Tris(4-Methoxyphenyl)Phosphine 三(4-甲氧苯基)膦

CAS 855-38-9 MFCD00014896

化学结构图

855-38-9
SMILES: COc1ccc(P(c2ccc(OC)cc2)c2ccc(OC)cc2)cc1

化学属性

Mol. FormulaC21H21O3P
Mol. Weight352.37
Melting Point130.0 to 135.0 deg-C
TSCAYes
Density1.422
Stability对空气敏感
Appearance white to pale yellow xtl.
Boiling Point457.8°C at 760 mmHg

别名和识别编码

Chemical NameTris(4-Methoxyphenyl)Phosphine
Synonym Tris(4-methoxyphenyl)phosphine {LY} Tris(4-methoxyphenyl)phosphine {} {LY} Tris(4-methoxyphenyl)phosphine {} {} {LY} Tris(4-methoxyphenyl)phosphine {} {} {} {LY} Tris(4-methoxyphenyl)phosphine {} {} {} {} {LY} Tris(4-methoxyphenyl)phosphine {} {} {} {} {} {LY} Tris(4-methoxyphenyl)phosphine {} {} {} {} {} {} {LY} Tris(4-methoxyphenyl)phosphine {} {} {} {} {} {} {} {LY} Tris(4-methoxyphenyl)phosphine {} {} {} {} {} {} {} {} {LY} Tris(4-methoxyphenyl)phosphine {} {} {} {} {} {} {} {} {} {LY} Tris(4-methoxyphenyl)phosphine {} {} {} {} {} {} {} {} {} {} {LY} Tris(4-methoxyphenyl)phosphine {} {} {} {} {} {} {} {} {} {} {} {LY} Tris(4-methoxyphenyl)phosphine {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tris(4-methoxyphenyl)phosphine {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tris(4-methoxyphenyl)phosphine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tris(4-methoxyphenyl)phosphine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
MDL NumberMFCD00014896
CAS Number855-38-9
PubChem Substance ID70071
EC Number212-723-0
Beilstein Registry Number2815911
Reaxys-RN2815911
Chemical Name Translation三(4-甲氧苯基)膦
InChIKeyUYUUAUOYLFIRJG-UHFFFAOYSA-N
LabNetwork Molecule IDLN00192838
InChIInChI=1S/C21H21O3P/c1-22-16-4-10-19(11-5-16)25(20-12-6-17(23-2)7-13-20)21-14-8-18(24-3)9-15-21/h4-15H,1-3H3
Canonical SMILESCOC1=CC=C(P(C2=CC=C(OC)C=C2)C3=CC=C(OC)C=C3)C=C1
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分类

  • {SNA} Basic Phosphine Ligands, Catalysis and Inorganic Chemistry, Chemical Synthesis, Cross-Coupling, Phosphine Compounds, Phosphine Ligands
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; ether; 1fragment

相关文献及参考

  • Short: III/35C4
  • Short: EINECS
  • Beilstein: 16,III,843

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Warning
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition 2-8°C, stored under nitrogen {LY} 2-8°C, stored under nitrogen Air Sensitive Store at room temperature {} {LY} 2-8°C, stored under nitrogen {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under
Hazard Codes Xi

其他信息

  • Sigma Aldrich:855-38-9(sigmaaldrich)
  • 三(4-甲氧苯基)膦价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T0861 三(4-甲氧基苯基)膦 Tris(4-methoxyphenyl)phosphine 5G 900元 2014/06/02 T0861 三(4-甲氧基苯基)膦 Tris(4-methoxyphenyl)phosphine 25G 2740元 2010/06/21 422240010 三(4-甲氧苯基)膦 Tris(4-methoxyphenyl)phosphine 95% 1 GR 335元
  • TCI Shanghai:三(4-甲氧基苯基)膦 Tris(4-methoxyphenyl)phosphine,>;95.0%(T)(855-38-9)
  • 图谱信息:三(4-甲氧苯基)膦(855-38-9)红外图谱(IR2) 三(4-甲氧苯基)膦(855-38-9)质谱(MS) 三(4-甲氧苯基)膦(855-38-9)红外图谱(IR1) 三(4-甲氧苯基)膦(855-38-9)核磁图( 13 CNMR) 三(4-甲氧苯基)膦(855-38-9)核磁图( 1 HNMR)
  • MOL 文件:855-38-9.mol
  • Alfa Aesar:三(4-甲氧苯基)膦,98% Tris(4-methoxyphenyl)phosphine, 98%(855-38-9)
  • Acros Organics:三(4-甲氧苯基)膦 Tris(4-methoxyphenyl)phosphine, 95%(855-38-9)

系列性分类


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