Tris(4-fluorophenyl)phosphine 三(4-氟苯基)膦
CAS 18437-78-0 MFCD00013553
化学结构图
SMILES: Fc1ccc(cc1)P(c1ccc(F)cc1)c1ccc(F)cc1
化学属性
| Mol. Formula | C18H12F3P |
|---|---|
| Mol. Weight | 316.26 |
| Melting Point | 79.0 to 83.0 deg-C |
| TSCA | No |
| Boiling Point | 160°C/0.1mmHg(lit.) |
| Appearance | off-white xtl. |
别名和识别编码
| Chemical Name | Tris(4-fluorophenyl)phosphine |
|---|---|
| CAS Number | 18437-78-0 |
| Alfabeta Name | TRISFLUOROPHENYLPHOSPHINE 4()- |
| MDL Number | MFCD00013553 |
| Synonym | tris-(4-fluoro-phenyl)-phosphane Phosphine, tris(4-fluorophenyl)- Tri-(p-fluorophenyl)phosphine; Tris(p-fluorophenyl)phosphine Tri-(p-fluorophenyl)phosphine Tris(4-fluorophenyl)phosphine tris(p-fluorophenyl)phosphine Tris-(4-fluorphenyl)-phosphin Phosphine, tris(p-fluorophenyl)- 三(4-氟苯基)膦 tri(4-fluorophenyl)phosphine |
| Beilstein Registry Number | 919838 |
| PubChem Substance ID | 160871182 |
| Chemical Name Translation | 三(4-氟苯基)膦 |
| InChIKey | GEPJPYNDFSOARB-UHFFFAOYSA-N |
| Reaxys-RN | 919838 |
| LabNetwork Molecule ID | LN00118649 |
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分类
- {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Phosphine Compounds, Phosphine Ligands
- {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
- {SNA} 12 Principles Aligned Products, Catalysis, Catalysis and Inorganic Chemistry, Chemical Synthesis, Greener Alternative Products, Phosphine Compounds, Phosphine Ligands
相关文献及参考
- Short: III/35C4 Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts and Coupling Constants for Hydrogen-1, Part 4: Inorganic and Organometallic Compounds Author: Gupta, R.R.; Platzer, N. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35C4 Year: 2001 Keyword: Hydrogen 1; Nuclear Magnetic Resonance ISBN: 3-540-41059-7 ISBN: 978-3-540-41059-1 Internet Resource: DOI:10.1007/b76570 RefComment: VII, 299 pages. With CD-ROM. Hardcover Abstract: This volume provides a comprehensive and evaluated compilation of nuclear magnetic resonance data. Chemical shifts and coupling constants of boron-11 and phosphorus-31 (subvol. A), fluorine-19 and nitrogen-15 (subvol. B), hydrogen-1 (subvol. C), and carbon-13 (subvol. D) compounds are tabulated together with the gross- and structure formulas and the most readily available solvents. Due to the large amount of the data merely chemical shifts are presented in the printed versions, and all the data, chemical shifts and coupling constants are provided on CD-ROM's.
安全信息
GHS Symbol
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- P302+P352+P332+P313+P362+P364
- P305+P351+P338+P337+P313
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36 Wear suitable protective clothing 穿戴适当的防护服；
- S37 Wear suitable gloves 戴适当手套；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
