CAS 7226-23-5 MFCD00006550-N,N'-Dimethylpropyleneurea N,N-二甲基丙烯基脲 TAO{mole}

N,N'-Dimethylpropyleneurea N,N-二甲基丙烯基脲

CAS 7226-23-5 MFCD00006550

化学结构图

SMILES: CN1CCCN(C)C1=O

化学属性

Mol. Formula	C6H12N2O
Mol. Weight	128.17
Density	1.06
Refractive index	1.4870 to 1.4900
Boiling Point	240.2°C at 760 mmHg
Flash Point	120°C
TSCA	Yes
Melting Point	-20°C
Solubility	可溶
Stability	易吸潮

别名和识别编码

Chemical Name	N,N'-Dimethylpropyleneurea
Synonym	N,N'-Dimethyltrimethyleneurea {LY} N,N'-Dimethyltrimethyleneurea {} {LY} N,N'-Dimethyltrimethyleneurea {} {} {LY} N,N'-Dimethyltrimethyleneurea {} {} {} {LY} N,N'-Dimethyltrimethyleneurea {} {} {} {} {LY} N,N'-Dimethyltrimethyleneurea {} {} {} {} {} {LY} N,N'-Dimethyltrimethyleneurea {} {} {} {} {} {} {LY} N,N'-Dimethyltrimethyleneurea {} {} {} {} {} {} {} {LY} N,N'-Dimethyltrimethyleneurea {} {} {} {} {} {} {} {} {LY} N,N'-Dimethyltrimethyleneurea {} {} {} {} {} {} {} {} {} {LY} N,N'-Dimethyltrimethyleneurea {} {} {} {} {} {} {} {} {} {} {LY} N,N'-Dimethyltrimethyleneurea {} {} {} {} {} {} {} {} {} {} {} {LY} N,N'-Dimethyltrimethyleneurea {} {} {} {} {} {} {} {} {} {} {} {} {LY} N,N'-Dimethyltrimethyleneurea {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N,N'-Dimethyltrimethyleneurea {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N,N'-Dimethyltrimethyleneurea {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
CAS Number	7226-23-5
EC Number	230-625-6
Beilstein Registry Number	110562
MDL Number	MFCD00006550
Reaxys-RN	110562
PubChem Substance ID	81646
Chemical Name Translation	N,N-二甲基丙烯基脲
Wiswesser Line Notation	T6NVNTJ A1 C1
LabNetwork Molecule ID	LN00224601
InChIKey	GUVUOGQBMYCBQP-UHFFFAOYSA-N
InChI	InChI=1S/C6H12N2O/c1-7-4-3-5-8(2)6(7)9/h3-5H2,1-2H3
Canonical SMILES	O=C1N(C)CCCN1C

信息真实价格透明资金保障专业采购外包团队在线服务

品牌质保精细包装现货库存一流品牌服务

产品应用

多功能溶剂，用于手性伯胺的 N-烷基化反应，醛醣的 O-烷基化反应，以及聚(芳醚)的合成。

安全信息

GHS Symbol

WGK Germany2

Hazard Codes Xn

Hazard statements

H361 Suspected of damaging fertility or the unborn child 怀疑对生育能力或未出生婴儿造成伤害
H317 May cause an allergic skin reaction 可能导致皮肤过敏
H318 Causes serious eye damage 严重伤害眼睛
H302 Harmful if swallowed 吞食有害

Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

RTECSUW7582500

Precautionary statements

P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P501 Dispose of contents/container to..… 处理内容物/容器.....
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P305+P351+P338
P332+P313
P305+P351+P338+P337+P313
P301+P312+P330
P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
P302+P350
P337+P313
P302+P352+P332+P313+P362+P364

Signal word

Risk Statements

R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
R62 Possible risk of impaired fertility 有削弱生殖能力的危险
R22 Harmful if swallowed 吞咽有害
R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
R36 Irritating to eyes 刺激眼睛
R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应

Safety Statements

S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；

Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1300 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Behavioral - ataxia
   Lungs, Thorax, or Respiration - respiratory stimulation
REFERENCE :
   JMCMAR Journal of Medicinal Chemistry.  (American Chemical Soc.,
   Distribution Office Dept. 223, POB POB 57136, West End Stn., Washington, DC
   20037)  V.6-    1963-  Volume(issue)/page/year: 11,214,1968

