CAS 111-26-2 MFCD00008240-Hexylamine 正己胺 TAO{mole}

Hexylamine 正己胺

CAS 111-26-2 MFCD00008240

化学结构图

SMILES: CCCCCCN

化学属性

Mol. Formula	C6H15N
Mol. Weight	101
Refractive index	1.4170 to 1.4200
Density	0.766 g/mL at 25 °C(lit.)
Boiling Point	130°C
Melting Point	-23 °C (lit.)
Flash Point	27°C(lit.)
TSCA	Yes
Solubility	微溶于水，可混溶于乙醇、乙醚。
Stability	对空气敏感

别名和识别编码

Chemical Name	Hexylamine
MDL Number	MFCD00008240
CAS Number	111-26-2
Synonym	HEXYLAMINE ENT 16554 NORMAL HEXYL AMINE 己胺/1-氨基己烷己胺 1-Hexanamine n-Hexylamine aminohexane hexylamine,[liquid] 1-Amine-n-hexane MONO-N-HEXYLAMINE 1-Hexylamine 正己胺 1-氨基己烷 ETHYL-N-BUTYLAMINE hexylamine 1-Aminohexane,1-Hexanamine 1-AMINOHEXANE RARECHEM AL BW 0240 Mono-n-hexylamine 正已胺 n-C6H13NH2 1-胺己烷 1-Aminohexan 1-Aminohexane 1-Hexanamin 1-HEXYLAMINE 1-氨基正己烷 AMINE C6 Hexylamin N-HEXYLAMINE n-Hexylamin n-Hexlamin ent16554
EC Number	203-851-8
Beilstein Registry Number	4,188
PubChem Substance ID	87570578
Chemical Name Translation	正己胺
Reaxys-RN	1731298
Wiswesser Line Notation	Z6
LabNetwork Molecule ID	LN00195679

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产品应用

用作有机合成中间体及生化试剂。

安全信息

GHS Symbol

WGK Germany1

Hazard statements

H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
H301+H311
H226 Flammable liquid and vapour 易燃液体和蒸气
H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。

Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

RTECSMQ4540000

Precautionary statements

P501 Dispose of contents/container to..… 处理内容物/容器.....
P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P301+P310
P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P305+P351+P338
P305+P351+P338+P310
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P273 Avoid release to the environment. 避免释放到环境中。
P303+P361+P353
P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
P370+P378

Signal word Danger

Packing GroupI

UN Number UN2734 2734 UN 2734 8/PG 1

Risk Statements

R35 Causes severe burns 会导致严重灼伤
R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
R10 Flammable 易燃
R21/22 Harmful in contact with skin and if swallowed 皮肤接触和不慎吞咽有害
R51/53

Safety Statements

S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；

Storage condition Flammables area 室温 Air Sensitive

Hazard Codes C C,F,Xi C,N

Hazard Class8/3

Warnings 危化品目录(2015) 危险化学品

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 420 uL/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine.
   (Chicago, IL)  V.2-10, 1950-54. For publisher information, see AEHLAU.
   Volume(issue)/page/year: 10,61,1954

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 670 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine.
   (Chicago, IL)  V.2-10, 1950-54. For publisher information, see AEHLAU.
   Volume(issue)/page/year: 10,61,1954

TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 500 ppm/4H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine.
   (Chicago, IL)  V.2-10, 1950-54. For publisher information, see AEHLAU.
   Volume(issue)/page/year: 10,61,1954

其他信息

Acros Organics:己胺/1-氨基己烷 Hexylamine, 99%(111-26-2)
毒性分级:中毒
上游原料:五氯化磷 --> 甲酮 --> 酮肟
方法一:由甲基正已基甲酮肟用五氯化磷处理而得。将甲基正已基甲酮肟于乙醚中用五氯化磷处理，然后加水搅匀后分层。重排生成的N-乙酰正乙胺溶在乙醚中，将乙醚层分出。蒸馏回收乙醚，剩余的油状液用氢氧化钾稀溶液水解，再进行蒸馏。收集130-133℃馏分即得己胺。
Hazard Note:Irritant/Flammable/Corrosive/Air Sensitive
灭火剂:干粉、干砂、二氧化碳、泡沫、1211灭火剂
海关编码:29211980
F:34
用途三:用作有机合成中间体及生化试剂。
类别:易燃液体
用途一:主要用于有机合成
MSDS 信息:正己胺(111-26-2).msds
敏感性:Air Sensitive
图谱信息:正己胺(111-26-2)红外图谱(IR1) 正己胺(111-26-2)质谱(MS) 正己胺(111-26-2)核磁图( 13 CNMR) 正己胺(111-26-2)核磁图( 1 HNMR) 正己胺(111-26-2)Raman光谱
Alfa Aesar:1-己基胺,99% 1-Hexylamine, 99%(111-26-2)
可燃性危险特性:遇明火、高温、氧化剂易燃; 燃烧产生有毒氮氧化物烟雾
Sigma Aldrich:111-26-2(sigmaaldrich)
用途二:用作有机合成中间体。
急性毒性:口服- 大鼠 LD50: 670 毫克/ 公斤
刺激数据:皮肤- 兔子 10 毫克/ 24小时重度; 眼睛- 兔子 2 毫克/ 24小时重度
TCI Shanghai:己胺 Hexylamine,>;99.0%(GC)(T)(111-26-2)
MOL 文件:111-26-2.mol
储运特性:库房通风低温干燥; 与氧化剂、酸类分开存放
外观性质:无色液体。
FEMA:4243
能与乙醇、乙醚混溶，微溶于水。有氨臭。水中溶解度:14 g/l (20°C)。
正己胺价格(试剂级):更新日期产品编号产品名称包装价格 2011/08/23 A21970302 正己胺 100ml 356元 2011/08/23 K5313101 正己胺purum》98.0％ 250ml 551元 2011/04/16 H0134 己胺 Hexylamine 25ML 177元
下游产品:异氰酸己酯