Sodium perchlorate 无水高氯酸钠(易制爆)

CAS 7601-89-0 MFCD00003480

化学结构图

7601-89-0
SMILES: [Na+].[O-][Cl+3]([O-])([O-])[O-]

化学属性

Mol. FormulaClO4.Na
Mol. Weight122.44
Melting Point468 °C(lit.)
Density2.2
TSCAYes
Solubility209 G/100 ML (15 ºC)

别名和识别编码

Chemical NameSodium perchlorate
Synonym ClNaO4 (sodium perchlorate) Hyperchloric acid sodium salt KM sodium perchlorate NaClO4 Natrium perchlorat Natriumperchloraat Natriumperchlorat Natriumperchlorat-Monohydrat PERCHLORIC ACID, SODIUM SALT Perchlorate de sodium Perchloric acid sodium salt Perchlorsäure Natrium-Salz SODIUM PERCHLORATE SODIUM PERCHLORATE ANHYDROUS*ACS REAGENT SODIUM PERCHLORATE, 98+% A.C.S. REAGENT SODIUM PERCHLORATE, ANHYDROUS REAGENT (ACS) Sodio (perclorato di) Sodium (perchlorate de) Sodium perchlorate Sodium perchlorate anhydrous Sodium perchlorate, anhydrous Sodium perchlorate, extra pure, 98% Sodium perchlorate, for analysis, 99+% anhydro
MDL NumberMFCD00003480
CAS Number7601-89-0
EC Number231-511-9
Merck Number14,8653
PubChem Substance ID522606
Chemical Name Translation无水高氯酸钠(易制爆)
Wiswesser Line NotationNA G-O4
InChIInChI=1S/ClHO4.Na/c2-1(3,4)5;/h(H,2,3,4,5);/q;+1/p-1
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分类

  • {SNA} ACS Grade, Chemical Synthesis, Essential Chemicals, Inorganic Salts, Solutions and Reagents, Oxidizing Agents, Perchlorates, Research Essentials, Synthetic Reagents
  • {SNA} Chemical Synthesis, Development Quantities for Research, Essential Chemicals, Oxidizing Agents, Perchlorates, Reagent Salts, Research Essentials, Salts, Sodium Salts
  • {SNA} Chemical Synthesis, Essential Chemicals, Oxidizing Agents, Perchlorates, Research Essentials, Salts, Sodium Salts, Synthetic Reagents
  • {Chemicalbook} 无机化工产品: 无机盐: Ce液化物及氯酸盐
  • {uni_hamburg} no charge; 2fragments; ionic

产品应用

  • 也用作制造高级酸和高氯酸盐类的原料，分析化学中的分析试剂。此外，还广泛用作氧化剂等。

相关文献及参考

  • Short: III/39
  • Short: III/31a
  • Merck: 14,8653

安全信息

Safety Statements
  • S13 Keep away from food, drink and animal foodstuffs 远离食品、饮料和动物饲料保存；
  • S22 Do not breathe dust 不要吸入粉尘；
  • S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服；
Packing GroupII
UN Number 1502 UN 1502 5.1/PG 2 UN1502
Risk Statements
  • R9 Explosive when mixed with combustible material 与易燃物混合会爆炸
  • R48/22
  • R36 Irritating to eyes 刺激眼睛
  • R22 Harmful if swallowed 吞咽有害
Storage condition Hygroscopic
WGK Germany1
RTECSSC9800000
Hazard Codes O;Xn 5.1 O,Xn
GHS Symbol
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P220 Keep/Store away from clothing/…/combustible materials. 保持远离/贮存远离服装/....../可燃材料。
  • P221 Take any precaution to avoid mixing with combustibles/… 采取一切防范措施，避免与可燃物混合/...
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P283 Wear fire/flame resistant/retardant clothing. 穿防火/阻燃/耐阻燃服。
  • P301+P312
  • P301+P317
  • P302+P352
  • P304+P340
  • P305+P351+P338
  • P306+P360
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医，如果你觉得不舒服
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P362+P364
  • P370+P378
  • P371+P380+P375
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P420 Store away from other materials. 远离其他材料。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Hazard statements
  • H271 May cause fire or explosion; strong oxidizer 可能会引起火宅或爆炸；强氧化剂。
  • H302 Harmful if swallowed 吞食有害
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
Personal Protective Equipment dust mask type N95 (US), Eyeshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Hazard Class5.1
Warnings 危化品目录(2015) 危险化学品 
TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Parenteral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 900 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   RPTOAN Russian Pharmacology and Toxicology (English Translation).
   Translation of FATOAO.  (Euromed Pub., 33, Woodlands Rd., Surbiton, Surrey,
   UK)  V.30-    1967-  Volume(issue)/page/year: 32,159,1969

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 2100 mg/kg
TOXIC EFFECTS :
   Behavioral - excitement
   Lungs, Thorax, or Respiration - dyspnea
   Nutritional and Gross Metabolic - body temperature decrease
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 17(8),33,1973

