CAS 98-00-0 MFCD00003252-Furfuryl alcohol 糠醇 TAO{mole}

Furfuryl alcohol 糠醇

CAS 98-00-0 MFCD00003252

化学结构图

SMILES: OCC1CCCO1

化学属性

Mol. Formula	C5H6O2
Mol. Weight	98.10
Density	1.135
Refractive index	1.4850 to 1.4880
Boiling Point	170°C
Melting Point	-29
Flash Point	65°C
TSCA	Yes
Autoignition Point	915 °F
Vapor Density	3.4 (vs air)
Vapor Pressure	0.5 mmHg ( 20 °C)
Solubility	MISCIBLE
Stability	对光敏感

别名和识别编码

Chemical Name	Furfuryl alcohol
CAS Number	98-00-0
Synonym	2-Furfurylalcohol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
EC Number	202-626-1
Beilstein Registry Number	17,112
MDL Number	MFCD00003252
PubChem Substance ID	7361
Reaxys-RN	106291
Merck Number	4305
Chemical Name Translation	糠醇
Wiswesser Line Notation	T5OJ B1Q
LabNetwork Molecule ID	LN00194709
InChI	InChI=1S/C5H6O2/c6-4-5-2-1-3-7-5/h1-3,6H,4H2
Canonical SMILES	OCC1=CC=CO1

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分类

{Chemicalbook} 食品添加剂: 食用香料（增香剂）: 天然等同香料和人造香
{SNA} A-F, Alcohol, Alcoholic & Nonalcoholic Beverages, All Alphabetically Sorted, Alphabetical Index of Analytical Standards, Analytical Standards, Analytical/Chromatography, Beer, Chromatography, Coffee, F, FM - FZ, Flavors and Fragrances, Food & Beverage Standards, Food Products & Beverages, Herbs & Spices, Lavender, Potato Chips, Refined Food Products, Rice Cake, Substance Classification
{SNA} Alphabetical Listings, Certified Food Grade Products, E - H, E-F,
{SNA} Building Blocks,

产品应用

溶剂。有机合成(制造蒽、树脂等)。防腐剂。香料。

安全信息

Signal word

GHS Symbol

WGK Germany1

Safety Statements

Risk Statements

R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
R21/22 Harmful in contact with skin and if swallowed 皮肤接触和不慎吞咽有害
R48/20
R36/37 Irritating to eyes and respiratory system 对眼睛和呼吸系统有刺激性
R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
R23 Toxic by inhalation 吸入有毒
R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

Precautionary statements

P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P305+P351+P338
P308+P313
P332+P313
P501 Dispose of contents/container to..… 处理内容物/容器.....
P302+P350
P337+P313
P403+P233
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P284 Wear respiratory protection.? 佩戴呼吸保护装置。
P201 Obtain special instructions before use. 使用前获取专门指示。
P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P301+P310+P330
P304+P340+P310
P403+
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
P273 Avoid release to the environment. 避免释放到环境中。
P305+P351+P338+P337+P313
P302+P352+P312+P361+P364
P405 Store locked up. 上锁保管。

Hazard Codes T Xn

Hazard statements

H331 Toxic if inhaled 吸入中毒
H302 Harmful if swallowed 吞食有害
H312 Harmful in contact with skin 皮肤接触有害
H335 May cause respiratory irritation 可能导致呼吸道刺激
H351 Suspected of causing cancer 怀疑致癌
H319 Causes serious eye irritation 严重刺激眼睛
H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
H227 Combustible liquid 可燃液体
H302+H312

Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

RTECSLU9100000

UN Number 2874

Packing GroupIII

Hazard Class6.1

Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {

Warnings 危化品目录(2015)

TYPE OF TEST            : LCLo - Lowest

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Unreported
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 632 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 55(6),73,1990

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 400 mg/kg
TOXIC EFFECTS :
   Behavioral - convulsions or effect on seizure threshold
REFERENCE :
   34ZIAG "Toxicology of Drugs and Chemicals," Deichmann, W.B., New York,
   Academic Press, Inc., 1969  Volume(issue)/page/year: -,280,1969

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 233 ppm/4H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-  Volume(issue)/page/year:

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 177 mg/kg
TOXIC EFFECTS :
   Behavioral - excitement
   Behavioral - ataxia
   Lungs, Thorax, or Respiration - cyanosis
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 25(9),52,1981

TYPE OF TEST            : Cytogenetic analysis
TEST SYSTEM             : Rodent - hamster Ovary
DOSE/DURATION           : 2500 umol/L
REFERENCE :
   CALEDQ Cancer Letters (Shannon, Ireland).  (Elsevier Scientific Pub. Ireland
   Ltd., POB 85, Limerick, Ireland)  V.1-    1975- Volume(issue)/page/year:
   13,89,1981