其他信息

图谱信息:N,N-二甲基丙烯基脲(7226-23-5)红外图谱(IR1) N,N-二甲基丙烯基脲(7226-23-5)核磁图( 13 CNMR) N,N-二甲基丙烯基脲(7226-23-5)核磁图( 1 HNMR) N,N-二甲基丙烯基脲(7226-23-5)质谱(MS)
用途一:非极性溶剂,毒性极低,耐光热,耐强酸强碱,溶解性好,可溶解各种有机,无机,高分子等.在药物制剂中,可作为辅料添加,提高药物吸收速度,延长作用时间.
MOL 文件:7226-23-5.mol
溶于水。
TCI Shanghai:1,3-甲基-3,4,5,6-四氢-2(1H)-嘧啶酮 1,3-Dimethyl-3,4,5,6-tetrahydro-2(1H)-pyrimidinone,>;98.0%(GC)(7226-23-5)
检测方法:GC
F:3-10
N,N-二甲基丙烯基脲价格(试剂级):更新日期产品编号产品名称包装价格 2011/08/23 xw010230 N,N-二甲基丙烯基脲 100g 260元 2011/04/16 D2014 1,3-甲基-3,4,5,6-四氢-2(1H)-嘧啶酮 1,3-Dimethyl-3,4,5,6-tetrahydro-2(1H)-pyrimidinone 500G 889元 2011/04/16 D2014 1,3-甲基-3,4,5,6-四氢-2(1H)-嘧啶酮 1,3-Dimethyl-3,4,5,6-tetrahydro-2(1H)-pyrimidinone 25G 139元
上游原料:二氯甲烷 --> 碳酸钾 --> 1,4-二氧六环 --> 硫酸二甲酯 --> 苄基三乙基氯化铵 --> 对甲苯磺酸水合物 --> 丙烯脲
外观性质:无色或浅黄色透明液体,溶于水。密度：1.064熔点：-20℃沸点：146 °C/44 mmHg折射率n20/D：1.4880闪点：121℃ 其结构中由于羰基具有强烈的吸电子效应，因而它是一种非质子的极性溶剂，具有高沸点、高闪点、低熔点，在过滤、蒸馏、溶剂萃取等工艺操作中使用方便；毒性极低，对人体危害微不足道，也减少了对环境的污染；由于它具有极强的溶解性，能溶解有机物、无机物、树脂、聚合物等，并对各种试剂具有活化性质，还能与其它高沸点溶剂混溶；具有极好的稳定性，在热的强碱和酸性条件下都很稳定，还具有耐水性及对光、氧的稳定性。因此DMPU应用到有机化学反应中能促进反应物溶解，加快反应速度，提高反应收率，还能替代毒性较大的溶剂。
海关编码:29335995
Sigma Aldrich:7226-23-5(sigmaaldrich)
存储注意事项:氮气保护
敏感性:Hygroscopic
Acros Organics:1,3-二甲基-3,4,5,6-四氢-2(1H)-嘧啶酮 1,3-Dimethyl-3,4,5,6-tetrahydro-2(1H)-pyrimidinone, 97%(7226-23-5)
MSDS 信息:DMPU(7226-23-5).msds
其结构中由于羰基具有强烈的吸电子效应，因而它是一种非质子的极性溶剂，具有高沸点、高闪点、低熔点，在过滤、蒸馏、溶剂萃取等工艺操作中使用方便；毒性极低，对人体危害微不足道，也减少了对环境的污染；由于它具有极强的溶解性，能溶解有机物、无机物、树脂、聚合物等，并对各种试剂具有活化性质，还能与其它高沸点溶剂混溶；具有极好的稳定性，在热的强碱和酸性条件下都很稳定，还具有耐水性及对光、氧的稳定性。因此DMPU应用到有机化学反应中能促进反应物溶解，加快反应速度，提高反应收率，还能替代毒性较大的溶剂。
Alfa Aesar:1,3-二甲基-3,4,5,6-四氢-2(1H)-嘧啶酮,98+% 1,3-Dimethyl-3,4,5,6-tetrahydro-2(1H)-pyrimidinone, 98+%(7226-23-5)
下游产品:2-吗啉代吡啶-3-醛 --> 2-氯-3-吡啶甲醛