Allyltributyltin 烯丙基三丁基锡
CAS 24850-33-7 MFCD00010346
化学结构图
SMILES: CCCC[Sn](CC=C)(CCCC)CCCC
化学属性
| Mol. Formula | C15H32Sn |
|---|---|
| Mol. Weight | 331 |
| Refractive index | n20/D 1.486(lit.) |
| Boiling Point | 88-92 °C/0.2 mmHg(lit.) |
| Density | 1.068 g/mL at 25 °C(lit.) |
| Flash Point | 103°(217°F) |
| TSCA | No |
| Stability | 对空气敏感 |
别名和识别编码
| Chemical Name | Allyltributyltin |
|---|---|
| CAS Number | 24850-33-7 |
| Alfabeta Name | ALLYLTRIBUTYLSTANNANE |
| MDL Number | MFCD00010346 |
| PubChem Substance ID | 24856436 |
| EC Number | 246-494-3 |
| Beilstein Registry Number | 3588340 |
| Synonym | 烯丙基三丁基锡 Allyltri-n-butyltin Allyltributyltin Tributyl-2-propenylstannane |
| Chemical Name Translation | 烯丙基三丁基锡 |
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分类
- {SNA} Chemical Synthesis, Organometallic Reagents, Organotin, Organotins
相关文献及参考
- Lewis acid-catalyzed stereoselective addition to aldehydes gives homoallylic alcohols: Chem. Lett., 919 (1979); Tetrahedron Lett., 25, 265, 1879 (1984); Synlett, 1694 (2002). For chemoselective allylation of aldehydes in the presence of ketones, see: Tetrahedron Lett., 36, 3723 (1995). In the presence of TI(O-i-Pr)4 and BINOL, enantioselective allylation of ketones can be accomplished with high ee: Tetrahedron: Asym., 11, 4163 (2000).
- Widely used nucleophilic, non-basic allylating agent.
- Couples with primary or secondary alkyl halides under free-radical conditions: J. Am. Chem. Soc., 104, 5829 (1982); Bull. Chem. Soc. Jpn., 56, 24801 (1983).
- Similarly, homoallylamines are formed from aldimines with TiCl4 or BF3 etherate: J. Org. Chem., 50, 146 (1985). For allylation of quinones, see p-Benzoquinone, A13162.
安全信息
GHS Symbol
- H315 Causes skin irritation 会刺激皮肤
- H301 Toxic if swallowed 吞食有毒
- H312 Harmful in contact with skin 皮肤接触有害
- H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
- H319 Causes serious eye irritation 严重刺激眼睛
- H372 Causes damage to organs through prolonged or repeated exposure 长期或频繁接触会损伤器官
- P273 Avoid release to the environment. 避免释放到环境中。
- P301+P310
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P305+P351+P338
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医，如果你觉得不舒服
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P301+P310+P330
- P302+P352+P312
- R25 Toxic if swallowed 吞咽有毒
- R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
- R21 Harmful in contact with skin 与皮肤接触有害
- R48/23/25
- R50/53
- S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
- S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- S35 This material and its container must be disposed of in a safe way 该物料及其容器必须以安全方式处置；
