CAS 96-33-3 MFCD00008627-Methyl acrylate 丙烯酸甲酯 TAO{mole}

Methyl acrylate 丙烯酸甲酯

CAS 96-33-3 MFCD00008627

化学结构图

SMILES: C=CC(=O)OC

化学属性

Mol. Formula	C4H6O2
Mol. Weight	86
Refractive index	1.4010 to 1.4040
Boiling Point	80
Density	0.956
Melting Point	-75
Flash Point	-1°C(lit.)
TSCA	Yes
Autoignition Point	874 °F
Vapor Density	3 (vs air)
Vapor Pressure	67.5 mmHg ( 20 °C)
Solubility	60 G/L (20 ºC)
Stability	对光敏感
Danger-Level	甲类
pH	:A

别名和识别编码

Chemical Name	Methyl acrylate
CAS Number	96-33-3
PubChem Substance ID	87561834
EC Number	202-500-6
Beilstein Registry Number	605396
MDL Number	MFCD00008627
Reaxys-RN	605396
Merck Number	6011
Synonym	2-Propensäuremethylester Propenoic acid methyl ester Methylacrylat Acrylsäure-methylester 2-Propenoic acid methyl ester METHYL ACRYLATE {Chemica 2-Propenoic acid, methyl ester 败脂酸甲酯,2-丙烯酸甲酯,丙烯酸甲酯浆料;异丁烯酸盐;甲基丙烯酸盐 methyl propenoate acrylic acid, methyl ester acrylatedemethyle Acrylsaeuremethylester Methylester kyseliny akrylove MA Methyl propenate METHYL 2-PROPENOATE Methacrylate Methyl 2-propenoate propenoic acid, methyl ester 丙烯酸甲酯（MA） acrylatedemethyle(french) 败脂酸甲酯 Methylprop-2-enoat Methyl-2-propenoat ACRYLIC ACID METHYL ESTER curithane103 丙烯酸甲酯 Methylacrylaat [sri773]methylacrylate,monomer methyl 2-propenoate Methyl propenoate 丙烯酸甲酯, 99%, STAB. WITH CA 15PPM 4-METHOXYPHENOL Acrylsäuremethylester 丙烯酸甲酯,异丁烯酸盐,甲基丙烯酸盐 AKOS BBS-00004387 Acrylic acid methyl ester Acrylate de methyle Methoxycarbonylethylene Methyl-acrylat Methyl-2-propenoate Methyl ester acrylic acid 2-Propenoicacidmethylesetr Metilacrilato Methyl acrylate 丙烯酸甲酯 METHYL ACRYLATE CH2=CHCOOCH3 2-PROPENOIC ACID METHYL ESTER 丙烯酸甲酯浆料 Curithane 103 prop-2-enoic acid methyl ester Methyl acrylate, inhibited 败脂酸甲酯,2-丙烯酸甲酯,丙烯酸甲酯浆料 Methyl prop-2-enoate METHYL PROPENOATE methyl acrylate Methyl acrylic ester
Chemical Name Translation	丙烯酸甲酯
Wiswesser Line Notation	1U1VO1
LabNetwork Molecule ID	LN00193624
InChI	InChI=1S/C4H6O2/c1-3-4(5)6-2/h3H,1H2,2H3

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产品应用

1 ．高分子聚合单体。
2 ．有机合成。供制作涂料、纺织、皮革、粘合剂等工业用的各种树脂。

安全信息

GHS Symbol

WGK Germany2

Hazard Codes 3

Hazard statements

H312+H332
H315 Causes skin irritation 会刺激皮肤
H317 May cause an allergic skin reaction 可能导致皮肤过敏
H301 Toxic if swallowed 吞食有毒
H335 May cause respiratory irritation 可能导致呼吸道刺激
H319 Causes serious eye irritation 严重刺激眼睛
H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
H332 Harmful if inhaled 吸入有害
H312 Harmful in contact with skin 皮肤接触有害
H412 Harmfutoaquaticlifewithlonglastingeffects 对水生生物有害并具有长期影响。
H302+H312
H331 Toxic if inhaled 吸入中毒

Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

RTECSAT2800000

Precautionary statements

P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
P233 Keep container tightly closed. ?保持容器密闭。
P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
P241+P242+P243
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
P273 Avoid release to the environment. 避免释放到环境中。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P301+P310
P301+P310+P330
P302+P352+P312+P362+P364
P303+P361+P353
P305+P351+P338
P305+P351+P338+P310
P305+P351+P338+P337+P313
P308+P311
P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
P370+P378
P403+P233
P501 Dispose of contents/container to..… 处理内容物/容器.....

