2,9-Dimethyl-1,10-Phenanthroline Hemihydrate 2,9-二甲基-1,10-菲罗啉半水合物

CAS 34302-69-7 MFCD00149306

化学结构图

34302-69-7
SMILES: CC1C=CC2=CC=C3C=CC(C)=NC3=C2N=1

化学属性

Mol. FormulaC27H24N4O
Mol. Weight421
Melting Point159-164
TSCAYes

别名和识别编码

Chemical Name2,9-Dimethyl-1,10-Phenanthroline Hemihydrate
Synonym 2,9-二甲基-1,10-菲咯啉 水合物 Neocuproine hemihydrate
CAS Number34302-69-7
PubChem Substance ID87567401
EC Number207-601-9
Beilstein Registry Number153179
MDL NumberMFCD00004973
Merck Number6449
Chemical Name Translation2,9-二甲基-1,10-菲罗啉半水合物
Reaxys-RN153179
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分类

  • {SNA} Building Blocks, Chemical Synthesis, Heterocyclic Building Blocks, N-Containing, Others
  • {SNA} Analytical Reagents for General Use, I-N, Puriss p.a., Puriss p.a., Spectroscopy, UV/Vis Reagents, UV/Visible (UV/VIS) Spectroscopy, 分析/色谱, 分析试剂
  • {SA} Analytical Reagents, Analytical Reagents for General Use, Analytical/Chromatography, I-N, Puriss p.a., Puriss p.a., Spectroscopy, UV/Vis Reagents, UV/Visible (UV/VIS) Spectroscopy
  • {SNA} Building Blocks, Chemical Synthesis, Heterocyclic Building Blocks, N-Containing, Other Heterocyclic Building Blocks

相关文献及参考

  • Reagent for copper: Anal. Chem., 46, 692 (1974).
  • Complexing agent for Cu(I) in the formation of aryl-sulfur bonds by reaction of aryl iodides with aryl and alkyl thiols: Org. Lett., 4, 2803 (2002). Co-catalyst in the Pd-catalyzed oxidation of alcohols: Adv. Synth. Catal., 345, 1341 (2003).

安全信息

GHS Symbol
WGK Germany3
Hazard Codes Xn Xi
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H318 Causes serious eye damage 严重伤害眼睛
  • H302 Harmful if swallowed 吞食有害
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
Signal word Danger
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
Risk Statements
  • R22 Harmful if swallowed 吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R37/38 Irritating to respiratory system and skin 对呼吸系统和皮肤有刺激性
  • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Heterocyclic Building Blocks 杂环合成砌块
  4. Others 其他杂环
  5. N-Containing - Others
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Analytical Reagents for General Use - Analytical Reagents
  4. Puriss p.a. - Analytical Reagents for General Use
  5. I-N, Puriss p.a. - Puriss p.a.