Triethylphosphine 三乙基膦

CAS 554-70-1 MFCD00009256

化学结构图

554-70-1
SMILES: CCP(CC)CC

化学属性

Mol. Formula(C2H5)3P
Mol. Weight118.16
Refractive indexn20/D 1.430
Boiling Point127-128°C
Density0.869 g/mL at 25 °C
TSCAYes
Flash Point1 ºF
Stability对空气和湿度敏感
Appearance colorless liq.

别名和识别编码

Chemical NameTriethylphosphine
Synonym TRIETHYL PHOSPHINE (CYTOP 320) CYTEC QUALITY {uni_hamburg} TRIETHYLPHOSPHINE SOLUTION, ~70% IN ISO- PROPANOL CYTOP(R) 320 triethyl-phosphine tl409 TriethylphosphineSureSealbottlecolorlessliq PEt3 Triethylphophine triethyl-phosphin Triethylphosphorus AURORA KA-1111 TRIETHYLPHOSPHINE (C2H5)3P Triethylphosphine solution Triethylphosphineinethanol triethyl phosphite 三乙膦 triethylphosphane 三乙基膦 溶液 Triethyl phosphine 三乙基磷 triethyl phosphine vial with 10 G 三乙基磷化氫 三乙基瞵 TRIETHYLPHOSPHINE SOLUTION, ~1 M IN THF PEt3 Triethylphosphorous solution Triethylphosphorous solution Phosphorus triethyl Phosphine, triethyl- Triethylphosphineredistilled 三乙基膦 TL 409 Triethylphosphine TRIETHYLPHOSPHINE, 1.0M SOLUTION IN TETR AHYDROFURAN Triethyl-phosphane
MDL NumberMFCD00009256
CAS Number554-70-1
PubChem Substance ID27365
EC Number209-068-8
Beilstein Registry Number969170
Merck Number14,9675
Chemical Name Translation三乙基膦
LabNetwork Molecule IDLN00223032
InChIInChI=1S/C6H15P/c1-4-7(5-2)6-3/h4-6H2,1-3H3
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分类

  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Phosphine Compounds, Phosphine Ligands
  • {uni_hamburg} no charge; 1fragment

相关文献及参考

  • Short: III/35C4
  • Merck:14,9675
  • Merck:14,9675 Beilstein: 4,IV,3431
  • Short: III/35A

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H302 Harmful if swallowed 吞食有害
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H351 Suspected of causing cancer 怀疑致癌
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H250 Catches fire spontaneously if exposed to air 暴露于空气自发着火
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSSZ3400000
Precautionary statements
  • P222 Do not allow contact with air. 不要与空气接触。
  • P422 Store contents under… 存储目录在…之下。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P231 Handle under inert gas. 在惰性气体中操作。
  • P370+P378
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
Signal word Danger
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S33 Take precautionary measures against static discharges 对静电采取预防措施;
  • S7/9 Keep container tightly closed and in a well-ventilated place 保持容器严格密闭,置于通风良好的场所;
Packing GroupI
UN Number UN2845 UN 2924 3/PG 2 2845
Risk Statements
  • R20 Harmful by inhalation 吸入有害
  • R17 Spontaneously flammable in air 在空气中能够自燃
  • R11 Highly flammable 非常易燃
  • R34 Causes burns 会导致灼伤
  • R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
  • R19 May form explosive peroxides 可能生成易爆的过氧化物质
  • R37 Irritating to respiratory system 刺激呼吸道
  • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
Storage condition 对空气和潮湿敏感 Air & Moisture Sensitive 储存温度2-8℃,充氩保存
Hazard Codes F,C F;C
Hazard Class4.2
TYPE OF TEST            : LC - Lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : >1 gm/m3/10M
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NDRC** National Defense Research Committee, Office of Scientific Research
   and Development, Progress Report.  Volume(issue)/page/year:
   NDCrc-132,DEC1942

Restrict 危险品

其他信息

  • MOL 文件:554-70-1.mol
  • Sigma Aldrich:554-70-1(sigmaaldrich)
  • MSDS 信息:Triethylphosphine(554-70-1).msds
  • F:10-13-23
  • 下游产品:醋硫葡金
  • 敏感性:Air & Moisture Sensitive
  • Alfa Aesar:三乙基膦,97% Triethylphosphine, 97%(554-70-1)

系列性分类


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