2,4-Difluorobenzaldehyde 2,4-二氟苯甲醛

CAS 1550-35-2 MFCD00010326

化学结构图

1550-35-2
SMILES: O=Cc1ccc(F)cc1F

化学属性

Mol. FormulaC7H4F2O
Mol. Weight142.10
Boiling Point168.6°C at 760 mmHg
Melting Point2-3°C
Density1.299
Refractive index1.4970 to 1.5010
Flash Point55°C
TSCANo
Stability对空气敏感
Appearance 无色透明液体

别名和识别编码

Chemical Name2,4-Difluorobenzaldehyde
CAS Number1550-35-2
Alfabeta NameDIFLUOROBENZALDEHYDE 24-,
MDL NumberMFCD00010326
EC Number216-287-2
Beilstein Registry Number7(4)560
PubChem Substance ID87569225
Synonym 2,4-Difluorobenzaldehyde {LY} 2,4-Difluorobenzaldehyde {} {LY} 2,4-Difluorobenzaldehyde {} {} {LY} 2,4-Difluorobenzaldehyde {} {} {} {LY} 2,4-Difluorobenzaldehyde {} {} {} {} {LY} 2,4-Difluorobenzaldehyde {} {} {} {} {} {LY} 2,4-Difluorobenzaldehyde {} {} {} {} {} {} {LY} 2,4-Difluorobenzaldehyde {} {} {} {} {} {} {} {LY} 2,4-Difluorobenzaldehyde {} {} {} {} {} {} {} {} {LY} 2,4-Difluorobenzaldehyde {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {LY} 2,4-Difluorobenzaldehyde {} {} {} {} {} {} {} {} {} {} {LY} 2,4-Difluorobenzaldehyde {} {} {} {} {} {} {} {} {} {} {} {LY} 2,4-Difluorobenzaldehyde {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,4-Difluorobenzaldehyde {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,4-Difluorobenzaldehyde {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,4-Difluorobenzaldehyde {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,4-Difluorobenzaldehyde {} {} {} {} {} {} {} {} {} {} {} {} {}
Reaxys-RN2243422
Chemical Name Translation2,4-二氟苯甲醛
LabNetwork Molecule IDLN00115673
InChIKeyWCGPCBACLBHDCI-UHFFFAOYSA-N
Canonical SMILESFC1=CC(F)=C(C=O)C=C1
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分类

  • {SNA} Aldehydes, Aryl Fluorinated Building Blocks, Building Blocks, C7, Carbonyl Compounds, Chemical Synthesis, Fluorinated Building Blocks, Organic Building Blocks, Organic Fluorinated Building Blocks, Other Fluorinated Organic Building Blocks

相关文献及参考

  • Regioselective nucleophilic displacement of the 2-fluoro substituent with benzyl mercaptide has been utilized in a synthesis of 1,2-benzisothiazole: Tetrahedron Lett., 34, 6525 (1993). For reaction scheme, compare 2',4'-Difluoroacetophenone, A13420.

安全信息

Warnings IRRITANT, FLAMMABLE
Signal word Warning
GHS Symbol
WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R10 Flammable 易燃
Precautionary statements
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P302+P352+P332+P313+P362+P364
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P305+P351+P338+P337+P313
  • P241+P242+P243
  • P403+P235
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Packing GroupIII
UN Number 1989
Storage condition 2-8°C, stored under nitrogen {LY} 2-8°C, stored under nitrogen Air Sensitive Flammables area {} {LY} 2-8°C, stored under nitrogen {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under
Hazard Codes 3
Hazard Class3

其他信息

  • 用途一:医药、农药、液晶材料中间体。
  • 敏感性:Air Sensitive
  • MSDS 信息:2,4-Difluorobenzaldehyde(1550-35-2).msds
  • TCI Shanghai:2,4-二氟苯甲醛 2,4-Difluorobenzaldehyde(1550-35-2)
  • 2,4-二氟苯甲醛价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 D2839 2,4-二氟苯甲醛 2,4-Difluorobenzaldehyde 5G 540元 2014/06/02 D2839 2,4-二氟苯甲醛 2,4-Difluorobenzaldehyde 25G 1520元 2010/06/21 271470050 2,4-二氟苯甲醛 2,4-Difluorobenzaldehyde 98% 5 GR 589元
  • F:10-23
  • Hazard Note:Irritant
  • MOL 文件:1550-35-2.mol
  • Alfa Aesar:2,4-二氟苯甲醛,98% 2,4-Difluorobenzaldehyde, 98%(1550-35-2)
  • Acros Organics:2,4-二氟苯甲醛 2,4-Difluorobenzaldehyde, 98%(1550-35-2)
  • Sigma Aldrich:1550-35-2(sigmaaldrich)

系列性分类


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