TYPE OF TEST            : DNA repair
TEST SYSTEM             : Bacteria - Bacillus subtilis
DOSE/DURATION           : 2 mg/disc
REFERENCE :
   DFSCDX Developments in Food Science.  (Elsevier Science Pub. Co., Inc., 52
   Vanderbilt Ave., New York, NY 10017)  V.1-    1978- Volume(issue)/page/year:
   13,353,1986

Restrict 危险品

其他信息

Sigma Aldrich:98-00-0(sigmaaldrich)
图谱信息:糠醇(98-00-0)质谱(MS) 糠醇(98-00-0)核磁图( 1 HNMR) 糠醇(98-00-0)红外图谱(IR2) 糠醇(98-00-0)红外图谱(IR1) 糠醇(98-00-0)核磁图( 13 CNMR)
{Chem
用途二:是树脂、清漆、颜料的良好溶剂和火箭燃料，还可用于合成纤维、橡胶、农药及铸造行业
防护措施:易燃、有毒。家鼠经口LD50为275mg/kg。其蒸气经呼吸道吸入、液体经皮肤吸收均可引起中毒。生产设备应密闭，操作现场应通风良好，操作人员应穿戴防护用具，避免直接与人体接触，防止吸入或者吞入。
参考质量标准:FAO/WHO，1998 酸值(OT-4) ≤1.0 折射率(n D 20 ) 1.4868～1.4870 相对密度(d 20 20 ) 1.1351
灭火剂:泡沫、二氧化碳、干粉， 1211
用途一:用作合成各种呋喃型树脂的原料、防腐涂料，亦是良好的溶剂
Alfa Aesar:乙醇糠酯,98%min Fur
下游产品:2-甲基呋喃 --> 2-甲基-3-羟
TCI Shanghai:糠醇 Furfuryl Alcohol,>;97.0%(GC)(98-00-0)
食品添加剂最大允许使用量最大允许残留量标准:添加剂中文名称允许使用该种添加剂的食品中文名称添加剂功能最大允许使用量（g/kg）最大允许残留量（g/kg）糠醇食品食品用香料用于配制香精的各香料成分不得超过在GB 2760中的最大允许使用量和最大允许残留量
用途三:GB 2761--1997规定为允许使用的食品用香料。主要用于配制焦香型香精。 FDA，§175．105：规定为非直接食品添加剂(粘结剂)。
{Chemi
{Chemicalb
Acros Organics:糠醇(2-呋喃甲醇) Furfuryl alcohol, 99%(98-00-0)
可燃性危险特性:遇明火、高温、强氧化剂可燃; 燃烧排放刺激烟雾
上游原料:甲醇 --> 甲苯 --> 碳酸钠 --> 氯 --> 氢 --> 硫磺 --> 重铬酸钠 --> 乳化剂 --> 三甲胺 --> 糠醛 --> 硫代磷酰氯 --> 氧化铜 --> 氧化铅 --> 黄磷 --> 三氧化二铬 --> 催化剂 --> 重铬酸钠 --> 硝酸铜 --> 二甲基硫代磷酰氯 --> 铬酸铵 --> 硝酸铜 --> 硝酸铜
用途四:糠醇用于有机合成，经水解制得乙酰丙酸（果酸）是营养药物果糖酸钙的中间体。由糠醇可制得各种性能的呋喃型树脂（如糠醇树脂，呋喃Ⅰ或呋喃Ⅱ型树脂），糠醇-脲醛树脂及酚醛树脂等；由糠醇制得的增塑剂的耐寒性优于丁，辛醇酯类，又是呋喃树脂，清漆，颜料的良好溶剂和火箭燃料。此外还用于合成纤维，橡胶，农药和铸造工业等。该品易燃，有毒。小鼠口服LD50为275mg/kg。
蒸气密度:3.4 (vs air)
微有灼烧气味。味苦。暴露在空气和光的照射下即变成棕红色，对碱稳定。遇酸易树脂化，特别对强酸极其敏感，反应激烈时往往着火。具特殊苦辣气味。极易溶于乙醇和乙醚，能与水混溶，但水溶液不稳定。中等毒，半数致死量(大鼠，经口)275mg/kg。有刺激性。
急性毒性:口服- 大鼠 LD50: 177 毫克/ 公斤; 口服- 小鼠 LD50: 160 毫克/ 公斤
类别:易燃液体
MOL 文件:98-00-0.mol
方法一:由糠醛经加氢还原而得。工业上加氢还原有液相加氢和气相加氢两种工艺。液相加氢法又分高压法和中压法，高压法多在
用途五:溶剂。有机合成(制造蒽、树脂等)。防腐剂。香料。
常规方法:用清洁、干燥、有防腐层的铁桶包装。每桶200kg。贮存在阴凉、干燥、通风处，严禁火种，切忌与强酸性、强氧化性化学药品及食品共贮运，装卸运输均按易燃有毒品有关规定执行。