CAS 928-51-8 MFCD00002967-4-Chloro-1-butanol 4-氯丁醇 TAO{mole}

4-Chloro-1-butanol 4-氯丁醇

CAS 928-51-8 MFCD00002967

化学结构图

SMILES: OCCCCCl

化学属性

Mol. Formula	C4H9ClO
Mol. Weight	108.57
Density	1.088 g/mL at 25 °C(lit.)
Refractive index	1.4510 to 1.4550
Flash Point	36°C(lit.)
TSCA	Yes
Boiling Point	84-85 °C at 16 mmHg
Appearance	无色液体。易溶于醇和醚。
Solubility	易溶于醇和醚。
pH	:A

别名和识别编码

Chemical Name	4-Chloro-1-butanol
Synonym	4-Chlorobutan-1-ol {LY} 4-Chlorobutan-1-ol {} {LY} 4-Chlorobutan-1-ol {} {} {LY} 4-Chlorobutan-1-ol {} {} {} {LY} 4-Chlorobutan-1-ol {} {} {} {} {LY} 4-Chlorobutan-1-ol {} {} {} {} {} {LY} 4-Chlorobutan-1-ol {} {} {} {} {} {} {LY} 4-Chlorobutan-1-ol {} {} {} {} {} {} {} {LY} 4-Chlorobutan-1-ol {} {} {} {} {} {} {} {} {LY} 4-Chlorobutan-1-ol {} {} {} {} {} {} {} {} {} {LY} 4-Chlorobutan-1-ol {} {} {} {} {} {} {} {} {} {} {LY} 4-Chlorobutan-1-ol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Chlorobutan-1-ol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Chlorobutan-1-ol {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Chlorobutan-1-ol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Chlorobutan-1-ol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Chlorobutan-1-ol {} {} {} {} {}
MDL Number	MFCD00002967
CAS Number	928-51-8
EC Number	213-175-5
Beilstein Registry Number	1(2)398
PubChem Substance ID	87565322
Reaxys-RN	1731408
Chemical Name Translation	4-氯丁醇
Wiswesser Line Notation	Q4G
LabNetwork Molecule ID	LN00008802
InChI	InChI=1S/C4H9ClO/c5-3-1-2-4-6/h6H,1-4H2
Canonical SMILES	OCCCCCl

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安全信息

Signal word Warning

GHS Symbol

WGK Germany3

Safety Statements

S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
S36 Wear suitable protective clothing 穿戴适当的防护服；
S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；

Risk Statements

R10 Flammable 易燃
R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
R22 Harmful if swallowed 吞咽有害
R19 May form explosive peroxides 可能生成易爆的过氧化物质
R34 Causes burns 会导致灼伤
R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害

Precautionary statements

P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
P501 Dispose of contents/container to..… 处理内容物/容器.....
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P305+P351+P338
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P332+P313
P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医，如果你觉得不舒服
P301+P312+P330
P337+P313
P302+P352+P332+P313+P362+P364
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
P370+P378
P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P303+P361+P353
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
P305+P351+P338+P337+P313
P241+P242+P243
P233 Keep container tightly closed. ?保持容器密闭。
P403+P235

RTECSEL1325000

Hazard statements

H226 Flammable liquid and vapour 易燃液体和蒸气
H315 Causes skin irritation 会刺激皮肤
H302 Harmful if swallowed 吞食有害
H335 May cause respiratory irritation 可能导致呼吸道刺激
H351 Suspected of causing cancer 怀疑致癌
H319 Causes serious eye irritation 严重刺激眼睛
H290 May be corrosive to metals 可能腐蚀金属。

Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

Hazard Codes Xn Xn,C,F

UN Number 1987 1993 UN 2920 8/PG 2

Storage condition 2-8°C {LY} 2-8°C <0°C <;0 Store at room temperature {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {

