Bismuth Trichloride 氯化铋
CAS 7787-60-2 MFCD00003461
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信息真实价格透明
资金保障
专业采购外包团队在线服务
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分类
- {SNA} Bismuth Catalysts, Bismuth Salts, Catalysis and Inorganic Chemistry, Chemical Synthesis, Essential Chemicals, Metal and Ceramic Science, Research Essentials, Salts, 材料科学
- {SNA} 83: Bi, Beaded Materials, Bi, Bismuth, Bismuth Catalysts
产品应用
- 制造铋盐,有机反应催化剂,高纯材料。
相关文献及参考
- For catalysis of Diels-Alder and hetero Diels-Alder reactions, see: J. Org. Chem., 62, 4880 (1997); Tetrahedron Lett., 39, 1161 (1998).
- Short: II/25A
- Catalyzes the addition of 1,3-dicarbonyl compounds to Michael acceptors under solvent-free conditions with microwave irradiation: Tetrahedron Lett., 38, 1449 (1997).
- Merck: 14,1262
- Lewis acid catalyst which promotes the rearrangement of acetanilides to o-amino ketones: Tetrahedron Lett., 3217 (1976).
- For a brief feature on Bi(III) catalysts, see: Synlett, 1194 (2001). For a review of their use in acylation and sulfonylation reactions, see: Synlett, 181 (2002).
- Promotes the chemoselective deprotection of N-Boc amino acids and peptides: Tetrahedron Lett., 47, 389 (2006).
- Silyl enol ethers can be ɑ-acylated with acyl chlorides in the presence of a catalytic amount of BiCl3 and NaI or ZnI2; other Lewis acids such as ZnCl2 were less effective: J. Org. Chem., 61, 3885 (1996).
- Arenes undergo sufonylation by heating with arenesulfonyl chlorides in the presence of BiCl3 (5 mol%) and triflic acid (10 mol%) to give high yields of mixed diaryl sulfones; neither BiCl3 nor TfOH alone is effective: Tetrahedron Lett., 40, 9233 (1999).
安全信息
GHS Symbol
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H303 May be harmfully swallowed 吞食可能有害
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P302+P352+P332+P313+P362+P364
- P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
- P332+P313
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- P305+P351+P338+P337+P313
- P302+P350
- P337+P313
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
- S20 When using do not eat or drink 使用时,不得进食,饮水;
- S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
- S3 Keep in a cool place 保存在阴凉处;
- S36 Wear suitable protective clothing 穿戴适当的防护服;
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 3334 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 30(6),16,1986
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 2250 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 30(6),16,1986
其他信息
- Acros Organics:氯化铋 Bismuth(III) chloride, anhydrous, 98+%(7787-60-2)
- 下游产品:氯乙烷
- 用途一:用作分析试剂及催化剂,也用于铋盐制取
- MOL 文件:7787-60-2.mol
- 有氯化氢气味,具溶解性。加热则挥发,约在430℃时升华。在水中分解成氧氯化铋,能溶于盐酸、硝酸、无水乙醇、丙酮和乙酸乙酯。
- 图谱信息:氯化铋(7787-60-2)红外图谱(IR1)
- 升华点:430 °C
- Sigma Aldrich:7787-60-2(sigmaaldrich)
- Alfa Aesar:氯化铋,98% Bismuth(III) chloride, 98% (dry wt.), may cont. up to 3% water(7787-60-2)
- 用途二:制造铋盐,有机反应催化剂,高纯材料。
- MSDS 信息:Bismuth trichloride (7787-60-2).msds
- 氯化铋价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 20008816 氯化铋 100g 43元 2010/06/21 208835000 氯化铋 Bismuth(III) chloride 98+%, anhydrous 500 GR 6703元 2010/06/21 208830250 氯化铋 Bismuth(III) chloride 98+%, anhydrous 25 GR 660元
- 敏感性:Hygroscopic