Signal word Danger

Safety Statements

S25 Avoid contact with eyes 避免眼睛接触；
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S33 Take precautionary measures against static discharges 对静电采取预防措施；
S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用（指明具体的消防器材种类，如果用水增加危险，注明“禁止用水”
S9 Keep container in a well-ventilated place 保持容器在通风良好的场所；

Risk Statements

R11 Highly flammable 非常易燃
R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应

UN Number 1919

Packing GroupII

Storage condition Light Sensitive 密封阴凉避光保存。密封阴凉避光保存。储存温度2-8°C Refrigerator (+4°C) + Flammables area

Hazard Class3

Warnings 危化品目录(2015)

{h

TYPE OF TEST            : TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Human
DOSE/DURATION           : 75 ppm
TOXIC EFFECTS :
   Sense Organs and Special Senses (Olfaction) - effect, not otherwise
   specified
   Sense Organs and Special Senses (Eye) - effect, not otherwise specified
   Lungs, Thorax, or Respiration - other changes
REFERENCE :
   34ZIAG "Toxicology of Drugs and Chemicals," Deichmann, W.B., New York,
   Academic Press, Inc., 1969  Volume(issue)/page/year: -,75,1969

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 277 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AMPMAR Archives des Maladies Professionnelles de Medecine du Travail et de
   Securite Sociale.  (SPPIF, B.P.22, F-41353 Vineuil, France)  V.7-    1946-
   Volume(issue)/page/year: 36,58,1975

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 1243 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JIHTAB Journal of Industrial Hygiene and Toxicology.  (Cambridge, MA)
   V.18-31, 1936-49.  For publisher information, see AEHLAU.
   Volume(issue)/page/year: 30,63,1948

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 254 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JDREAF Journal of Dental Research.  (International Assoc. for Dental
   Research, 734 15th St., NW, Suite 809, Washington, DC 20005)  V.1-    1919

TYPE OF TEST            : Cytogenetic analysis
TEST SYSTEM             : Rodent - hamster Fibroblast
DOSE/DURATION           : 189 ppm
REFERENCE :
   ESKHA5 Eisei Shikenjo Hokoku.  Bulletin of the Institute of Hygienic
   Sciences.  (Kokuritsu Eisei Shikenjo Kagaku, 18-1 Bushitsu Johobu,
   Setagaya-ku, Tokyo 158, Japan)  V.1-    1886-  Volume(issue)/page/year:
   (102),77,1984

TYPE OF TEST            : Cytogenetic analysis
TEST SYSTEM             : Rodent - hamster Lung
DOSE/DURATION           : 6500 ug/L
REFERENCE :
   GMCRDC Gann Monograph on Cancer Research.  (Plenum Pub. Corp., 233 Spring
   St., New York, NY 10013) No. 11-    1971-  Volume(issue)/page/year:
   27,95,1981

TYPE OF TEST            : Micronucleus test
ROUTE OF EXPOSURE       : Intraperitoneal
TEST SYSTEM             : Rodent - mouse
DOSE/DURATION           : 37500 ug/kg
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 135,189,1984

TYPE OF TEST            : Mutation in mammalian somatic cells
TEST SYSTEM             : Rodent - mouse Lymphocyte
DOSE/DURATION           : 14 mg/L
REFERENCE :
   EMMUEG Environmental and Molecular Mutagenesis.  (Alan R. Liss, Inc., 41 E.
   11th St., New York, NY 10003)  V.10-    1987-  Volume(issue)/page/year:
   11,49,1988

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Rodent - mouse Lymphocyte
DOSE/DURATION           : 22 mg/L
REFERENCE :
   ENMUDM Environmental Mutagenesis.  (New York, NY)  V.1-9, 1979-87.  For
   publisher information, see EMMUEG.  Volume(issue)/page/year: 8(Suppl
   6),4,1986

TYPE OF TEST            : Cytogenetic analysis
TEST SYSTEM             : Rodent - mouse Lymphocyte
DOSE/DURATION           : 22 mg/L
REFERENCE :
   ENMUDM Environmental Mutagenesis.  (New York, NY)  V.1-9, 1979-87.  For

