CAS 5717-37-3 MFCD00009160-Ethyl 2-(triphenylphosphoranylidene)propionate 乙氧甲酰基亚乙基三苯基膦 TAO{mole}

Ethyl 2-(triphenylphosphoranylidene)propionate 乙氧甲酰基亚乙基三苯基膦

CAS 5717-37-3 MFCD00009160

化学结构图

SMILES: CCOC(=O)C(C)=P(c1ccccc1)(c1ccccc1)c1ccccc1

化学属性

Mol. Formula	C23H23O2P
Mol. Weight	362.40
Melting Point	154-160°C
TSCA	No
Density	1.14
Stability	对空气敏感
Boiling Point	497.2°C at 760 mmHg

别名和识别编码

Chemical Name	(1-Ethoxycarbonylethylidene)Triphenylphosphorane
CAS Number	5717-37-3
Alfabeta Name	ETHYLTRIPHENYLPHOSPHORANYLIDENEPROPANOATE 2()-
MDL Number	MFCD00009160
Synonym	Ethyl 2-(triphenylphosphoranylidene)propionate {LY} Ethyl 2-(triphenylphosphoranylidene)propionate {} {LY} Ethyl 2-(triphenylphosphoranylidene)propionate {} {} {LY} Ethyl 2-(triphenylphosphoranylidene)propionate {} {} {} {LY} Ethyl 2-(triphenylphosphoranylidene)propionate {} {} {} {} {LY} Ethyl 2-(triphenylphosphoranylidene)propionate {} {} {} {} {} {LY} Ethyl 2-(triphenylphosphoranylidene)propionate {} {} {} {} {} {} { {} {} {} {} {} {} {LY} Ethyl 2-(triphenylphosphoranylidene)propionate {} {} {} {} {} {} {} {LY} Ethyl 2-(triphenylphosphoranylidene)propionate {} {} {} {} {} {} {} {} {LY} Ethyl 2-(triphenylphosphoranylidene)propionate {} {} {} {} {} {} {} {} {} {LY} Ethyl 2-(triphenylphosphoranylidene)propionate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {LY} Ethyl 2-(triphenylphosphoranylidene)propionate {} {} {} {} {} {} {} {} {} {} {} {LY} Ethyl 2-(triphenylphosphoranylidene)propionate {} {} {} {} {} {} {} {} {}
PubChem Substance ID	79792
EC Number	227-215-4
Reaxys-RN	757112
Beilstein Registry Number	16(4)977
Chemical Name Translation	乙氧甲酰基亚乙基三苯基膦
InChIKey	KZENFXVDPUMQOE-UHFFFAOYSA-N
LabNetwork Molecule ID	LN00173624
InChI	InChI=1S/C23H23O2P/c1-3-25-23(24)19(2)26(20-13-7-4-8-14-20,21-15-9-5-10-16-21)22-17-11-6-12-18-22/h4-18H,3H2,1-2H3
Canonical SMILES	O=C(C(C)=P(C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3)OCC

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安全信息

Warnings IRRITANT

WGK Germany3

Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter

Storage condition 2-8°C, stored under nitrogen {LY} 2-8°C, stored under nitrogen <0°C Air Sensitive {} {LY} 2-8°C, stored under nitrogen {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY

Hazard Codes T

Safety Statements

S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；

Risk Statements

R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
R25 Toxic if swallowed 吞咽有毒

GHS Symbol

Hazard statements

H302 Harmful if swallowed 吞食有害
H312 Harmful in contact with skin 皮肤接触有害
H315 Causes skin irritation 会刺激皮肤
H319 Causes serious eye irritation 严重刺激眼睛
H332 Harmful if inhaled 吸入有害
H335 May cause respiratory irritation 可能导致呼吸道刺激
H413 Maycauselonglastingharmfuleffectstoaquaticlife 可能对水生生物造成长期持续有害影响。

Precautionary statements

P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P264+P265
P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
P273 Avoid release to the environment. 避免释放到环境中。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P301+P312
P301+P317
P302+P352
P304+P312
P304+P340
P305+P351+P338
P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
P317
P319
P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
P322 Specific measures (see …on this label). 具体治疗（见本标签上的）。
P330 Rinse mouth. 漱口
P332+P313
P332+P317
P337+P313
P337+P317
P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
P362+P364
P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
P403+P233
P405 Store locked up. 上锁保管。
P501 Dispose of contents/container to..… 处理内容物/容器.....

其他信息

Acros Organics:乙氧甲酰亚乙基三苯基膦 (Carbethoxyethylidene)triphenylphosphorane, balance TPPO, ca. 94%(5717-37-3)
MSDS 信息:(Carbethoxyethylidene)triphenylphosphorane(5717-37-3).msds
敏感性:Air Sensitive
乙氧甲酰基亚乙基三苯基膦价格(试剂级):更新日期产品编号产品名称包装价格 2011/04/16 C1641 2-(三苯基膦烯)丙酸乙酯 Ethyl 2-(Triphenylphosphoranylidene)propionate 5G 630元 2010/06/21 146080250 乙氧甲酰基亚乙基三苯基膦 (Carbethoxyethylidene)triphenylphosphorane ca. 94%, balance TPPO 25 GR 1954元 2010/06/21 146080050 乙氧甲酰基亚乙基三苯基膦 (Carbethoxyethylidene)triphenylphosphorane ca. 94%, balance TPPO 5 GR 590元
Alfa Aesar:(1-乙氧基羰基乙基叶立德)三苯基磷,97% (1-Ethoxycarbonylethylidene)triphenylphosphorane, 97%(5717-37-3)
Sigma Aldrich:5717-37-3(sigmaaldrich)
乙氧甲酰基亚乙基三苯基膦价格(试剂级):更新日期产品编号产品名称包装价格 2014/06/02 C1641 2-(三苯基膦烯)丙酸乙酯 Ethyl 2-(Triphenylphosphoranylidene)propionate 5G 500元 2010/06/21 146080250 乙氧甲酰基亚乙基三苯基膦 (Carbethoxyethylidene)triphenylphosphorane ca. 94%, balance TPPO 25 GR 1954元 2010/06/21 146080050 乙氧甲酰基亚乙基三苯基膦 (Carbethoxyethylidene)triphenylphosphorane ca. 94%, balance TPPO 5 GR 590元
用途一:是Wittig反应中的一种反应试剂，该反应是Wittig试剂与醛、酮的羰基发生亲核加成反应，形成烯烃或含双键的酯。
MOL 文件:5717-37-3.mol