2-Allylphenol 2-烯丙基苯酚

CAS 1745-81-9 MFCD00002250

化学结构图

1745-81-9
SMILES: C=CCc1ccccc1O

化学属性

Mol. FormulaC9H10O
Mol. Weight134.17
Refractive index1.5430 to 1.5470
Boiling Point220 °C at 760 mmHg
Density1.02
Flash Point88°C(lit.)
TSCAYes
Melting Point-6 °C
Solubility7 G/L (20 ºC)

别名和识别编码

Chemical Name2-Allylphenol
CAS Number1745-81-9
PubChem Substance ID15624
EC Number217-119-0
Beilstein Registry Number742121
MDL NumberMFCD00002250
Reaxys-RN742121
Synonym 2-(Prop-2-en-1-yl)phenol {LY} 2-(Prop-2-en-1-yl)phenol 2-allylphenol 2-allylphenol potassium 2-allylphenol sodium {} {LY} 2-(Prop-2-en-1-yl)phenol {} {} {LY} 2-(Prop-2-en-1-yl)phenol {} {} {} {LY} 2-(Prop-2-en-1-yl)phenol {} {} {} {} {LY} 2-(Prop-2-en-1-yl)phenol {} {} {} {} {} {LY} 2-(Prop-2-en-1-yl)phenol {} {} {} {} {} {} {LY} 2-(Prop-2-en-1-yl)phenol {} {} {} {} {} {} {} {LY} 2-(Prop-2-en-1-yl)phenol {} {} {} {} {} {} {} {} {LY} 2-(Prop-2-en-1-yl)phenol {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {LY} 2-(Prop-2-en-1-yl)phenol {} {} {} {} {} {} {} {} {} {} {LY} 2-(Prop-2-en-1-yl)phenol {} {} {} {} {} {} {} {} {} {} {} {LY} 2-(Prop-2-en-1-yl)phenol {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-(Prop-2-en-1-yl)phenol {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-(Prop-2-en-1-yl)phenol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-(Prop-2-en-1-yl)phenol {} {} {} {} {} {} {} {} {}
Alfabeta NameALLYLPHENOL 2-
Chemical Name Translation2-烯丙基苯酚
Wiswesser Line NotationQR B2U1
LabNetwork Molecule IDLN00335274
InChIInChI=1S/C9H10O/c1-2-5-8-6-3-4-7-9(8)10/h2-4,6-7,10H,1,5H2
Canonical SMILESC=CCC1=CC=CC=C1O
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分类

  • {SNA} Building Blocks, C9 to C20+, Chemical Synthesis, Organic Building Blocks, Oxygen Compounds, Phenols
  • {SA} Building Blocks, C9 to C20+, Chemical Synthesis, Organic Building Blocks, Oxygen Compounds, Phenols
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; alcohol; 1fragment
  • Building Blocks, C9 to C20+, Chemical Synthesis, Organic Building Blocks, Oxygen Compounds, Phenols

相关文献及参考

  • Short: IV/18B
  • Short: EINECS
  • Undergoes phosphine-free Pd-catalyzed cross-coupling with vinylic halides and triflates to give dihydrobenzopyrans: Tetrahedron Lett., 39, 237 (1998); for reaction scheme, see Palladium(II)­ acetate, 10516.
  • Short: III/38B

安全信息

GHS Symbol
WGK Germany1
Hazard statements
  • H227 Combustible liquid 可燃液体
  • H301 Toxic if swallowed 吞食有毒
  • H301+H311
  • H311 Toxic in contact with skin 皮肤接触中毒
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H318 Causes serious eye damage 严重伤害眼睛
  • H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes 8 C C,Xi
RTECSSJ3850000
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛,皮肤或衣服。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P310
  • P301+P312
  • P301+P316
  • P301+P330+P331
  • P301+P330+P331+P310
  • P302+P352
  • P302+P361+P354
  • P303+P361+P353
  • P303+P361+P353+P310+P363
  • P304+P340
  • P304+P340+P310
  • P305+P351+P338
  • P305+P351+P338+P310
  • P305+P354+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P316
  • P317
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P322 Specific measures (see …on this label). 具体治疗(见本标签上的)。
  • P330 Rinse mouth. 漱口
  • P361 Remove/Take off immediately all contaminated clothing. 立即去除/脱掉所有被污染的衣服。
  • P361+P364
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P370+P378
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
UN Number 1760 2923
Risk Statements
  • R21/22 Harmful in contact with skin and if swallowed 皮肤接触和不慎吞咽有害
  • R34 Causes burns 会导致灼伤
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
Packing GroupIII
Warnings IRRITANT
Hazard Class8
TYPE OF TEST            : TD - Toxic dose (other than lowest)
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 3360 mg/kg/12W-I
TOXIC EFFECTS :
   Tumorigenic - neoplastic by RTECS criteria
   Skin and Appendages - tumors
REFERENCE :
   CNREA8 Cancer Research. (Public Ledger Building, Suit 816, 6th & Chestnut
   Sts., Philadelphia, PA 19106)  V.1-    1941-  Volume(issue)/page/year:
   19,413,1959

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 8400 mg/kg/30W-I
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Skin and Appendages - tumors
REFERENCE :
   CNREA8 Cancer Research. (Public Ledger Building, Suit 816, 6th & Chestnut
   Sts., Philadelphia, PA 19106)  V.1-    1941-  Volume(issue)/page/year:
   19,413,1959

Storage condition 2-8°C, stored under nitrogen {LY} 2-8°C, stored under nitrogen {} {LY} 2-8°C, stored under nitrogen {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitro

其他信息

  • Sigma Aldrich:1745-81-9(sigmaaldrich)
  • 2-烯丙基酚价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 A0233 2-烯丙基苯酚 2-Allylphenol 25G 113元 2014/06/02 A0233 2-烯丙基苯酚 2-Allylphenol 500G 877元 2010/06/21 102995000 2-烯丙基酚 2-Allylphenol 99+% 500 GR 1190元
  • 毒性分级:高毒
  • Acros Organics:2-烯丙基苯酚 2-Allylphenol,99+%(1745-81-9)
  • TCI Shanghai:2-烯丙基苯酚 2-Allylphenol,>;97.0%(GC)(1745-81-9)
  • 可燃性危险特性:可燃;燃烧产生刺激烟雾
  • Alfa Aesar:2-丙烯基苯酚,98+% 2-Allylphenol, 98+%(1745-81-9)
  • 急性毒性:腹腔-小鼠LDL0: 256 毫克/公斤
  • MSDS 信息:2-Allylphenol(1745-81-9).msds
  • 储运特性:库房通风低温干燥; 与食品原料分开存放
  • 海关编码:29071900
  • 灭火剂:干粉、泡沫、砂土、二氧化碳, 雾状水
  • MOL 文件:1745-81-9.mol
  • 图谱信息:2-烯丙基酚(1745-81-9)Raman光谱 2-烯丙基酚(1745-81-9)红外图谱(IR1) 2-烯丙基酚(1745-81-9)质谱(MS) 2-烯丙基酚(1745-81-9)核磁图( 1 HNMR) 2-烯丙基酚(1745-81-9)核磁图( 13 CNMR)
  • 类别:有毒物品

系列性分类


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