Restrict 危险品

其他信息

{Chem
防护措施:丙烯酸甲酯毒性中等，对眼、皮肤、粘膜有较强的刺激和腐蚀作用，并可经皮肤吸收而引起中毒，大鼠经口LD50
毒性分级:中毒
图谱
下游产品:2-膦酸丁烷-1,2,4-三羧酸 --> 无纺布胶 --> BT型改性丙烯酸树脂涂饰剂系列 --> CSF系列改性丙烯酸树脂乳液 --> 1-甲基-4-哌啶酮盐酸盐 --> 防油、防水涂饰剂 --> 全候性系列树脂 --> AC防霉涂饰剂 --> 桃醛 --> 十四醛三聚物 --> 丙烯酸 2-乙基己酯 -->
职业标准:TWA 35 毫克/ 立方米
防护措施:丙烯酸甲酯毒性中等，对眼、皮肤、粘膜有较强的刺激和腐蚀作用，并可经皮肤吸收而引起中毒，大鼠经口LD50为300mg/kg。兔口服LD50为280mg/kg。慢性中毒症状为头痛、嗜睡、手脚痉挛等。工作场所最高容许浓度为35mg/m3。操作场所应加强通风。操作人员应佩戴胶手
灭火剂:干粉、干砂、二氧化碳、泡沫、1
图谱信息:丙烯酸甲
MSDS 信息:丙烯酸甲酯(96-33-3).msds
爆炸物危险特性:与空气混合可爆
灭火剂:干粉、干砂、二氧化碳、泡沫、1211灭火剂
图谱信息:丙烯酸甲酯(96-33-3)质谱(MS) 丙烯酸甲酯(96-33-3)红外图谱(IR1) 丙烯酸甲酯(96-33-3)核磁图( 13 CNMR) 丙烯酸甲酯(96-33-3)Raman光谱丙烯酸甲酯(96-33-3)核磁图( 1 HNMR)
{Chemi
Acros Organics:甲基丙烯酸酯 Methyl acrylate, stabilized, 99%(96-33-3)
蒸气密度:3 (vs air)
刺激数据:眼睛- 兔子 100 毫克重度; 皮肤- 兔子 10 毫克/ 24小时
Alfa Aesar:丙烯酸甲酯,99%,stab.withca15ppm4-methoxyphenol Methyl acrylate, 99%, stab. with ca 15ppm 4-methoxyphenol(96-33-3)
上游原料:甲醇 --> 马来酸酐 --> 环氧丙烷 --> 甘油 --> 丙烯酸 --> 卡波姆树脂 --> 丙烯酰胺 --> 蓖麻油 --> 丙烯醛 --> 苯甲酸 --> 丙
用途四:丙烯酸甲酯是有机合成中间体及合成高分子的单体，由丙烯酸甲酯合成共聚橡胶具有良好的耐高温及耐油性能。与丙烯腈共聚可改变聚丙烯腈纤维的可纺性、耐塑料及染色性。与甲基丙烯酸甲酯、乙酸乙烯或苯乙烯共聚是性能良好的涂料和地板上光剂。此外，在医药制造、皮革加工、造纸、粘合剂制造、油漆等工业中也有其日益广泛的用途。
上游原料:甲醇 --> 马来酸酐 --> 环氧丙烷 --> 甘油 --> 丙烯酸 --> 卡波姆树脂 --> 丙烯酰胺 --> 蓖麻油 --> 丙烯醛 --> 苯甲酸 --> 丙二醇 --> 植物油 --> 季戊四醇 --> 聚醚 --> 乙烯酮 --> 菜籽油
有辛辣气味，是一种催泪剂。易燃，微溶于水。水中溶解度在20℃时为6g/100ml；40℃时5克/100ml,水在丙烯甲酯中溶解度为1.8ml/100g。能溶于醇和醚。在贮存过程中易聚合，光、热和过氧化物能加速其聚合作用。纯粹的单体在低于10℃时不聚合。通常加入对苯二酚单甲醚0.1%作阻聚剂。易燃。中等毒，
有辛辣气味，是一种催泪剂。易燃，微溶于水。水中溶解度在20℃时为6g/100ml；40℃时5克/100ml,水在丙烯甲酯中溶解度为1.8ml/100g。能溶于醇和醚。在贮存过程中易聚合，光、热和过氧化物能加速其聚合作用。纯粹的单体在低于10℃时不聚合。通常加入对苯二酚单甲醚0.1%作阻聚剂。易燃。中等毒，半数致死量（大鼠，经口）0.3g/kg。有催泪性。对呼吸系统和皮肤有刺激性。易
用途三:主要用于涤/棉、涤/腈等混纺织物经纱上浆
蒸气压:67.5 mm Hg ( 20 °C)