Diethyl ether 乙醚

CAS 60-29-7 MFCD00011646

化学结构图

60-29-7
SMILES: CCOCC

化学属性

Mol. Formula(CH3CH2)2O
Mol. Weight74.12
Refractive indexn20/D 1.3530(lit.)
Boiling Point34.6 °C(lit.)
Density0.706 g/mL at 25 °C(lit.)
Melting Point-116 °C(lit.)
Flash Point-45 ºC
TSCAYes
Solubility69 G/L (20 ºC)
Autoignition Point320 °F
Vapor Density2.6 (vs air)
Vapor Pressure28.66 psi ( 55 °C)
Danger-Level-
pH-:-
Redox-

别名和识别编码

Chemical NameDiethyl ether
Synonym Anaesthetic ether Diethyl ether Aether Anesthesia ether Solvent ether Oxyde d'ethyle 二乙醚 醚,二乙醚,乙氧基乙烷 Ethoxyethane Ether RCRA waste number U117 乙醚 Etere etilico 乙基醚 乙醚 Dwuetylowy eter Diaethylaether Ethyl ether Diethyl oxide Anesthetic ether Ether ethylique
CAS Number60-29-7
PubChem Substance ID3283
EC Number200-467-2
Beilstein Registry Number1696894
MDL NumberMFCD00011646
Merck Number14,3806
Chemical Name Translation乙醚
Wiswesser Line Notation2O2
InChIInChI=1S/C4H10O/c1-3-5-4-2/h3-4H2,1-2H3
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分类

  • 3-MCPD, Acrylamide, Adulterants, Allergens, Analytical Reagents, Analytical/Chromatography, Applications, Benzene, Beverages, Bisphenol A (BPA), BADGE, BFDGE, and NOGE, Chromatography Reagents & Solvents, Derivatization of Fatty Acids to FAMEs, Diethyl Ether, Dioxins/Furans/PCBs, Disinfection Product Residues and Solvents, Edible Oils, Essential Oils, FAMEs by Boiling Point Elution, FAMEs by Degree of Unsaturation, Fats (fatty acids, FAMEs, glycerides), Edible Oils, Sterols, Flavors & Fragrances, Food & Beverage Analysis,
  • {SNA} Anhydrous, Anhydrous Solvents, Diethyl Ether,

产品应用

  • 农药残留分析,有机机的溶剂,有机合成,浸出剂,微量分析试剂,分析磷,清洗剂,麻醉剂测尿17酮,油脂、树脂、蜡、硝化纤维素、芳香油、生物碱等的萃取剂。

相关文献及参考

  • Merck: 14,3806 Beilstein: 1,IV,1314

安全信息

GHS Symbol
WGK Germany1
Hazard Codes F+,Xn F+;Xn
Hazard statements
  • H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕
  • H224 Extremely flammable liquid and vapour 极端易燃液体和蒸气
  • H302 Harmful if swallowed 吞食有害
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US)
RTECSKI5775000
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
Signal word Danger
UN Number UN1155 1155
Risk Statements
  • R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
  • R66 Repeated exposure may cause skin dryness or cracking 反复接触可能导致皮肤干燥或皴裂
  • R12 Extremely flammable 极端易燃
  • R22 Harmful if swallowed 吞咽有害
  • R19 May form explosive peroxides 可能生成易爆的过氧化物质
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所;
  • S29 Do not empty into drains 不要排入下水道;
  • S33 Take precautionary measures against static discharges 对静电采取预防措施;
Packing GroupI
Storage condition 密封阴凉保存。
Restrict 易制毒
Warnings 危化品目录(2015) 危险化学品
TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 8 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   HBAMAK "Abdernalden's Handbuch der Biologischen Arbeitsmethoden." (Leipzig,
   Ger. Dem. Rep.)  Volume(issue)/page/year: 4,1295,1935

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 996 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JPMSAE Journal of Pharmaceutical Sciences.  (American Pharmaceutical Assoc.,
   2215 Constitution Ave., NW, Washington, DC 20037)  V.50-    1961-
   Volume(issue)/page/year: 67,566,1978

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 2420 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   PWPSA8 Proceedings of the Western Pharmacology Society.  (Univ. of
   California Dept. of Pharmacology, Los Angeles, CA 90024)  V.1-    1958-
   Volume(issue)/page/ye

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - m

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Amphibian - frog
DOSE/DURATION           : 24 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   HBAMAK "Abdernalden's Handbuch der Biologischen Arbeitsmethoden." (Leipzig,
   Ger. Dem. Rep.)  Volume(issue)/page/year: 4,1295,1935

{hazard_com}

TYPE OF TEST            : Mutation test systems - not otherwise specified
TEST SYSTEM             : Rodent - hamster Fibroblast
DOSE/DURATION           : 1 pph
REFERENCE :
   ANESAV Anesthesiology.  (Lippincott/Harper, Journal Fulfillment Dept., 2350
   Virginia Ave., Hagerstown, MD 21740)  V.1-    1940- Volume(issue)/page/year:
   43,21,1975

TYPE OF TEST            : DNA repair
TEST SYSTEM             : Bacteria - Escherichia coli
DOSE/DURATION           : 35670 ug/well/16H
REFERENCE :
   CBINA8 Chemico-Biological Interactions.  (Elsevier Scientific Pub. Ireland
   Ltd., POB 85, Limerick, Ireland)  V.1-    1969-  Volume(issue)/page/year:
   15,219,1976

TYPE OF TEST            : DNA inhibition
TEST SYSTEM             : Rodent - mouse Embryo
DOSE/DURATION           : 2850 mg/L
REFERENCE :
   JJATDK JAT, Journal of Applied Toxicology.  (John Wiley & Sons Ltd., Baffins
   Lane, Chichester, W. Sussex PO19 1UD, UK)  V.1-    1981-
   Volume(issue)/page/year: 5,1,1985

其他信息

  • 有特殊刺激气味,带甜味,极易挥发,易燃烧,其蒸气重于空气,能溶于乙醇、苯、氯仿、石油醚和油类,微溶于水。易燃。低毒,半数致死量(大鼠,经口)1700mg/kg。有麻醉性。

系列性分类


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