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 551 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   COREAF Comptes Rendus Hebdomadaires des Seances, Academie des Sciences.
   (Paris, France)  V.1-261, 1835-1965.  For publisher information, see CRASEV.
    Volume(issue)/page/year: 257,791,1963

TYPE OF TEST            : DNA repair
TEST SYSTEM             : Bacteria - Escherichia coli
DOSE/DURATION           : 1500 pmol/plate
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 21,171,1973

Restrict 易制爆

其他信息

  • 类别:氧化剂
  • 高氯酸钠价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 342180025 高氯酸钠 Sodium perchlorate 98%, extra pure 2.5 KG 4076元 2010/06/21 197120050 高氯酸钠 Sodium perchlorate 99+%, for analysis 5 GR 362元 2010/06/21 197120010 高氯酸钠 Sodium perchlorate 99+%, for analysis 1 KG 2177元
  • 下游产品:5-（4-甲氧基苯基）-2-氯嘧啶 --> 5-氨基嘧啶-2-2羧酸
  • 毒性分级:中毒
  • 用途二:主要用作制造高氯酸和其他高氯酸盐的原料。用于火药工业。用作氧化剂。
  • 用途一:用作分析试剂、氧化剂
  • 可燃性危险特性:遇有机物、还原剂、硫、磷等易燃物及硫酸可燃; 燃烧产生有毒氯化物烟雾
  • 方法一:工业上采用电解法生产高氯酸钠。 电解法将工业氯酸钠在溶解槽内加水，通人蒸汽于45～50℃下溶解，使其饱和(溶液含氯酸钠650～700 g/L)后加入氢氧化钡除去铬酸根等杂质，过滤后，将澄清液送入电解槽，在电流强度为1500 A、槽电压为5～6 V、Ph6～7、电解温度为50～7(J℃下进行连续电解，生成的高氯酸钠溶液浓度达700 g/L时，经蒸发浓缩，冷却至30℃析出结晶，固液分离，在80～100℃下进行气流干燥，制得高氯酸钠。其 NaC1O3+H2O-2e→NaC1O4+2H +
  • 急性毒性:口服- 大鼠 LD50: 2100 毫克/ 公斤; 腹注- 小鼠 LD50: 551 毫克/ 公斤
  • F:3
  • 上游原料:氢氧化钡
  • 图谱信息:高氯酸钠(7601-89-0)红外图谱(IR1)
  • MSDS 信息:过氯酸钠(7601-89-0).msds
  • 敏感性:Hygroscopic
  • Alfa Aesar:无水高氯酸钠,ACS,98.0-102.0% Sodium perchlorate, anhydrous, ACS, 98.0-102.0%(7601-89-0)
  • 毒性:高氯酸钠粉尘能刺激皮肤、眼睛、咽喉、鼻黏膜等。如不慎溅入眼睛或溅到皮肤上，立即用水冲洗干净。 生产人员工作时应穿工作服，戴防护口罩或防毒面具，乳胶手套，穿长统胶靴等劳保用品。生产设备要密闭，车间通风要良好，下班后要淋浴。
  • Sigma Aldrich:7601-89-0(sigmaaldrich)
  • 爆炸物危险特性:遇有机物、还原剂、硫、磷等易燃物可爆
  • MOL 文件:7601-89-0.mol
  • 灭火剂:水、砂土
  • 参考质量标准:参考标准 指标名称 指标 工业级 高氯酸钠(NaC1O4)/%≥ 98 水不溶物/%≤ 0.2 氯化物(以Cl - 计)/%≤ 0.06 硫酸盐(以SO4 2- 计)/%≤ 0.2 氯化物和氯酸盐/%≤ 0.2
  • Acros Organics:高氯酸钠 Sodium perchlorate, extra pure, 98%(7601-89-0)
  • 外观性质:无色或白色斜方晶系结晶，有吸湿性。
  • 易溶于水和醇，不溶于醚。有强氧化性，与浓硫酸、有机物接触或与可燃混合物撞击时，均会发生爆炸。
  • 储运特性:库房通风; 轻装轻卸; 与有机物、还原剂、硫磷易燃物分开存放
  • 用途三:用于制造火药、炸药。也用作制造高级酸和高氯酸盐类的原料，分析化学中的分析试剂。此外，还广泛用作氧化剂等。

系列性分类

  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Sodium - Catalysis and Inorganic Chemistry
  1. Research Essentials 基础科研
  2. Essential Chemicals - Research Essentials
  3. Inorganic Salts, Solutions and Reagents - Essential Chemicals
  4. ACS Grade - Inorganic Salts, Solutions and Reagents
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Oxidation - Synthetic Reagents
  4. Perchlorates - Oxidation
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Oxidation - Synthetic Reagents
  4. Others - Oxidation