CAS 90-43-7 MFCD00002208-2-Phenylphenol 2-苯基苯酚 TAO{mole}

2-Phenylphenol 2-苯基苯酚

CAS 90-43-7 MFCD00002208

化学结构图

SMILES: Oc1ccccc1-c1ccccc1

化学属性

Mol. Formula	C12H10O
Mol. Weight	170.21
Boiling Point	282
Melting Point	57-59
Density	1.213
Flash Point	124°(255°F)
TSCA	Yes
Vapor Pressure	7 mmHg ( 140 °C)
Solubility	0.7 G/L (20 ºC)

别名和识别编码

Chemical Name	2-Phenylphenol
Synonym	[1,1'-Biphenyl]-2-ol {LY} [1,1'-Biphenyl]-2-ol o-Biphenylol o-Hydroxybiphenyl phenylphenol, o- {} {LY} [1,1'-Biphenyl]-2-ol {} {} {LY} [1,1'-Biphenyl]-2-ol {} {} {} {LY} [1,1'-Biphenyl]-2-ol {} {} {} {} {LY} [1,1'-Biphenyl]-2-ol {} {} {} {} {} {LY} [1,1'-Biphenyl]-2-ol {} {} {} {} {} {} {LY} [1,1'-Biphenyl]-2-ol {} {} {} {} {} {} {} {LY} [1,1'-Biphenyl]-2-ol {} {} {} {} {} {} {} {} {LY} [1,1'-Biphenyl]-2-ol {} {} {} {} {} {} {} {} {} {LY} [1,1'-Biphenyl]-2-ol {} {} {} {} {} {} {} {} {} {} {LY} [1,1'-Biphenyl]-2-ol {} {} {} {} {} {} {} {} {} {} {} {LY} [1,1'-Biphenyl]-2-ol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} [1,1'-Biphenyl]-2-ol {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} [1,1'-Biphenyl]-2-ol {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} [1,1'-Biphenyl]-2-ol {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {}
CAS Number	90-43-7
PubChem Substance ID	7017
EC Number	201-993-5
Beilstein Registry Number	606907
MDL Number	MFCD00002208
Reaxys-RN	606907
Merck Number	7304
Chemical Name Translation	2-苯基苯酚
Wiswesser Line Notation	QR BR
LabNetwork Molecule ID	LN00193965
InChI	InChI=1S/C12H10O/c13-12-9-5-4-8-11(12)10-6-2-1-3-7-10/h1-9,13H
Canonical SMILES	OC1=C(C2=CC=CC=C2)C=CC=C1

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分类

{SNA} Al
{SNA} 2000/60/EC, Additional Standards, All Fungicides, Alphabetical, Analytical Standards, Chemical Class, E numbers (Food Additives), E200–E299 (preservatives), E231, EPA, Endocrine Disruptors (Draft), European Community: ISO, DIN and DL 152, Flavor and Fragrance Standards, Fluorescent Indicators and Probes, Food & Beverage Standards, Food and Cosmetic Component Standards, Fruits, Fungicides, Lemon, Lipophilic and Membrane Probes, M-R, M-Z, Method and Regulation Specific, N-P, Oeko-Tex Standard 100,

产品应用

荧光测定丙糖（trioses）的试剂。

安全信息

GHS Symbol

WGK Germany2

Hazard statements

H302 Harmful if swallowed 吞食有害
H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
H315 Causes skin irritation 会刺激皮肤
H319 Causes serious eye irritation 严重刺激眼睛
H335 May cause respiratory irritation 可能导致呼吸道刺激

Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves

Hazard Codes

RTECSDV5775000

Precautionary statements

P403 Store in a well-ventilated place. 储存在通风良好的地方。
P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P332+P313
P501 Dispose of contents/container to..… 处理内容物/容器.....
P301+P312+P330
P273 Avoid release to the environment. 避免释放到环境中。
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P305+P351+P338
P302+P350
P337+P313

Signal word

UN Number UN3077

Safety Statements

S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
S22 Do not breathe dust 不要吸入粉尘；

Risk Statements

R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
R50 Very toxic to aquatic organisms 对水生生物极毒

Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

Packing GroupIII

Hazard Class9

Warnings 危化品目录(2015)

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 478 gm/kg/91W-C
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Liver - tumors
REFERENCE :
   FCTOD7 Food and Chemical Toxicology.  (Pergamon Press Inc., Maxwell House,
   Fairview Park, Elmsford, NY 10523)  V.20-    1982- Volume(issue)/page/year:
   22,865,1984

TYPE OF TEST            : TD - Toxic dose (other than lowest)
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 478 gm/kg/91W-C
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Kidney, Ureter, Bladder - tumors
REFERENCE :
   FCTOD7 Food and Chemical Toxicology.  (Pergamon Press Inc., Maxwell House,
   Fairview Park, Elmsford, NY 10523)  V.20-    1982- Volume(issue)/page/year:
   22,865,1984

