Sodium chlorate 氯酸钠(易制爆)
CAS 7775-09-9 MFCD00003479
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信息真实价格透明
资金保障
专业采购外包团队在线服务
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现货库存
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分类
- {SNA} ACS Grade, Chemical Synthesis, Essential Chemicals, Inorganic Salts,
- {SNA} Chemical Synthesis, Essential Chemicals, Inorganic Salts, Research Essentials, Salts, Sodium, Sodium Salts, Synthetic Reagents
- Analytical Reagents, Analytical Reagents for General Use, Analytical Standards, Analytical/Chromatography, Chromatography, Environmental Standards, Herbicides, Inorganics, Pesticides & Metabolites, Puriss p.a., Q-S, Puriss p.a.
- {SNA} Analytical Reagents for General Use, Analytical Standards, Essential Chemicals, Inorganics,
- {SNA} Analytic
产品应用
- A sulfation biosynthesis inhibitor.
相关文献及参考
- Short: III/20a
- Short: III/20b
- Merck: 14,8598
安全信息
GHS Symbol
- H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
- H302 Harmful if swallowed 吞食有害
- H271 May cause fire or explosion; strong oxidizer 可能会引起火宅或爆炸;强氧化剂。
- P220 Keep/Store away from clothing/…/combustible materials. 保持远离/贮存远离服装/....../可燃材料。
- P273 Avoid release to the environment. 避免释放到环境中。
- S46 If swallowed, seek medical advice immediately and show this container or label 食入时,立即求医并出示容器/标签;
- S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
- S13 Keep away from food, drink and animal foodstuffs 远离食品、饮料和动物饲料保存;
- S17 Keep away from combustible material 远离可燃物料;
- R22 Harmful if swallowed 吞咽有害
- R9 Explosive when mixed with combustible material 与易燃物混合会爆炸
- R51/53
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Unreported SPECIES OBSERVED : Human - child DOSE/DURATION : 185 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : GUCHAZ Guide to the Chemicals Used in Crop Protection. (Information Canada, 171 Slater St., Ottawa, Ont., Canada) Volume(issue)/page/year: 6,461,1973
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intraperitoneal SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 596 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : COREAF Comptes Rendus Hebdomadaires des Seances, Academie des Sciences. (Paris, France) V.1-261, 1835-1965. For publisher information, see CRASEV. Volume(issue)/page/year: 257,791,1963
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 8350 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : UZBZAZ Uzbekskii Biologicheskii Zhurnal. Uzbek Biological Journal. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) No.1- 1958- Volume(issue)/page/year: (1),40,1986
