1,2:5,6-Bis-O-(1-Methylethylidene)-D-Mannitol 双丙酮-D-甘露糖醇
CAS 1707-77-3 MFCD00003211
化学结构图
SMILES: CC1(C)OC[C@H]([C@@H](O)[C@H](O)[C@H]2COC(C)(C)O2)O1
化学属性
| Mol. Formula | C12H22O6 |
|---|---|
| Mol. Weight | 262.30 |
| Melting Point | 120-122°C |
| TSCA | No |
| Density | 1.175 |
| Solubility | methanol: 100 mg/mL, clear, colorless |
| Refractive index | 6.5 ° (C=8, CHCl3) |
| Boiling Point | 382°C at 760 mmHg |
别名和识别编码
| Chemical Name | 1,2:5,6-Bis-O-(1-Methylethylidene)-D-Mannitol |
|---|---|
| CAS Number | 1707-77-3 |
| Alfabeta Name | BISMETHYLETHYLIDENEMANNITOL :OD12561()------,, |
| MDL Number | MFCD00003211 |
| Synonym | Diacetone-D-mannitol, 97% {LY} Diacetone-D-mannitol, 97% {} {LY} Diacetone-D-mannitol, 97% {} {} {LY} Diacetone-D-mannitol, 97% {} {} {} {LY} Diacetone-D-mannitol, 97% {} {} {} {} {LY} Diacetone-D-mannitol, 97% {} {} {} {} {} {LY} Diacetone-D-mannitol, 97% {} {} {} {} {} {} {LY} Diacetone-D-mannitol, 97% {} {} {} {} {} {} {} {LY} Diacetone-D-mannitol, 97% {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Diacetone-D-mannitol, 97% {} {} {} {} {} {} {} {} {} {LY} Diacetone-D-mannitol, 97% {} {} {} {} {} {} {} {} {} {} {LY} Diacetone-D-mannitol, 97% {} {} {} {} {} {} {} {} {} {} {} {LY} Diacetone-D-mannitol, 97% {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Diacetone-D-mannitol, 97% {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Diacetone-D-mannitol, 97% {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Diacetone-D-mannitol, 97% {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Diacetone-D-mann |
| PubChem Substance ID | 96011 |
| Beilstein Registry Number | 83765 |
| EC Number | 216-954-8 |
| Reaxys-RN | 83765 |
| Chemical Name Translation | 双丙酮-D-甘露糖醇 |
| InChIKey | ODYBCPSCYHAGHA-ZYUZMQFOSA-N |
| LabNetwork Molecule ID | LN00011222 |
| Canonical SMILES | O[C@H]([C@]1([H])OC(C)(OC1)C)[C@@H]([C@]2([H])OC(C)(OC2)C)O |
| InChI | InChI=1S/C12H22O6/c1-11(2)15-5-7(17-11)9(13)10(14)8-6-16-12(3,4)18-8/h7-10,13-14H,5-6H2,1-4H3/t7-,8-,9-,10-/m1/s1 |
信息真实价格透明
资金保障
专业采购外包团队在线服务
信息真实价格透明
资金保障
专业采购外包团队在线服务
品牌质保精细包装
现货库存
一流品牌服务
分类
- Pharmaceuticals
- {SNA} Carbohydrate Chemistry, Carbohydrate Derivatives, Chemical Biology, Chemical Synthesis
- Chiral Reagents
- Intermediates & Fine Chemicals
产品应用
- Nebivolol intermediate.
相关文献及参考
- Beilstein:19(1)826
- Ono, Y., et al.: Steroids, 71, 529 (2006),
- Treatment with NaIO 4 affords the useful synthon 2,3-O-isopropylidene-D-glyceraldehyde (glyceraldehyde acetonide): J. Org. Chem., 56, 4056 (1991); Org. Synth. Coll., 9, 450 (1998). This in turn can be homologated diastereoselectively using 2-(Trimethylsilyl)thiazole, B21903: Org. Synth. Coll., 9, 52 (1998). For use of Pb(OAc) 4 in the formation of glyceraldehyde acetonide as a chiral precursor of cyclopropyl carbocyclic nucleosides as HIV reverse transcriptase inhibitors, see: J. Org. Chem., 60, 5236 (1995).
安全信息
GHS Symbol
- S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛，皮肤或衣服。
其他信息
- 比旋光度:6 ° (c=5, Chloroform)
- 双丙酮-D-甘露糖醇价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 D2024 1,2:5,6-二-O-亚异丙基-D-甘露醇 1,2:5,6-Di-O-isopropylidene-D-mannitol 5G 445元 2014/06/02 D2024 1,2:5,6-二-O-亚异丙基-D-甘露醇 1,2:5,6-Di-O-isopropylidene-D-mannitol 25G 1360元 2010/05/25 L12127 1，2，5，6-二邻异亚丙基-D-甘露醇 1,2:5,6-Di-O-isopropylidene-D-mannitol 5g 435元
- Alfa Aesar:1，2，5，6-二邻异亚丙基-D-甘露醇 1,2:5,6-Di-O-isopropylidene-D-mannitol(1707-77-3)
- 下游产品:(R)-(-)-甘油醇缩丙酮
- Sigma Aldrich:1707-77-3(sigmaaldrich)
- F:10-21
- MOL 文件:1707-77-3.mol
- TCI Shanghai:双丙酮-D-甘露糖醇 1,2:5,6-Di-O-isopropylidene-D-mannitol,>;95.0%(GC)(1707-77-3)
