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分类

• {SNA} Analytical Standards, EP Standards, EP Standards L - M, Pharmacopeia & Metrological Institutes Standards, 分析/色谱
• {SNA} Analytical Standards, EP Standards, EP Standards L - M,
• {SNA} Analytical Standards, Analytical/Chromatography, Chromatography, EP Standards, EP Standards L - M, Pharmaceutical Standards, Pharmacopeia Standards
• {SNA} Analytical Standards, Chromatography, EP Standards, EP Standards L - M, Pharmaceutical Standards, Pharmacopeia Standards, 分析/色谱
• {SN
• {SNA} Analytical Standards, EP Standards, EP Standards L - M, Pharmacopeia Metrological Institutes Standards, 分析/色谱

相关文献及参考

• Bifunctional catalyst for a wide variety of acylation reactions. See, for example: J. Chem. Soc. (C), 89 (1969).
• Reacts with SOCl2 to form di-2-pyridyl sulfite, a useful reagent for in situ formation of N-sulfinylamines, nitriles, isocyanides and carbodiimides under mild conditions: Tetrahedron Lett., 27, 1925 (1986).
• Beilstein:21,43
• For use of 2-pyridyl esters as active esters in peptide coupling, see: J. Chem. Soc.(C), 2896 (1971); Chem. Ber., 118, 468 (1985). The group can be introduced on to the N-protected peptide using DCC in pyridine, and is displaced by the amino-residue under mild conditions. For peptide reagents, see Appendix 6. Similar methodology has also been used in an improved preparation of trichloroethyl esters: Synthesis, 24 (1979).

安全信息

GHS Symbol

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 410 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   TOXIA6 Toxicon.  (Pergamon Press Ltd., Headington Hill Hall, Oxford OX3 OBW,
   UK)  V.1-    1962-  Volume(issue)/page/year: 23,815,1985

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 750 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AIPTAK Archives Internationales de Pharmacodynamie et de Therapie. (Heymans
   Institute of Pharmacology, De Pintelaan 185, B-9000 Ghent, Belgium)  V.4-   
   1898-  Volume(issue)/page/year: 93,143,1953

其他信息

• 下游产品:3-甲氧基-2-吡啶醛 --> 3-(N,N-二甲氨基甲酰氧基)吡啶
• Sigma Aldrich:142-08-5(sigmaaldrich)
• 检测方法:GC
• 图谱信息:3-羟基吡啶(109-00-2)红外图谱(IR2) 3-羟基吡啶(109-00-2)核磁图( 1 HNMR) 3-羟基吡啶(109-00-2)红外图谱(IR1) 3-羟基吡啶(109-00-2)核磁图( 13 CNMR) 3-羟基吡啶(109-00-2)质谱(MS)
• 下游产品:2-羟基-5-溴吡啶 --> 二吡啶硫碳酸酯 --> 活性嫩黄M-7G --> 3,5-二氯-2-羟基吡啶 --> 4-[[5-(氨基羰基)-1-乙基-1,6-二氢-2-羟基-4-甲基-6-氧代-3-吡啶基]偶氮]-6-[(4,6-二氯-1,3,5-三嗪-2-基)氨基]-1,3-苯二磺酸二钠盐
• Hazard Note:Irritant
• {Ch
• MOL 文件:142-08-5.mol
• 用途一:用于有机合成、医药和染料的制备
• 上游原料:发烟硫酸 --> 硫酸汞 --> 3-吡啶磺酸
• Alfa Aesar:2-羟基吡啶,98+% 2-Hydroxypyridine, 98+%(142-08-5)
• Acros Organics:2-羟基吡啶 2-Hydroxypyridine, 97%(142-08-5)
• 图谱信息:2-羟基吡啶(142-08-5)质谱(MS) 2-羟基吡啶(142-08-5)核磁图( 1 HNMR) 2-羟基吡啶(142-08-5)红外图谱(IR1) 2-羟基吡啶(142-08-5)核磁图( 13 CNMR) 2-羟基吡啶(142-08-5)红外图谱(
• 用途三:有机合成和医药中间体。
• 方法一:由吡啶经磺化、碱熔、中和而得。将发烟硫酸加入干燥的反应锅内，搅拌下滴加吡啶，再加入硫酸汞。加热至230-240℃，保温13-14h。冷至20-25℃，加入乙醇中，继续冷至5℃以下，析出结晶。过滤，得吡啶-3-磺酸。熔点345℃，收率62%。将氢氧化钠及吡啶-3-磺酸加入反应锅内，在160℃熔融，升温至220-230℃保温4h。冷至100℃，加水溶解，用30%的盐酸调节pH至4，减压浓缩，过滤 除去氯化钠。滤液用饱和碳酸钠调节pH至8-9，冷却过滤，烘干，得3-羟基吡啶粗品，收率64%。用甲苯进行重结晶而得精品，熔点126-128℃，含量98%，精制收率80%。
• TCI Shanghai:3-羟基吡啶 3-Hydroxypyridine,>;98.0%(GC)(T)(109-00-2)
• 存储注意事项:光敏感
• 2-羟基吡啶价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 H0330 2-羟基吡啶 2-Hydroxypyridine 250G 2140元 2014/06/02 H0330 2-羟基吡啶 2-Hydroxypyridine 25G 456元 2010/06/21 121840500 2-羟基吡啶 2-Hydroxypyridine 97% 50 GR 1003元
• 用途二:用作医药中间体。
• Acros Organics:3-羟基吡啶 3-Hydroxypyridine, 98%(
• 检测方法:HPLC,NMR
• MOL 文件:109-00-2.mol
• 3-羟基吡啶价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 H0331 3-羟基吡啶 3-Hydroxypyridine 25G 267元 2014/06/02 H0331 3-羟基吡啶 3-Hydroxypyridine 500G 1460元 2010/06/21 121855000 3-羟基吡啶 3-Hydroxypyridine 98% 500 GR 1972元
• MSDS 信息:2-Hydroxypyridine(142-08-5).msds