3-(Dimethylamino)-1-propylamine 3-(二甲氨基)-1-丙胺
CAS 109-55-7 MFCD00008216
化学结构图
SMILES: CN(C)CCCN
化学属性
| Mol. Formula | C5H14N2 |
|---|---|
| Mol. Weight | 102.18 |
| Refractive index | 1.4330 to 1.4370 |
| Boiling Point | 136°C |
| Density | 0.812 |
| Flash Point | 38°C(lit.) |
| TSCA | Yes |
| Melting Point | -60°C |
| Vapor Density | 3.6 (vs air) |
| Vapor Pressure | 5 mmHg ( 20 °C) |
| Solubility | 溶于水、多数有机溶剂。 |
| Stability | 对空气敏感 |
| pH | :A |
别名和识别编码
| Chemical Name | 3-(Dimethylamino)-1-propylamine |
|---|---|
| Synonym | 3-二甲氨基-1-丙胺 N,N-Dimethyltrimethylenediamine 3-(dimethylamino)-n-propylamine N,N- N,N-dimethyl-1,3-propanediamine { 3-(Dimethylamino)-1-propylamine Propylamine, 3-(N,N-dimethylamino)- 3-Amino-1-(dimethylamino)propa N,N-Dimethyl-1,3-propylenediamine 3-二甲氨基-１-丙胺 二甲基氨基丙胺 二甲基丙二胺 N,N-Dimethyltrimethylendiamin 1-dimethylamino-3-aminopropane 1,3-propanediamine, N,N-dimeth 1-氨基-3-(二甲氨基)丙烷 (3-Dimethylamino)propylamine RARECHEM AL BW 0072 N-(3-aminopropyl)dimethyl N,N-dimethylpropane-1,3-diamine 1- N,N-二甲基-1,3-二氨基丙烷 N,N-DIMETHYLTRIMETHYLENEDIAMINE 3-(Dimethylamino)propylamine 3-DIMETHYLAMINO-1-PROPYLAMINE 3-Amino-1-(dimethylamino)propane N,N-二甲基-1,3-丙二胺 N,N-二甲基-1,3-二氨基丙烷 N，N-二甲基-1，3-丙二胺 二甲氨基丙胺 N,N-DIMETHYL-1,3-PROPANEDIAMINE 3-aminopropyldimethylamine 3,3-dimethylaminopropylamine 3-Dimethylami 3-N,N-Dimethylaminopropylamine {u {C 1-Amino-3-(dimethylamino)propa N 二甲基-1,3-丙二胺 gamma-(Dimethylamino)propylamine 3-(Dimethylamino)propanamine 3-(N,N-dimethylamino)propylamine 3-二甲胺基丙胺 γ-Dimethylaminopropylamine 3-(Dimethylam {uni_ 3-二甲氨基丙胺 3-二甲胺基丙胺(DMAPA) 3-(dimethylamino)propylamine 二甲基-1,3-二氨基丙烷 N,N-Dimethyl-1,3-diaminopropane N,N-dimethyl-1,3-propandiami 3-Propanediamine,N,N-dimethyl-1 N,N-Dimethylpropylenediamine N,N-Dimethyl-1,3-propane dia |
| CAS Number | 109-55-7 |
| PubChem Substance ID | 7993 |
| EC Number | 203-680-9 |
| Beilstein Registry Number | 4(3)554 |
| MDL Number | MFCD00008216 |
| Reaxys-RN | 605293 |
| Chemical Name Translation | 3-(二甲氨基)-1-丙胺 |
| Wiswesser Line Notation | Z3N1&1 |
| LabNetwork Molecule ID | LN00222153 |
| InChI | InChI=1S/C5H14N2/c1-7(2)5-3-4-6/h3-6H2,1-2H3 |
信息真实价格透明
资金保障
专业采购外包团队在线服务
信息真实价格透明
资金保障
专业采购外包团队在线服务
品牌质保精细包装
现货库存
一流品牌服务
分类
- {SNA} Building Blocks, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks, Polyamines
- {Chemicalbook} 农药中间体: 杀菌剂中间体: 氨基甲酸酯类杀菌剂
- Building Blocks, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks, Polyamines
- {uni_hamburg} no charge; 1fragment
产品应用
- DMAPA is suitable reagent used in the following studies:The palladium-catalyzed amination of aryl amines;The derivatization of pullulan to form cationic pullulan;The parallel synthesis of alkylamine lipidoids;Tthe anomeric deacetylation of protected sugars.
相关文献及参考
- Beilstein:4(3)554
- Useful for cleavage of N-alkylphthalimide derivatives to give primary amines, as an alternative to the carcinogenic methylhydrazine: Org. Synth. Coll., 9, 13, 16 (1993).
- Short: IV/20C
- Short: EINECS
- Useful for cleavage of N-alkylphthalimide derivatives to give primary amines, as an alternative to the carcinogenic methylhydrazine: Org. Synth. Coll., 9, 13, 16 (1993).