TYPE OF TEST            : TD - Toxic dose (other than lowest)
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 135 gm/kg/26W-C
TOXIC EFFECTS :
   Tumorigenic - neoplastic by RTECS criteria
   Kidney, Ureter, Bladder - tumors
REFERENCE :
   FCTOD7 Food and Chemical Toxicology.  (Pergamon Press Inc., Maxwell House,
   Fairview Park, Elmsford, NY 10523)  V.20-    1982- Volume(issue)/page/year:
   25,359,1987

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Unreported
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 2700 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   TRENAF Kenkyu Nenpo--Tokyo-toritsu Eisei Kenkyusho.  Annual Report of Tokyo
   Metropolitan Research Laboratory of Public Health.  (Tokyo-toritsu Eisei
   Kenkyusho, 24-1, 3-chome, Hyakunin-cho, Shin-juku-ku, Tokyo 160, Japan) V.1-
      1949/50-  Volume(issue)/page/year: 29,89,1978

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1050 mg/kg
TOXIC EFFECTS :
   Behavioral - ataxia
   Cardiac - other changes
   Lungs, Thorax, or Respiration - respiratory depression
REFERENCE :
   NAIZAM Nara Igaku Zasshi.  Journal of the Nara Medical Association.  (Nara
   Igakkai, c/o Narakenritsu Ika Daigaku, Shijo-cho, Kashihara, Nara-ken,
   Japan)  V.1-    1950-  Volume(issue)/page/year: 32,425,1981

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 50 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: AD277-689

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 2 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NNGADV Nippon Noyaku Gakkaishi.  Journal of the Pesticide Science Society of
   Japan.  (Nippon

TYPE OF TEST            : Cytogenetic analysis
TEST SYSTEM             : Human Fibroblast
DOSE/DURATION           : 200 ug/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 54,255,1978

TYPE OF TEST            : Unscheduled DNA synthesis
ROUTE OF EXPOSURE       : Oral
TEST SYSTEM             : Rodent - rat
DOSE/DURATION           : 336 gm/kg/4W (Continuous)
REFERENCE :
   CALEDQ Cancer Letters (Shannon, Ireland).  (Elsevier Scientific Pub. Ireland
   Ltd., POB 85, Limerick, Ireland)  V.1-    1975- Volume(issue)/page/year:
   48,19,1989

TYPE OF TEST            : Mutation in mammalian somatic cells
TEST SYSTEM             : Human Embryo
DOSE/DURATION           : 20 mg/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 156,123,1985

TYPE OF TEST            : DNA damage
ROUTE OF EXPOSURE       : Oral
TEST SYSTEM             : Rodent - mouse
DOSE/DURATION           : 2 gm/kg
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 395,189,1997

TYPE OF TEST            : Sister chromatid exchange
TEST SYSTEM             : Rodent - hamster Ovary
DOSE/DURATION           : 29900 ug/L
REFERENCE :
   NTPTR* National Toxicology Program Technical Report Series.  (Research
   Triangle Park, NC 27709) No.206-  Volume(issue)/page/year: NTP-TR-301,1986

TYPE OF

TYPE OF TEST            : Cytogenetic analysis
TEST SYSTEM             : Rodent - hamster Ovary
DOSE/DURATION           : 100 mg/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 141,95,1984

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 6 gm/kg
SEX/DURATION            : female 6-15 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death,
   e.g., stunted fetus)
   Reproductive - Effects on Embryo or Fetus - fetal death
REFERENCE :
   NNGADV Nippon Noyaku Gakkaishi.  Journal of the Pesticide Science Society of
   Japan.  (Nippon Noyaku Gakkai, 1-43-11, Komagome, Toshima-ku, Tokyo 170,
   Japan)  V.1-    1976-  Volume(issue)/page/year: 3,365,1978

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE                    : 13050 mg/kg
SEX/DURATION            : female 7-15 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death,
   e.g., stunted fetus)
REFERENCE :
   TRENAF Kenkyu Nenpo--Tokyo-toritsu Eisei Kenkyusho.  Annual Report of Tokyo
   Metropolitan Research Laboratory of Public Health.  (Tokyo-toritsu Eisei
   Kenkyusho, 24-1, 3-chome, Hyakunin-cho, Shin-juku-ku, Tokyo 160, Japan) V.1-
      1949/50-  Volume(issue)/page/year: 29,89,1978

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE                    : 13050 mg/kg
SEX/DURATION            : female 7-15 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Specific Developmental Abnormalities - Central Nervous System
   Reproductive - Specific Developmental Abnormalities - eye/ear
   Reproductive - Specific Developmental Abnormalities - musculoskeletal system
REFERENCE :
   TRENAF Kenkyu Nenpo--Tokyo-toritsu Eisei Kenkyusho.  Annual Report of Tokyo
   Metropolitan Research Laboratory of Public Health.  (Tokyo-toritsu Eisei
   K

