CAS 1038-95-5 MFCD00008542-Tri-p-tolylphosphine 三(对甲苯基)膦 TAO{mole}

Tri-p-tolylphosphine 三(对甲苯基)膦

CAS 1038-95-5 MFCD00008542

化学结构图

SMILES: Cc1ccc(P(c2ccc(C)cc2)c2ccc(C)cc2)cc1

化学属性

Mol. Formula	C21H21P
Mol. Weight	304.37
Density	1.422
Melting Point	147.0 to 150.0 deg-C
TSCA	Yes
Stability	对空气敏感
Appearance	white xtl.
Boiling Point	399.8°C at 760 mmHg
Flash Point	206.3°C

别名和识别编码

Chemical Name	Tri(p-tolyl)phosphine
Synonym	Tri-p-tolylphosphine {LY} Tri-p-tolylphosphine {} {LY} Tri-p-tolylphosphine {} {} {LY} Tri-p-tolylphosphine {} {} {} {LY} Tri-p-tolylphosphine {} {} {} {} {LY} Tri-p-tolylphosphine {} {} {} {} {} {LY} Tri-p-tolylphosphine {} {} {} {} {} {} {LY} Tri-p-tolylphosphine {} {} {} {} {} {} {} {LY} Tri-p-tolylphosphine {} {} {} {} {} {} {} {} {LY} Tri-p-tolylphosphine {} {} {} {} {} {} {} {} {} {LY} Tri-p-tolylphosphine {} {} {} {} {} {} {} {} {} {} {LY} Tri-p-tolylphosphine {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {LY} Tri-p-tolylphosphine {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tri-p-tolylphosphine {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tri-p-tolylphosphine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tri-p-tolylphosphine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tri-p-tolylphosphine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
MDL Number	MFCD00008542
CAS Number	1038-95-5
EC Number	213-863-5
Beilstein Registry Number	651045
PubChem Substance ID	13956
Reaxys-RN	651045
Chemical Name Translation	三(对甲苯基)膦
Wiswesser Line Notation	1R DPR D1&R D1
InChIKey	WXAZIUYTQHYBFW-UHFFFAOYSA-N
LabNetwork Molecule ID	LN00226948
InChI	InChI=1S/C21H21P/c1-16-4-10-19(11-5-16)22(20-12-6-17(2)7-13-20)21-14-8-18(3)9-15-21/h4-15H,1-3H3
Canonical SMILES	CC1=CC=C(C=C1)P(C2=CC=C(C=C2)C)C3=CC=C(C=C3)C

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安全信息

Signal word

GHS Symbol

WGK Germany3

Safety Statements

S36 Wear suitable protective clothing 穿戴适当的防护服；
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S37 Wear suitable gloves 戴适当手套；
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；

Risk Statements

R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

Precautionary statements

P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P264+P265
P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P302+P350
P302+P352
P302+P352+P332+P313+P362+P364
P304+P340
P305+P351+P338
P305+P351+P338+P337+P313
P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
P319
P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
P332+P313
P332+P317
P337+P313
P337+P317
P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
P362+P364
P403+P233
P405 Store locked up. 上锁保管。
P501 Dispose of contents/container to..… 处理内容物/容器.....

Hazard statements

H315 Causes skin irritation 会刺激皮肤
H319 Causes serious eye irritation 严重刺激眼睛
H335 May cause respiratory irritation 可能导致呼吸道刺激

RTECSSZ3880000

Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves

Storage condition 2-8°C, stored under nitrogen {LY} 2-8°C, stored under nitrogen Air Sensitive Store at room temperature {} {LY} 2-8°C, stored under nitrogen {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under

Hazard Codes Xi

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 180 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#02043

其他信息

三对苯甲基膦价格(试剂级):更新日期产品编号产品名称包装价格 2014/06/02 T0862 三(4-甲基苯基)膦 Tris(4-methylphenyl)phosphine 5G 596元 2014/06/02 T0862 三(4-甲基苯基)膦 Tris(4-methylphenyl)phosphine 25G 1590元 2010/06/21 422330010 三对苯甲基膦 Tri-p-tolylphosphine 95% 1 GR 354元
Acros Organics:三对甲苯基膦 Tri-p-tolylphosphine, 95%(1038-95-5)
敏感性:Air Sensitive
MOL 文件:1038-95-5.mol
TCI Shanghai:三(4-甲基苯基)膦 Tris(4-methylphenyl)phosphine,>;95.0%(GC)(T)(1038-95-5)
F:10-23
图谱信息:三对苯甲基膦(1038-95-5)红外图谱(IR1) 三对苯甲基膦(1038-95-5)质谱(MS) 三对苯甲基膦(1038-95-5)核磁图( 1 HNMR) 三对苯甲基膦(1038-95-5)核磁图( 13 CNMR) 三对苯甲基膦(1038-95-5)红外图谱(IR2)
Alfa Aesar:三(对甲苯基)膦,98% Tri(p-tolyl)phosphine, 98%(1038-95-5)
Sigma Aldrich:1038-95-5(sigmaaldrich)
检测方法:HPLC,NMR
上游原料:乙醇 --> 盐酸 --> 乙酸乙酯 --> 四氢呋喃 --> 二氯甲烷 --> 石油醚 --> 镁 --> 三氯化磷 --> 对溴甲苯 --> 3,5-二甲基溴苯
存储注意事项:空气敏感