Packing GroupIII

Hazard Class3

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 3650 mg/kg/8W-I
TOXIC EFFECTS :
   Tumorigenic - neoplastic by RTECS criteria
   Lungs, Thorax, or Respiration - tumors
REFERENCE :
   CNREA8 Cancer Research. (Public Ledger Building, Suit 816, 6th & Chestnut
   Sts., Philadelphia, PA 19106)  V.1-    1941-  Volume(issue)/page/year:
   39,391,1979

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : >100 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JOCEAH Journal of Organic Chemistry.  (American Chemical Soc., Distribution
   Office Dept. 223, POB 57136, West End Stn., Washington, DC 20037)  V.1-
   1936-  Volume(issue)/page/year: 21,739,1956

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 990 mg/kg
TOXIC EFFECTS :
   Behavioral - muscle contraction or spasticity
   Gastrointestinal - ulceration or bleeding from stomach
   Liver - other changes
REFERENCE :
   ZHYGAM Zeitschrift fuer die Gesamte Hygiene und Ihre Grenzgebiete.  (VEB
   Verlag Volk und Gesundheit, Neue Gruenstr. 18, Berlin DDR-1020, Ger. Dem.
   Rep.)  V.1-    1955-  Volume(issue)/page/year: 26,17,1980

其他信息

方法一:由四氢呋喃与氯化氢反应而得：在四氢呋喃沸腾的情况下，慢慢通入氯化氢气体。随着反应的进行，反应液温度逐渐升高，直至100℃以上。当温度停留在103.5-105.5℃稳定时，即反应结束。减压分馏，收集80-90℃（1.87kPa）馏分得粗品；再进行减压分馏，收集81-82℃（1.87kPa）馏分得成品，产率为54%-57%。
Sigma Aldrich:928-51-8(sigmaaldrich)
急性毒性:口服-小鼠 LD50: 990 毫克/公斤; 腹腔-小鼠 LD50: >; 100 毫克/公斤
Alfa Aesar:4-氯-1-丁醇,tech.85% 4-Chloro-1-butanol, tech. 85%(928-51-8)
4-氯-1-丁醇价格(试剂级):更新日期产品编号产品名称包装价格 2014/06/02 C0144 4-氯-1-丁醇(含有数量不等的四氢呋喃) 4-Chloro-1-butanol (contains varying amounts of Tetrahydrofuran) 25G 476元 2014/06/02 C0144 4-氯-1-丁醇(含有数量不等的四氢呋喃) 4-Chloro-1-butanol (contains varying amounts of Tetrahydrofuran) 500G 3310元 2010/06/21 356315000 4-氯-1-丁醇 4-Chloro-1-butanol 85%, balance THF and HCl 500 GR 7467元
图谱信息:4-氯-1-丁醇(928-51-8)Raman光谱 4-氯-1-丁醇(928-51-8)质谱(MS) 4-氯-1-丁醇(928-51-8)红外图谱(IR1) 4-氯-1-丁醇(928-51-8)核磁图( 13 CNMR)
MSDS 信息:4-Chloro-1-butanol(928-51-8).msds
毒性分级:中毒
TCI Shanghai:4-氯-1-丁醇(含有数量不等的四氢呋喃) 4-Chloro-1-butanol (contains varying amounts of Tetrahydrofuran),>;85.0%(GC)(928-51-8)
Acros Organics:4-氯-1-丁醇 4-Chloro-1-butanol, balance THF andHCl, 85%(928-51-8)
储运特性:库房低温通风干燥; 防明火, 防高温, 与氧化剂分开存放
类别:易燃液体
可燃性危险特性:遇热, 明火, 氧化剂燃烧; 热分解排出有毒氯化物烟雾
MOL 文件:928-51-8.mol
用途二:用于有机合成。
用途一:用作有机合成中间体
海关编码:29055910
下游产品:1-(4-(吡咯烷-1-基)丁基)肼 --> 1-(4-吗啉基丁基)肼 --> 4-氨基-1-丁醇
Hazard Note:Harmful
灭火剂:雾水,二氧化碳, 泡沫, 干粉