CAS 106-95-6 MFCD00000244-Allyl bromide 3-溴丙烯(烯丙基溴) TAO{mole}

Allyl bromide 3-溴丙烯(烯丙基溴)

CAS 106-95-6 MFCD00000244

化学结构图

SMILES: C=CCBr

化学属性

Mol. Formula	C3H5Br
Mol. Weight	120.98
Refractive index	1.4650 to 1.4710
Boiling Point
Density	1.398
Melting Point	No Data Available
Flash Point	-2.22°C
TSCA	Yes
Autoignition Point	554 °F
Vapor Density	4.2 (vs air)
Solubility	不溶于水，溶于乙醇、乙醚、氯仿、四氯化碳、二硫化碳等多数有机溶剂。
Stability	对热、光线和空气敏感
Danger-Level	-
pH	-:-
Redox	-

别名和识别编码

Chemical Name	Allyl bromide
Synonym	3-Bromo-1-propene 3-Brompropen 3-bromo-1-propen 3-bromo-1-propene 3-bromo-propen 3-溴-1-丙烯 3-溴-1-丙烯,烯丙基溴 3-溴丙烯 3-溴代丙烯 3-溴烯丙烯 Allyl Bromide (Stabilized with Propylene Oxide) {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
CAS Number	106-95-6
PubChem Substance ID	7841
EC Number	203-446-6
Beilstein Registry Number	605308
MDL Number	MFCD00000244
Reaxys-RN	605308
Merck Number	288
Chemical Name Translation	3-溴丙烯(烯丙基溴)
Wiswesser Line Notation	E2U1
LabNetwork Molecule ID	LN00196351
InChI	InChI=1S/C3H5Br/c1-2-3-4/h2H,1,3H2
Canonical SMILES	C=CCBr

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产品应用

本品用于有机合成，可用合成染料、香料；医药工业用于制“西可巴比妥”药物；农业用作土壤熏蒸剂。

安全信息

GHS Symbol

WGK Germany3

Hazard Codes 3 F,T,N

Hazard statements

H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
H300 Fatal if swallowed 吞食致命
H301 Toxic if swallowed 吞食有毒
H310 Fatal in contact with skin 皮肤接触致命
H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
H315 Causes skin irritation 会刺激皮肤
H319 Causes serious eye irritation 严重刺激眼睛
H330 Fatal if inhaled 吸入致命
H331 Toxic if inhaled 吸入中毒
H335 May cause respiratory irritation 可能导致呼吸道刺激
H340 May cause genetic defects 可能导致遗传性缺陷
H350 May cause cancer 可能致癌
H400 Verytoxictoaquaticlife 对水生生物毒性非常大。

Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

RTECSUC7090000

Precautionary statements

P201 Obtain special instructions before use. 使用前获取专门指示。
P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
P233 Keep container tightly closed. ?保持容器密闭。
P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
P241+P242+P243
P242 Use only non-sparking tools. 只能使用无火花工具。
P243 Take precautionary measures against static discharge. 采取预防措施，防止静电放电。
P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛，皮肤或衣服。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
P273 Avoid release to the environment. 避免释放到环境中。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P281 Use personal protective equipment as required. 使用所需的个人防护装备。
P284 Wear respiratory protection.? 佩戴呼吸保护装置。
P301+P310
P301+P330+P331
P301+P330+P331+P310
P302+P350
P302+P352
P303+P361+P353
P303+P361+P353+P310+P363
P304+P340
P304+P340+P310
P305+P351+P338
P305+P351+P338+P310
P308+P313
P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
P320 Specific treatment is urgent (see … on this label). 紧急具体治疗（见本标签上的）。
P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
P322 Specific measures (see …on this label). 具体治疗（见本标签上的）。
P330 Rinse mouth. 漱口
P332+P313
P337+P313
P361 Remove/Take off immediately all contaminated clothing. 立即去除/脱掉所有被污染的衣服。
P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
P370+P378
P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
P403+P233
P403+P235
P405 Store locked up. 上锁保管。
P501 Dispose of contents/container to..… 处理内容物/容器.....

