Borane tetrahydrofuran complex solution 硼烷四氢呋喃络合物
CAS 14044-65-6 MFCD00012429
化学结构图
SMILES: B.C1CCOC1
化学属性
| Mol. Formula | C4H11BO |
|---|---|
| Mol. Weight | 86 |
| Density | 0.898 |
| Flash Point | -22°C(lit.) |
| TSCA | Yes |
| Boiling Point | 66 |
| Solubility | 起反应 |
| Stability | 对空气敏感，对湿度敏感 |
| Danger-Level | - |
| pH | -:- |
| Redox | - |
别名和识别编码
| Chemical Name | Borane tetrahydrofuran complex solution |
|---|---|
| Beilstein Registry Number | 3668402 |
| MDL Number | MFCD00012429 |
| PubChem Substance ID | 24850560 |
| Synonym | BORANE TETRAHYDROFURAN COMPLEX SOLUTION, ~1 M IN THF TETRAHYDROFURAN BORANE Borane tetrahydrofuran complex solution 四氫喃硼烷 四氢喃硼烷 硼烷-四氢呋喃 BORANE BORANE-TETRAHYDROFURAN COMPLEX, CA. 1.8M SOLUTION IN TETRAHYDROFURAN, TECH. BTHF Borane-tetrahydrofuran complex, 1M solution tetrahydrofuran BORANE-TETRAHYDROFURAN COMPLEX, 1.5M SOL N IN TETRAHYDROFURAN AND ETHER, TECH. BORANE-TETRAHYDROFURAN COMPLEX 1.0M SO& BORANE TETRAHYDROFURAN COMPLEX BORANE-TETRAHYDROFURAN BORON HYDRIDE-TETRAHYDROFURAN COMPLEX Tetrahydrofuran borane |
| EC Number | 237-881-8 |
| CAS Number | 14044-65-6 |
| Reaxys-RN | 3668402 |
| Chemical Name Translation | 硼烷四氢呋喃络合物 |
| LabNetwork Molecule ID | LN01358165 |
信息真实价格透明
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信息真实价格透明
资金保障
专业采购外包团队在线服务
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分类
- {SA} 25mL Sure/Seal Reagents, Boranes, Chemical Synthesis, Organometallic Reagents, Reduction, Synthetic Reagents
- {SNA} 25mL Sure/Seal Reagents, Boranes, Chemical Synthesis, Organometallic Reagents, Reduction, Synthetic Reagents
- {SNA} Boranes, Chemical Synthesis, Reduction, Synthetic Reagents
产品应用
- 用于将聚酰胺纤维表面的酰胺基还原为仲胺。
相关文献及参考
- Beilstein:17(3/4)24
- Examples of hydroboration reactions:
- For other reactions of borane, see Borane-dimethyl sulfide complex, L07705.
- For use in the reduction of carboxylic acids to alcohols, see: Org. Synth. Coll., 7, 221 (1990).
- Hydroboration, followed by reaction of the trialkylborane with a diazoketone to give a homologated ketone: Org. Synth. Coll., 6, 919 (1988). In situ generation of "disiamyl" borane from 2-methyl-2-butene, and use of this reagent in selective hydroboration reactions: Org. Synth. Coll., 7, 258 (1990). Preparation of di-3-pinanylborane from (-)-ɑ-pinene, and its use in asymmetric hydroborations, see: Org. Synth. Coll., 7, 339 (1990).
安全信息
GHS Symbol
- H315 Causes skin irritation 会刺激皮肤
- H302 Harmful if swallowed 吞食有害
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- H260 In contact with water releases flammable gases which may ignite spontaneously 与水接触时释放可燃气体，可自燃。
- H318 Causes serious eye damage 严重伤害眼睛
- H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
- H351 Suspected of causing cancer 怀疑致癌
- H319 Causes serious eye irritation 严重刺激眼睛
- P303+P361+P353
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire. 远离任何与水接触的可能，因为会剧烈反应可能产生闪火。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P370+P378
- P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P422 Store contents under… 存储目录在…之下。
- P231+P232
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P301+P330+P331+P310
- P403+P233
- P305+P351+P338+P310
- R11 Highly flammable 非常易燃
- R22 Harmful if swallowed 吞咽有害
- R19 May form explosive peroxides 可能生成易爆的过氧化物质
- R37/38 Irritating to respiratory system and skin 对呼吸系统和皮肤有刺激性
- R14/15 Reacts violently with water, liberating extremely flammable gases 遇水剧烈反应，释放出高度可燃气体
- R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- R66 Repeated exposure may cause skin dryness or cracking 反复接触可能导致皮肤干燥或皴裂
- R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
其他信息
- 灭火剂:干粉、二氧化碳、泡沫、1211灭火剂
- F:1-10-13-34
- Alfa Aesar:四氢呋喃硼烷,1M在四氢呋喃溶剂中,在氩气保护下储存在ChemSeal密封瓶中密封 Borane-tetrahydrofuran complex, 1M soln. in THF, packaged under Argon in resealable ChemSeal™ bottles(14044-65-6)
- 爆炸物危险特性:一般使用其溶液; 纯物品不稳定; 其四氢呋喃溶液室温不稳定可爆炸
- MOL 文件:14044-65-6.mol
- 可燃性危险特性:受热分解排出辛辣刺激烟雾
- 下游产品:1-(4-(吡咯烷-1-基)丁基)肼 --> 6-溴-1,2,3,4-四氢异喹啉 --> 1-(4-吗啉基丁基)肼 --> 1-(3-(吡咯烷-1-基)丙基)肼 --> 1-甲基-3-苯基哌嗪 --> 儿萘酚硼烷
- 储运特性:库房通风低温
- Acros Organics:硼烷四氢呋喃溶液 Borane-tetrahydrofuran complex, 1M solution in THF, Stabilized, AcroSeal?(14044-65-6)
- Sigma Aldrich:14044-65-6(sigmaaldrich)
- 用途一:蒎烯的配套产品，用于原料药孟鲁司特钠、恩替卡韦的生产。
- 存储注意事项:氮气保护
- TCI Shanghai:四氢呋喃硼烷(8.5%的四氢呋喃溶液,约0.9Mol/L)(含稳定剂硼氢化钠) Borane - Tetrahydrofuran Complex (8.5% in Tetrahydrofuran, ca. 0.9mol/L) (stabilized with Sodium Borohydride)(14044-65-6)
- 和水剧烈反应。对空气和湿度敏感。
- 图谱信息:硼烷四氢呋喃络合物(14044-65-6)红外图谱(IR1)
- 敏感性:Air & Moisture Sensitive
- 类别:爆炸物品
- 硼烷四氢呋喃络合物价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 A17619201 硼烷四氢呋喃溶液(+4℃) 100ml 541元 2011/04/16 T2346 硼烷-四氢呋喃络合物(8.5%的四氢呋喃溶液, 约0.9mol/L)(含稳定剂硼氢化钠) Borane - Tetrahydrofuran Complex (8.5% in Tetrahydrofuran, ca. 0.9mol/L) (stabilized with Sodium Borohydride) 500ML 2150元 2011/04/16 T2346 硼烷-四氢呋喃络合物(8.5%的四氢呋喃溶液, 约0.9mol/L)(含稳定剂硼氢化钠) Borane - Tetrahydrofuran Complex (8.5% in Tetrahydrofuran, ca. 0.9mol/L) (stabilized with Sodium Borohydride) 100ML 760元