TYPE OF TEST : LDLo - Lowest published lethal dose ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Mammal - dog DOSE/DURATION : 700 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : HBAMAK "Abdernalden's Handbuch der Biologischen Arbeitsmethoden." (Leipzig, Ger. Dem. Rep.) Volume(issue)/page/year: 4,1289,1935
TYPE OF TEST :
TYPE OF TEST : LDLo - Lowest published lethal
TYPE OF TEST : LD
TYPE OF TEST : DNA inhibition ROUTE OF EXPOSURE : Oral TEST SYSTEM : Rodent - rat DOSE/DURATION : 84 mg/kg/12W (Continuous) REFERENCE : JEPOEC Journal of Environmental Pathology, Toxicology and Oncology. (Chem-Orbital, POB 134, Park Forest, IL 60466) V.5(4)- 1984- Volume(issue)/page/year: 6(1),105,1985
TYPE OF TEST : Sex chromosome loss and nondisjunction ROUTE OF EXPOSURE : Oral TEST SYSTEM : Insect - Drosophila melanogaster DOSE/DURATION : 250 mmol/L REFERENCE : MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 90,91,1981
TYPE OF TEST : Mutation in microorganisms TEST SYSTEM : Bacteria - Salmonella typhimurium DOSE/DURATION : 40 umol/plate REFERENCE : MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 90,91,1981
其他信息
- 类别:氧化剂
- 无气味。约300℃时释放出氧,较高温度全部分解。溶于约ml冷水、0.5ml沸水、约130ml乙醇、50ml沸乙醇、4ml甘油,水溶液呈中性,氯化钠能降低其水中溶解度。有强氧化性。与有机物或还原性物质摩擦或撞击能引起燃烧或爆炸。低毒,半数致死量(大鼠,经口)12000mg/kg。
- 毒性:粉尘能刺激皮肤、黏膜和眼睛。如不慎氯酸钠溅人眼睛或溅到皮肤上,应立刻用大量水冲洗干净。吸入氯酸钠粉尘,因积累在体内而引起中毒,会出现恶心、大量呕吐、下泻、呼吸困难、肾损害等症状。误食时,要立即饮服食盐水或温肥皂水使其吐出,然后速送医院治疗。致死量为10g。 生产人员工作时应穿工作服,戴防护口罩、乳胶手套、塑料或橡皮围裙,穿长统胶靴等劳保用品,以保护呼吸器官和皮肤。生产设备要密闭,车间通风应良好。下班后要洗淋浴。
- {Chem
- 方法一:氯酸钠生产主要采用电解法,使用的电解槽主要有3种:石墨阳极电解槽现已淘汰;二氧化铅阳极电解槽和旧式金属阳极电解槽日趋淘汰;新型金属阳极电解槽正在被迅速推广。金属阳极电解槽又分为复极式电解槽和单极电解槽。 电解法将食盐加水于40~45℃下溶解,使其达到饱和,在精制槽中加入纯碱、烧碱、氯化钡以除去钙、镁和硫酸根等杂质,再送入调液器调酸并加入红矾钠,使盐水符合下列要求:NaCI≥280 g/L;Na2Cr2O72~3 g/L;Ca 2+ +Mg 2+ ≤1×10 -5 ;SO4 2+ <5 g/L。然后送去电解,通过化学反
- 灭火剂:雾状水
- 毒性分级:中毒
- 外观性质:无色无臭结晶,味咸而凉,有潮解性。
- 下游产品:二氧化锰 --> 氰化亚铜 --> 苯乙醇 --> 间苯氧基苯甲醛 --> 富马酸 --> 氨茴酸甲酯 --> N-氯代丁二酰亚胺 --> 糠酸 --> 次氯酸钙 --> 铂 --> 高氯酸 --> 乙基麦芽酚 --> 普鲁士兰 --> 二氧化氯 --> 亚氯酸钠 --> 5-叔丁基-2-甲基呋喃-3-碳酰氯 --> 还原深蓝BO --> 偶氮二甲酰胺 --> 氯化铜 --> 氧化苯乙烯 --> 硫化蓝CV --> 1,1-二甲基肼 --> 磺胺甲恶唑 --> 碘酸钙 --> 1-氯蒽醌 --> 高氯酸钾 --> 颜料绿 18 --> 还原黄4 --> 柠檬酸铁铵 --> N-叔丁基-2-苯并噻唑次磺酰胺 --> 虫胶 --> N,N-二异丙基-2-苯并噻唑次磺酰胺 --> 2-(4-吗啉基二硫代)苯并噻唑 --> 士林棕3GR --> 稳定性二氧化氯 --> 漂白淀粉 --> 氯化磷酸钠 --> 还原棕 3 --> 6-氯间甲酚 OR 3-甲基-6-氯苯酚
- Sigma Aldrich:7775-09
- 用途四:氧化剂。除草剂。
- Alfa Aesar:氯酸钠,ACS,9
- 常规方法:用内衬聚乙烯塑料袋的铁桶包装,桶口密封牢固,每桶净重50kg。包装上应有明显的“氧化剂”和“有毒品”标志。 属一级无机氧化剂,危规编号:21014。应贮存在阴凉、通风、干燥的库房内。注意防潮。严防粉末散落在地上,如有散落,必须立刻用湿黄砂拌和后扫干净。不得与糖类、油类、木炭等有机物、硫黄、赤磷、还原剂、硝酸盐、酸类(尤其是硫酸)和一切易燃物品共贮混运。运输过程中要防雨淋和日晒,注意防潮。装卸时要轻拿轻放,防止摩擦,严禁撞击。 失火时,先用砂土,再用雾状水和各种灭火器扑救,但不可用高压水。
- 用途二:用于制造二氧化氯、亚氯酸钠及高氯酸盐,用作除草剂、印染氧化剂和媒染剂、纸浆漂白剂,还用于鞣革、烟火等
- Alfa Aesar:氯酸钠,ACS,99.0%min Sodium chlorate, ACS, 99.0% min(7775-09-9)
- 可燃性危险特性:遇有机物、还原剂、硫、磷等易燃物可燃; 燃烧产生有毒氯化物烟雾
- Sigma Aldrich:7775-09-9(sigmaaldrich)
- 刺激数据:皮肤- 兔子 500 毫克/ 24小时 轻度; 眼- 兔子 10 毫克 轻度
- 水中溶解度(g/100ml):不同温度(℃)时每100毫升水中的溶解克数: 79.6g/0℃;87.6g/1