3-Fluoroaniline 3-氟苯胺

CAS 372-19-0 MFCD00007758

化学结构图

372-19-0
SMILES: Nc1cccc(F)c1

化学属性

Mol. FormulaC6H6FN
Mol. Weight111
Density1.156
Refractive index1.5440 to 1.5470
Flash Point77°C(lit.)
TSCANo
Boiling Point186
Solubility不溶
Melting Point-2°C
pH:A

别名和识别编码

Chemical Name3-Fluoroaniline
Synonym 1-Amino-3-fluorobenzene 3-Fluoranilin 3-Fluoroaniline 3-Fluorophenylamine 3-氟苯胺 3-氟苯胺,98+% m-Fluoroaniline Aniline, m-fluoro- Aniline, m-fluoro- M-FLUOROANILINE
MDL NumberMFCD00007758
CAS Number372-19-0
EC Number206-747-0
Beilstein Registry Number1305471
PubChem Substance ID9742
Chemical Name Translation3-氟苯胺
Reaxys-RN1305471
InChIKeyQZVQQUVWFIZUBQ-UHFFFAOYSA-N
Wiswesser Line NotationZR CF
LabNetwork Molecule IDLN00223197
InChIInChI=1S/C6H6FN/c7-5-2-1-3-6(8)4-5/h1-4H,8H2
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分类

  • {SNA} Amines, Aryl Fluorinated Building Blocks, Building Blocks, C6, Chemical Synthesis, Fluorinated Building Blocks, Nitrogen Compounds, Organic Building Blocks, Organic Fluorinated Building Blocks, Other Fluorinated Organic Building Blocks
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment

产品应用

  • 医药、农药、液晶材料中间体。

相关文献及参考

  • Short: II/27B
  • Beilstein:12,597
  • Short: II/14a
  • Short: II/19b

安全信息

Signal word Danger
GHS Symbol
WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S36/39 Wear suitable protective clothing and eye/face protection 穿戴适当的防护服和眼睛/面保护；
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
Risk Statements
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R22 Harmful if swallowed 吞咽有害
  • R33 Danger of cumulative effects 有累积作用的危险
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
  • R37/38 Irritating to respiratory system and skin 对呼吸系统和皮肤有刺激性
  • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P310+P330
  • P302+P350
  • P302+P352+P312+P361+P364
  • P304+P340+P311
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P332+P313
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
RTECSBY1400000
Packing GroupIII
UN Number 2941
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H318 Causes serious eye damage 严重伤害眼睛
  • H302 Harmful if swallowed 吞食有害
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H227 Combustible liquid 可燃液体
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes 6.1 Xn Xn,T,Xi
Hazard Class6.1
Warnings 危化品目录(2015) 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Bird - wild bird species
DOSE/DURATION           : 56 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   21,315,1972

Restrict 危险品

其他信息

  • Sigma Aldrich:372-19-0(sigmaaldrich)
  • Alfa Aesar:3-氟苯胺,98+% 3-Fluoroaniline, 98+%(372-19-0)
  • Hazard Note:Toxic/Irritant
  • 外观性质:淡黄色液体。
  • 可燃性危险特性:明火可燃; 高热放出有毒氟化物和氮氧化物气体
  • 检测方法:GC,NMR
  • 类别:有毒物品
  • MSDS 信息:间氟苯胺(372-19-0).msds
  • TCI Shanghai:3-氟苯胺 3-Fluoroaniline,>;98.0%(GC)(372-19-0)
  • 下游产品:4'-溴-3'-氟乙酰苯胺 --> 7-喹啉甲酸 --> 1-(3-氟苯基)哌嗪 --> 3-氟苯磺酰氯 --> 3-氟乙酰苯胺 --> 3-氟苯酚 --> 3-氟-N-甲基苯胺 --> 异氰-3-氟基苯酯
  • 不溶于水，溶于四氯化碳、乙醚和乙醇。
  • Acros Organics:3-氟苯胺 3-Fluoroaniline, 98%(372-19-0)
  • 储运特性:库房通风低温干燥; 与氧化剂、酸类、食品添加剂分开存放
  • 急性毒性:口服- 鹌鹑 LD50: 56 毫克/ 公斤
  • 海关编码:29214210
  • 3-氟苯胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 xw010065 3-氟苯胺 100ml 380元 2011/04/16 F0101 3-氟苯胺 3-Fluoroaniline 25G 603元 2011/04/16 F0101 3-氟苯胺 3-Fluoroaniline 250G 3540元
  • 灭火剂:泡沫、二氧化碳、砂土、干粉。
  • 用途一:用作有机合成中间体
  • 上游原料:铁粉 --> 氟硼酸 --> 3-硝基苯胺
  • 用途二:医药、农药、液晶材料中间体。
  • MOL 文件:372-19-0.mol
  • 图谱信息:3-氟苯胺(372-19-0)红外图谱(IR1) 3-氟苯胺(372-19-0)核磁图( 1 HNMR) 3-氟苯胺(372-19-0)核磁图( 13 CNMR) 3-氟苯胺(372-19-0)质谱(MS)
  • 毒性分级:高毒

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Fluorinated Building Blocks 氟化物砌块
  4. Organic Fluorinated Building Blocks - Fluorinated Building Blocks
  5. Other Fluorinated Organic Building Blocks - Organic Fluorinated Building Blocks
  6. Aryl Fluorinated Building Blocks 芳基氟化物
  7. C6 - Aryl Fluorinated Building Blocks
  1. C6 - Amines
  1. C10 - Amines
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Halogenated 卤化物 (氟氯溴碘)
  5. Fluoro 氟化物
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Amines 胺
  6. C11 to C38