Restrict 危险品

其他信息

用途四:防霉剂；果蔬保鲜剂。主要用于柑橘类表皮的防霉。欧洲经济共同体各国及美国除柑橘外，尚用于黄瓜、胡萝卜、苹果、甜瓜、番茄等。日本仅限用于柑橘类，最大残留量0.01g/kg(1990)。各国的使用情况如下(允许用量，mg/kg)加拿大樱桃，5；柑橘类、黄瓜、胡椒、菠萝、番茄，10；甘薯，15；胡萝卜、桃、李属水果，20；苹果、梨，25；甜瓜，12。欧共体柑橘类，12。荷兰柑橘类，10。英国柑橘类，70；苹果、梨、菠萝，10；甜瓜，125．美国
可燃性危险特性:可燃; 燃烧产生刺激烟雾
方法五:可由磺化法生产苯酚的蒸馏残渣中回收。苯酚的蒸馏残渣含苯基苯酚40%左右，其它成分为苯酚、无机盐、水等。经真空蒸馏，分离出混位苯基苯酚馏分段，真空度为53.3-66.7kPa，温度在65-75℃开始截取至100℃以上，但不得超过1345℃。再利用邻、对位羟基联苯在三氯乙烯中溶解度的不同，将二者分离为纯净物。将混合位物（主要2-羟基联苯和4-羟基联苯）加热溶解于三氯乙烯中，经冷却，先析出4-羟基联苯结晶，经离心过滤、干燥得至4-羟基联苯。母液用碳酸钠溶液洗涤，再加稀碱液使2-羟基联苯成盐。静置分层后，取上层2-羟基联苯钠盐减压脱水，即得钠盐成品。2-羟基联苯钠盐为白色至淡红色粉末。极易溶于水，在100g水中可溶122g，2%的水溶液pH为11.1-12.2。亦易溶于丙酮、甲醇，溶于甘油，但不溶于油脂。2-羟基联苯钠盐经酸化可制得2-羟基联苯，两者都是食品添加剂。
刺激数据:皮肤- 兔子 20 毫克/ 24小时中度; 眼睛- 兔子 0.05 毫克/ 24小时重度
用途六:2-羟基联苯用作疏水性合成纤维氯纶、涤纶等采用
用途五:本品用于强
溶于大多数有机溶剂；几乎不溶于水，溶解度：0.7 g/l(20°C)水,800 g/l异丙醇；微有特殊气味。
邻苯基苯酚价格(试剂级):更新日期产品编号产品名称包装价格 2014/06/02 P0200 2-苯基苯酚 2-Phenylphenol 500G 442元 2014/06/02 P0200 2-苯基苯酚 2-Phenylphenol 25G 117元 2010/06/21 130760050 邻苯基苯酚
用途三:作为防腐杀菌剂，我国规定还可用于柑橘保鲜，最大使用量为3.0g/kg，残留量不大于12mg/kg。
用途四:防霉剂；果蔬保鲜剂。主要用于柑橘类表皮的防霉。欧洲经济共同体
所属类别一:皮革化学品: 邻苯基苯酚
灭火剂:干粉、泡沫、砂土
方法二:磺化法生产苯酚的蒸馏残渣中约含有40%的混位（对位和邻位）苯基苯酚。根据其在三氯乙烯中溶解度的不同，将蒸馏残渣在53.3-66.7KPa的真空度下减压分馏，收集65-100℃馏分，即为混位苯基苯酚。将混位物加热溶解于三氯乙烯中，冷却后鲜析出对位苯基苯酚。离心过滤后，用碳酸钠溶液洗涤母液，使邻苯基苯酚成为钠盐，静置后取上层钠盐，经酸化后即得产品。
爆炸物危险特性:与空气混合可爆
参考
方法二:磺化法生产苯酚的蒸馏
所属类别三:饲料添加剂: 饲料贮存添加剂
溶于大多数有机溶剂；几乎不溶于水，
所属类别四:食品添加剂: 防腐剂
含量分析:精确称取粉末状试样约2g，加氢氧化钠试液(TS-224)25ml，必要时可温热溶解，冷却后加水至500ml，以此作为试样液。取此试样液25ml移入碘瓶，准确加入0.1mol
Sigma Aldrich:90-43-7(sigmaaldrich)
邻苯基苯酚价格(试
外观性质:白色或褐色的絮状物, 具有特殊气味。
使用限量:GB 2760
方法四:从磺化法生产苯酚的副产物中得到邻苯基苯酚和对苯基苯酚的混合物，将其加热溶于三氯乙烯中，经冷却析出对位苯基苯酚结晶，经离心过滤，固体干燥得对苯基苯酚。母液用碳酸钠溶液洗涤后，加稀氢氧化钠中和，再酸化得邻苯基苯酚。