CAS 13746-66-2 MFCD00011392-Potassium hexacyanoferrate(III) 铁氰化钾 TAO{mole}

Potassium hexacyanoferrate(III) 铁氰化钾

CAS 13746-66-2 MFCD00011392

化学结构图

SMILES: N#C[Fe-3](C#N)(C#N)(C#N)(C#N)C#N.[K+].[K+].[K+]

化学属性

Mol. Formula	K3Fe(CN)6
Mol. Weight	329.24
Melting Point	dec.
Density	1.89
TSCA	Yes
Solubility	464 G/L (20 ºC)
Stability	对光敏感

别名和识别编码

Chemical Name	Potassium hexacyanoferrate(III)
Synonym	Potassium hexacyanoferrate(III), 99.5% {LY} Potassium hexacyanoferrate(III), 99.5% {} {LY} Potassium hexacyanoferrate(III), 99.5% {} {} {LY} Potassium hexacyanoferrate(III), 99.5% {} {} {} {LY} Potassium hexacyanoferrate(III), 99.5% {} {} {} {} {LY} Potassium hexacyanoferrate(III), 99.5% {} {} {} {} {} {LY} Potassium hexacyanoferrate(III), 99.5% {} {} {} {} {} {} {LY} Potassium hexacyanoferrate(III), 99.5% {} {} {} {} {} {} {} {LY} Potassium hexacyanoferrate(III), 99.5% {} {} {} {} {} {} {} {} {LY} Potassium hexacyanoferrate(III), 99.5% {} {} {} {} {} {} {} {} {} {LY} Potassium hexacyanoferrate(III), 99.5% {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Potassium hexacyanoferrate(III), 99.5% {} {} {} {} {} {} {} {} {} {} {} {LY} Potassium hexacyanoferrate(III), 99.5% {} {} {} {} {} {} {} {} {} {} {} {} {LY} Potassium hexacyanoferrate(III), 99.5% {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Potassium hexacyanoferrate(III), 99.5% {} {} {} {} {} {} {
MDL Number	MFCD00011392
PubChem Substance ID	57651743
CAS Number	13746-66-2
EC Number	237-323-3
Merck Number	14,7630
Chemical Name Translation	铁氰化钾
Wiswesser Line Notation	NC-FE-CN&CN&CN&CN&CN &-KA- 3
LabNetwork Molecule ID	LN00195663
Canonical SMILES	K3Fe(CN)6

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产品应用

色谱分析用试剂,点滴分析测定高铁、铯、镓、汞、锌和二氧化铀等。有机合成的缓和氧化剂。氮肥生产甲醇的含硫量分析。农药除草醚生产中废水分析。

安全信息

WGK Germany2

RTECSLJ8225000

Personal Protective Equipment Eyeshields, Gloves Eyeshields, Gloves, half-mask respirator (US), multi-purpose combination respirator cartridge (US)

Risk Statements

R32 Contact with acids liberates very toxic gas 与酸接触释放出毒性很高的气体

Storage condition Store at room temperature, keep dry and cool {LY} Store at room temperature, keep dry and cool {} {LY} Store at room temperature, keep dry and cool {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store

Safety Statements

S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 2970 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 51(4),23,1986

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1600 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   KODAK* Kodak Company Reports.  (343 State St., Rochester, NY 14650)
   Volume(issue)/page/year: 21MAY1971

TYPE OF TEST            : Gene conversion and mitotic recombination
TEST SYSTEM             : Yeast - Saccharomyces cerevisiae
DOSE/DURATION           : 100 mmol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 117,149,1983

TYPE OF TEST            : Mutation test systems - not otherwise specified
TEST SYSTEM             : Bacteria - Escherichia coli
DOSE/DURATION           : 750 nmol/tube
REFERENCE :
   LAMEDS LARC Medical.  (19 bis, rue d'Inkermann, 59000 Lille, France)  V.1-
   1981-  Volume(issue)/page/year: 6,252,1986

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Yeast - Saccharomyces cerevisiae
DOSE/DURATION           : 100 mmol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 117,149,1983

GHS Symbol

UN Number

Hazard Codes

Precautionary statements

P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛，皮肤或衣服。

Packing GroupIII

其他信息

其热溶液能被酸分解，放出剧毒氰化氢气体。遇亚铁盐生成兰色沉淀。能被光及还原剂还原成亚铁氰化钾。缓慢溶于2.5份冷水、1.3份沸水，微溶于乙醇。其水溶液在存放过程中逐渐分离。最小致死量(大鼠，经口)1600mg/kg。红色透明结晶，溶于水、丙酮，不溶于乙醇、液氨。