useful route to oxygen or nitrogen heterocycles: J. Heterocycl. Chem., 11, 771 (1974); 13, 349 (1976); 15, 1313 (1978):
- For an improved method for the synthesis of substituted pyrrolidines using TBTH as reducing agent, avoiding the reaction reversal encountered with borohydride, see: Synth. Commun., 26, 1507 (1996).
- Mercuration/demercuration of aliphatic isocyanates provides a mild route to primary amines: Tetrahedron Lett., 36, 8859 (1995).
- For a review of organomercurials in synthesis, see: Tetrahedron, 38, 1713 (1982).
安全信息
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P273 Avoid release to the environment. 避免释放到环境中。
- P301+P310
- P284 Wear respiratory protection.? 佩戴呼吸保护装置。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
GHS Symbol
- H330 Fatal if inhaled 吸入致命
- H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
- H310 Fatal in contact with skin 皮肤接触致命
- H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
- H300 Fatal if swallowed 吞食致命
- S13 Keep away from food, drink and animal foodstuffs 远离食品、饮料和动物饲料保存；
- S36 Wear suitable protective clothing 穿戴适当的防护服；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
- S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
- S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
- R26/27/28 Very toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有剧毒
- R50/53
- R33 Danger of cumulative effects 有累积作用的危险
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 40900 ug/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 46(8),12,1981
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intraperitoneal SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 6500 ug/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 25(7),27,1981
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 23900 ug/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Mosco
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Administration onto the skin SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 570 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 25(7),27,1981
TYPE OF TEST : Mutation in mammalian somatic cells TEST SYSTEM : Rodent - hamster Ovary DOSE/DURATION : 100 nmol/L REFERENCE : EMMUEG Environmental and Molecular Mutagenesis. (Alan R. Liss, Inc., 41 E. 11th St., New York, NY 10003) V.10- 1987- Volume(issue)/page/year: 27,30,1996
TYPE OF TEST : Mutation test systems - not otherwise specified TEST SYSTEM : Rodent - mouse Cells - not otherwise specified DOSE/DURATION : 50 mg/L REFERENCE : MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 17,93,1973
TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Intraperitoneal SPECIES OBSERVED : Rodent - hamster DOSE : 2 mg/kg SEX/DURATION : female 8 day(s) after conception TOXIC EFFECTS : Reproductive - Fertility - post-implantation mortality (e.g. dead and/or resorbed implants per total number of implants) Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death, e.g., stunted fetus) Reproductive - Specific Developmental Abnormalities - other developmental abnormalities REFERENCE : ENVRAL Environmental Research. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1967- Volume(issue)/page/year: 8,207,1974
TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - hamster DOSE : 25 mg/kg SEX/DURATION : female 8 day(s) after conception TOXIC EFFECTS : Reproductive - Specific Developmental Abnormalities - other developmental abnormalities REFERENCE : ENVRAL Environmental Research. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1967- Volume(issue)/page/year: 8,207,1974
TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Intravenous SPECIES OBSERVED : Rodent - rat DOSE : 3 mg/kg SEX/DURATION : female 10 day(s) after conception TOXIC EFFECTS : Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death, e.g., stunted fetus) REFERENCE : ATSUDG Archives of Toxicology, Supplement. (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ 07094) No.1- 1978- Volume(issue)/page/year: 7,382,1984
TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - hams
其他信息
- 职业标准:TLV-TWA 0.05 毫克 (汞)/立方米; STEL 0.10 毫克 (汞)/立方米
- MSDS 信息:乙酸汞(1600-27-7).msds
- 用途一:用作分析试剂，也用于有机合成
- 储运特性:库房通风低温干燥; 与酸类, 食品分开储运
- 乙酸汞价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 80077160 乙酸汞（剧毒） 250g 1350元 2010/06/21 255650050 乙酸汞 Mercuric acetate 99+% 5 GR 622元 2010/06/21 175021000 乙酸汞 Mercuric acetate 98% 100 GR 627元
- 用途二:用作有机合成催化剂，用于医药工来和分析试剂。该品为剧毒品。
- Alfa Aesar:乙酸汞(II),ACS,98.0%min Mercury(II) acetate, ACS, 98.0% min(1600-27-7)
- 类别:有毒物品
- 毒性分级:剧毒
- 可燃性危险特性:受热分解剧毒含汞蒸气, 及可燃气体
- 下游产品:亚胺培南(一水物) --> DL-苏氨酸 --> 棕榈酸乙烯酯 --> 硬脂酸酯乙烯基 --> 1-甲基环己醇
- 外观性质:白色结晶或粉末，有乙酸气味。
- 上游原料:汞 --> 氧化汞(II), 黄
- TSCA:Yes
- Acros Organics:乙酸汞 Mercuricacetate,98%(1600-27-7)
- Sigma Aldrich:1600-27-7(sigmaaldrich)
- 水中溶解度(g/100ml):每100毫升水中的溶解克数: 25g/20℃
- MOL 文件:1600-27-7.mol
- 图谱信息:乙酸汞(1600-27-7)红外图谱(IR1) 乙酸汞(1600-27-7)红外图谱(IR2)
- 灭火剂:水, 二氧化碳, 干粉
- 方法一:由乙酸与黄色氧化汞反应而得。将300ml30%的乙酸加热后，逐渐加入110g黄色氧化汞。溶解后趁热过滤，于暗处浓缩滤液至有结晶薄膜生成。经冷却，滤出结晶。母液再经浓缩结晶，得乙酸汞100g。
- 急性毒性:口服-大鼠 LD50: 40.9 毫克/公斤; 口服-小鼠 LD50: 23.9 毫克/公斤