- Short: IV/8A
安全信息
GHS Symbol
- H226 Flammable liquid and vapour 易燃液体和蒸气
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- H317 May cause an allergic skin reaction 可能导致皮肤过敏
- H302 Harmful if swallowed 吞食有害
- H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled 吸入可能导致过敏或哮喘症状或呼吸困难
- H311 Toxic in contact with skin 皮肤接触中毒
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338+P310
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P301+P330+P331+P310
- P303+P361+P353
- P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
- P304+P340
- R10 Flammable 易燃
- R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
- R22 Harmful if swallowed 吞咽有害
- R34 Causes burns 会导致灼伤
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- R21/22 Harmful in contact with skin and if swallowed 皮肤接触和不慎吞咽有害
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- S1/2 None 上锁保管并避免儿童触及；
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Administration onto the skin SPECIES OBSERVED : Rodent - rabbit DOSE/DURATION : 600 uL/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : UCDS** Union Carbide Data Sheet. (Union Carbide Corp., 39 Old Ridgebury Rd., Danbury, CT 06817) Volume(issue)/page/year: 12/15/1971
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 1870 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron, OH 44311) V.19- 1958- Volume(issue)/page/year: 23,95,1962
其他信息
- MOL 文件:109-55-7.mol
- 可燃性危险特性:易燃; 燃烧产生有毒氮氧化物烟雾
- 上游原料:氢 --> 二甲胺 --> 二甲氨基丙腈 --> 氢化催化剂
- {Chemica
- 用途二:N，
- 溶于水及大多数有机溶剂。
- 刺激数据:皮肤-兔子 0.1 毫克/24小时; 眼睛-兔子 5 毫克 中度
- 蒸气密度:3.6 (vs air)
- 下游产品:二甲基氨基丙基乙基碳酰胺 --> 1-(3-二甲基氨基丙基)-3-乙基碳二亚胺
- 凝固点:-70℃
- 方法一:其制备方法是在高压釜中投入β-二甲氨基丙腈溶液和氢化催化剂，通N 2 取代高压釜中的空气，取代合格后开动搅拌，在适宜的温度下通入氢气，釜压5.0 MPa，反应至釜压不降为反应终点，取样分析，冷却，然后该粗产品移入精馏釜进行减压精馏，先脱去溶剂，再收集73～75℃/9×10 3 Pa馏分为产品。反应方程式：(CH 3 ) 2 NCH 2 CH 2 CN+2H 2 [催化剂]→(CH 3 ) 2 NCH 2 CH 2 CH 2 NH 2
- 毒性分级:中毒
- 类别:易燃液体
- 蒸气压:5 mm Hg ( 20 °C)
- Alfa Aesar:N,N-二甲基-1,3-丙二胺,99% N,N-Dimethyl-1,3-propanediamine, 99%(109-55-7)
- 用途三:用作有机合成中间体，用来制取染料、离子交换树酯、环氧树脂固化剂、油料和无氰电镀锌添加剂、纤维及皮革处理剂和杀菌剂等。该品分子中既含有伯胺基，又有叔胺基，用作环氧树酯固化剂兼具固化剂和促进剂两种功能。主要用于层压品、浇铸品和粘合剂等，一般用量为2-6份。
- 图谱信息:N,N-二甲基-1,3-二氨基丙烷(109-55-7)Raman光谱 N,N-二甲基-1,3-二氨基丙烷(109-55-7)核磁图( 13 CNMR) N,N-二甲基-1,3-二氨基丙烷(109-55-7)红外图谱(IR1) N,N-二甲基-1,3-二氨基丙烷(109-55-7)质谱(MS) N,N-二甲基-1,3-二氨基丙烷(109-55-7)核磁图( 1 HNMR)
- TCI Shanghai:N,N-二甲基-1,3-丙二胺 N,N-Dimethyl-1,3-propanediamine,>;99.0%(GC)(109-55-7)
- 外观性质:无色液体,具有氨味。
- 储运特
- 存储注意事项:氮气保护
- DMAPA is a dialkylamino alkyl amine. DMAPA has been prepared from dimethylamine and acrylonitrile and confirmed by 1H NMR
- Sigma Aldrich:109-55-7(sigmaaldrich)
- 急性毒性:口服-大鼠 LD50: 1870 毫克/
- Acros Organics:N,N-二甲基-1,3-丙二胺 3-Dimethylaminopropylamine, 99%(109-55-7)
- N,N-二甲基-1,3-二氨基丙烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 K3938001 3-二甲氨基-1-丙胺purum≥98％ 250ml 220元 2011/04/16 D0790 N,N-二甲基-1,3-丙二胺 N,N-Dimethyl-1,3-propanediamine 25ML 131元 2011/04/16 D0790 N,N-二甲基-1,3-丙二胺 N,N-Dimethyl-1,3-propanediamine 500ML 291元
- 方法二:以二甲氨基丙腈[1738-25-6]为原料在Ni-Al催化剂存在下加氢、甲醇，然后经过滤、精馏，制得3-二甲氨基丙胺成品。所得产品纯度可达99%以上，每吨产品消耗二甲氨基丙腈1150kg。