Signal word Danger

Safety Statements

S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
S53 Avoid exposure - obtain special instructions before use 避免接触，使用前获得特别指示说明；
S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；

Risk Statements

R11 Highly flammable 非常易燃
R23/25 Toxic by inhalation and if swallowed 吸入及吞食都有毒
R25 Toxic if swallowed 吞咽有毒
R34 Causes burns 会导致灼伤
R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
R45 May cause cancer 可能致癌
R46 May cause inheritable genetic damage 可能引起遗传基因损害
R50 Very toxic to aquatic organisms 对水生生物极毒

UN Number 1099 UN1099

Storage condition +4°C 2-8°C 4 4℃ Light Sensitive {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {

Packing GroupI

Hazard Class3/6.1

Warnings 危化品目录(2015)

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Mammal - species unspecified
DOSE/DURATION           : 4110 mg/m3
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 18(4),55,1974

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 120 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JJATDK JAT, Journal of Applied Toxicology.  (John Wiley & Sons Ltd., Baffins
   Lane, Chichester, W. Sussex PO19 1UD, UK)  V.1-    1981-
   Volume(issue)/page/year: 9,235,1989

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 10 gm/m3/30M
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   FAVUAI Fiziologicheski Aktivnye Veshchestva.  Physiologically Active
   Substances.  (Izdatel'stvo Naukova Dumka, Kiev, USSR)  No.1-    1966-
   Volume(issue)/page/year: 7,35,1975

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 48 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-

TYPE OF TEST            : Unscheduled DNA synthesis
TEST SYSTEM             : Human HeLa cell
DOSE/DURATION           : 500 umol/L
REFERENCE :
   CALEDQ Cancer Letters (Shannon, Ireland).  (Elsevier Scientific Pub. Ireland
   Ltd., POB 85, Limerick, Ireland)  V.1-    1975- Volume(issue)/page/year:
   20,263,1983

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 1 umol/plate
REFERENCE :
   BCPCA6 Biochemical Pharmacology.  (Pergamon Press Inc., Maxwell House,
   Fairview Park, Elmsford, NY 10523)  V.1-    1958-  Volume(issue)/page/year:
   29,993,1980

Restrict -

其他信息

用途一:用作医药中间体
图谱信息:3-溴丙烯(106-95-6)核磁图( 13 CNMR) 3-溴丙烯(106-95-6)质谱(MS) 3-溴丙烯(106-95-6)核磁图( 1 HNMR) 3-溴丙烯(106-95-6)红外图谱(IR1)
下游产品:佛手苷内酯 --> 丁香酚 --> 茴香脑 --> 1-辛烯 --> 异硫氰酸烯丙酯 --> 花椒毒醇 --> 3-羟基-3-甲基谷氨酸 --> 尼多克罗 --> 氯哌噻吨 --> 烯丙苯 --> 氟咯草酮 --> 2-甲氧基-3-溴丙烯 --> 罗库溴铵 --> 4-烯丙基苯甲醚 --> 烯丙基腈 --> 烯丙基三甲基硅烷
Acros Organics:烯丙基溴 Allylbromide,stabilized,99%(106-95-6)
储运特性:库房通风低温干燥; 与氧化剂分开存放
灭火剂:干粉、干砂、二氧化碳、泡沫、1211灭火剂
爆炸物危险特性:与空气混合可爆
可燃性危险特性:遇明火、高温、氧化剂易燃; 高热分解有毒溴化物气体
有不愉快刺激气味。能与乙醇、氯仿、乙醚、二硫化碳和四氯化碳混溶，微溶于水。半数致死量(小鼠，腹腔)108mg/kg。有催泪性和腐蚀性。商品一般加有银绒作稳定剂。
MSDS 信息:烯丙基溴(106-95-6).msds
用途三:本品用于有机合成，可用合成染料、香料；医药工业用于制“西可巴比妥”药物；农业用作土壤熏蒸剂。
F:8-19
急性毒性:口服- 大鼠 LD50: 120 毫克/ 公斤; 腹腔- 小鼠 LD50: 48 毫克/ 公斤
类别:易燃液体
蒸气密度:4.2 (vs air)
3-溴丙烯价格(试剂级):更新日期产品编号产品名称包装价格 2011/08/23 80002126 烯丙基溴;溴丙烯;3-溴-1-丙烯 100ml 186元 2011/04/16 B0643 烯丙基溴 Allyl Bromide 25G 160元 2011/04/16 B0643 烯丙基溴 Allyl Bromide 500G 660元
方法一:1.由烯丙醇溴化而得：向反应罐投入氢溴酸，在搅拌下加入硫酸、烯丙醇。升温回流2h，加热至8℃时有馏液蒸出，收集68-73℃馏分。水洗后，用无水硫酸钠脱水，过滤，得烯丙基溴。2.丙烯溴化法。
外观性质:无色到淡黄色液体，有令人不愉快的刺激性气味。
用途二:用于有机合成如合成染料、香料；医药工业上用于西可巴比妥的制造；农业上用作土壤熏蒸剂。
Sigma Aldrich:106-95-6(sigmaaldrich)
Alfa Aesar:3-溴-1-丙烯,烯丙基溴,99% Allyl bromide, 99%(106-95-6)
毒性分级:高毒
上游原料:丙烯醇
海关编码:29033036
TCI Shanghai:烯丙基溴 Allyl Bromide,>;98.0%(GC)(106-95-6)
MOL 文件:106-95-6.mol