2,4-Dichloroaniline 2,4-二氯苯胺
CAS 554-00-7 MFCD00007661
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分类
- Alpha sort, Alphabetic, Amines, Analytical Standards, Analytical/Chromatography, Aromatics, Chemical Class, Chromatography, D, DIA - DIC, Environmental Standards, Pesticides & Metabolites
- {S
- {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
- {SNA} Alphabetical Index of Analytical Standards,
- {SNA} Amines, Building Blocks, C6, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks
- {SNA} Alphabetical Index of Analytical Standards, Amines, Analytical Standards, Analytical/Chromatography, Aromatics, Chemical Class, Chromatography,
产品应用
- 有机合成中间体,农药中间体。
相关文献及参考
- Short: III/31a
- Short: III/20b
- Beilstein:12,621
安全信息
GHS Symbol
- H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
- H331 Toxic if inhaled 吸入中毒
- H311 Toxic in contact with skin 皮肤接触中毒
- H301 Toxic if swallowed 吞食有毒
- H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
- H302 Harmful if swallowed 吞食有害
- H301+H311+H331
- P273 Avoid release to the environment. 避免释放到环境中。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P301+P310
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P305+P351+P338
- P304+P340+P310
- P301+P312+P330
- P302+P350
- P337+P313
- P403+P233
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P284 Wear respiratory protection.? 佩戴呼吸保护装置。
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
- P332+P313
- P302+P352+P310+P361+P364
- P308+P311
- P361 Remove/Take off immediately all contaminated clothing. 立即去除/脱掉所有被污染的衣服。
- P305+P351+P338+P337+P313
- P405 Store locked up. 上锁保管。
- P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
- P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛,皮肤或衣服。
- P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
- S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
- S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
- S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后,立即用大量…(由生产厂家指定)冲洗;
- S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
- R33 Danger of cumulative effects 有累积作用的危险
- R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入,皮肤接触及吞食都有毒
- R50/53
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 400 mg/kg TOXIC EFFECTS : Behavioral - muscle weakness Lungs, Thorax, or Respiration - cyanosis Lungs, Thorax, or Respiration - respiratory depression REFERENCE : TSCAT* Office of Toxic Substances Report. (U.S. Environmental Protection Agency, Office of Toxic Substances, 401 M St., SW, Washington, DC 20460) Volume(issue)/page/year: OTS 206512
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 1600 mg/kg TOXIC EFFECTS : Behavioral - muscle weakness Lungs, Thorax, or Respiration - cyanosis Lungs, Thorax, or Respiration - respiratory depre
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intraperitoneal SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 400 mg/kg TOXIC EFFECTS : Behavioral - muscle weakness Lungs, Thorax, or Respiration - cyanosis Lungs, Thorax, or Respiration - respiratory depression REFERENCE : TSCAT* Office of Toxic Substances Report. (U.S. Environmental Protection Agency, Office of Toxic Substances, 401 M St., SW, Washington, DC 20460) Volume(issue)/page/year: OTS 206512
TYPE OF TEST : LDLo - Lowest published lethal dose ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Mammal - cat DOSE/DURATION : 113 mg/kg TOXIC EFFECTS : Behavioral - hallucinations, distorted perceptions Lungs, Thorax, or Respiration - cyanosis Blood - methemoglobinemia-carboxyhemoglobin REFERENCE : AEXPBL Archiv fuer Experimentelle Pathologie und Pharmakologie. (Leipzig, Ger. Dem. Rep.) V.1-109, 1873-1925. For publisher information, see NSAPCC. Volume(issue)/page/year: 72,241
其他信息
- Hazard Note:Toxic/Irritant
- F:8-9-23
- 储运特性:库房通风低温干燥; 与氧化剂、食品添加剂、酸类分开存放
- MSDS 信息:2,4-二氯苯胺(554-00-7).msds
- 用途二:用作染料中间体。
- 图谱信息:2,4-二氯苯胺(554-00-7)核磁图( 13 CNMR) 2,4-二氯苯胺(554-00-7)红外图谱(IR2) 2,4-二氯苯胺(554-00-7)红外图谱(IR1) 2,4-二氯苯胺(554-00-7)质谱(MS)
- 类别:有毒物品
- TCI Shanghai:2,4-二氯苯胺 2,4-Dichloroaniline,>;99.0%(GC)(554-00-7)
- 用途一:用作抗感染药环丙沙星、农药杀菌剂酰胺唑、除草剂(PUMA)和染料的合成原料
- Alfa Aesar:2,4-二氯苯胺,99% 2,4-Dichloroaniline, 99%(554-00-7)
- 用途三:有机合成中间体,农药中间体。
- Acros Organics:2,4-二氯苯胺 2,4-Dichloroaniline, 98%(554-00-7)
- 2,4-二氯苯胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 D0321 2,4-二氯苯胺 2,4-Dichloroaniline 25G 152元 2014/06/02 D0321 2,4-二氯苯胺 2,4-Dichloroaniline 500G 1020元 2010/06/21 150392500 2,4-二氯苯胺 2,4-Dichloroaniline 98% 250 GR 1146元
- 海关编码:29214210
- 方法一:由乙酰苯胺经氯化、水解而得。
- 可燃性危险特性:明火可燃;燃烧释放有毒氯化物和氮氧化物烟雾;与氧化剂起作用
- 外观性质:白色结晶。
- 检测方法:HPLC,NMR
- 下游产品:2,4-二氯苯硫酚 --> 环丙酸酰胺
- 毒性分级:高毒
- Sigma Aldrich:554-00-7(sigmaaldrich)
- 急性毒性:口服-大鼠 LD50: 1600 毫克/公斤;口服-小鼠 LD50: 400 毫克/公斤
- 见光或露置空气中逐渐变色。溶于醇、醚、有机溶剂和酸类,几乎不溶于水。有毒,最小致死量(猫,经口)173mg/kg。有刺激性。
- MOL 文件:554-00-7.mol
- 灭火剂:泡沫、二氧化碳、干粉、砂土。