Iodoethane 碘乙烷
CAS 75-03-6 MFCD00001091
信息真实价格透明
资金保障
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信息真实价格透明
资金保障
专业采购外包团队在线服务
品牌质保精细包装
现货库存
一流品牌服务
分类
- {uni_hamburg} no charge; 1fragment
- {SNA} Essential Chemicals, Inorganic Salts, Solutions and Reagents, Reagent Plus, Research Essentials
产品应用
- A useful synthetic reagent for the introduction of ethyl groups
相关文献及参考
- Short: II/19c
- Merck: 14,3813 Beilstein:1,96
- Merck: 14,3813
- Short: II/19b
- Short: II/14a
安全信息
GHS Symbol
- S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
- S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾;
- S24 Avoid contact with skin 避免皮肤接触;
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
- S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
- S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
- R10 Flammable 易燃
- R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
- R20/22 Harmful by inhalation and if swallowed 吸入和不慎吞咽有害
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- R37/38 Irritating to respiratory system and skin 对呼吸系统和皮肤有刺激性
- R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
- R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P233 Keep container tightly closed. ?保持容器密闭。
- P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
- P241+P242+P243
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
- P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P284 Wear respiratory protection.? 佩戴呼吸保护装置。
- P301+P312
- P301+P312+P330
- P302+P352
- P302+P352+P333+P313+P362+P364
- P303+P361+P353
- P304+P340
- P305+P351+P338
- P305+P351+P338+P337+P313
- P308+P311
- P337+P313
- P342+P311
- P403+P235
- P405 Store locked up. 上锁保管。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- H226 Flammable liquid and vapour 易燃液体和蒸气
- H315 Causes skin irritation 会刺激皮肤
- H317 May cause an allergic skin reaction 可能导致皮肤过敏
- H302 Harmful if swallowed 吞食有害
- H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled 吸入可能导致过敏或哮喘症状或呼吸困难
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- H319 Causes serious eye irritation 严重刺激眼睛
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intraperitoneal SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 560 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : 85GMAT "Toxicometric Parameters
TYPE OF TEST : LC50 - Lethal concentration, 50 percent kill ROUTE OF EXPOSURE : Inhalation SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 65 gm/m3/30M TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : FAVUAI Fiziologicheski Aktivnye Veshchestva. Physiologically Active Substances. (Izdatel'stvo Naukova Dumka, Kiev, USSR) No.1- 1966- Volume(issue)/page/year: 7,35,1975
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Subcutaneous SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 1 gm/kg TOXIC EFFECTS : Peripheral Nerve and Sensation - flaccid paralysis without anesthesia (usually neuromuscular blockage) Lungs, Thorax, or Respiration - respiratory stimulation Lungs, Thorax, or Respiration - other changes REFERENCE : JJPAAZ Japanese Journal of Pharmacology. (Japanese Pharmacological Soc., c/o Dept. of Pharmacology, Faculty of Medicine, Kyoto Univ., Sakyo-ku, Kyoto 606, Japan) V.1- 1951- Volume(issue)/page/year: 3,99,1954
TYPE OF TEST : LDLo - Lowest published lethal dose ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rabbit DOSE/DURATION : 300 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : 38MKAJ "Patty's Industrial Hygiene and Toxicology," 3rd rev. ed., Clayton, G.D., and F.E. Clayton, eds., New York, John Wiley & Sons, Inc., 1978-82. Vol. 3 originally pub. in 1979; pub. as 2nd rev. ed. in
TYPE OF TEST : Mutation in microorganisms TEST SYSTEM : Bacteria - Escherichia coli DOSE/DURATION : 20 umol/L REFERENCE : ARTODN Archives of Toxicology. (Springer-Verlag, Heidelberger Pl. 3, D-1000 Berlin 33, Fed. Rep. Ger.) V.32- 1974- Volume(issue)/page/year: 46,277,1980
TYPE OF TEST : DNA damage TEST SYSTEM : Bacteria - Escherichia coli DOSE/DURATION : 1 umol/L REFERENCE : ARTODN Archives of Toxicology. (Springer-Verlag, Heidelberger Pl. 3, D-1000 Berlin 33, Fed. Rep. Ger.) V.32- 1974- Volume(issue)/page/year: 46,277,1980
其他信息
- 外观性质:无色澄清重质液体,有醚的气味。
- 用途一:用作分析试剂,也用于有机合成
- 蒸气密度:5.38 (vs air)
- 用途四:测定矿物折射指数,校正折光计,分离矿物,心脏血液排出量测定。用作化学试剂、医药用助渗剂(测定心血液输出量)。也用于有机合成和用作试剂。甲状腺肿治疗药,植物生长刺激素等。
- 上游原料:红磷 --> 黄磷 --> 工业乙醇
- 图谱信息:碘乙烷(75-03-6)核磁图( 13 CNMR) 碘乙烷(75-03-6)红外图谱(IR2) 碘乙烷(75-03-6)核磁图( 1 HNMR) 碘乙烷(75-03-6)红外图谱(IR1) 碘乙烷(75-03-6)质谱(MS)
- MSDS 信息:碘乙烷(75-03-6).msds
- 类别:有毒物品
- TCI Shanghai:碘乙烷(含稳定剂铜屑) Iodoethane (stabilized with Copper chip),>;99.0%(GC)(75-03-6)
- 灭火剂:泡沫、干粉、砂土
- 下游产品:2-甲基-4-羧基吡啶 --> 碱性红 1 --> 2-乙氧基苯甲酸 --> 1-BOC-4-乙基-4-哌啶甲酸 --> 5-乙基-2-糠醛 --> 3-苯基环氧乙烷甲酸乙酯 --> 3-乙氧基-1,2-丙二胺 --> 非那西丁 --> 邻苯二乙醚 --> 四碘甲烷 --> 1-乙基-6,7-亚甲氧基-4-喹啉酮-3-羧酸 --> 2-乙酰基-3-乙基吡嗪 --> 加拉碘铵
- 有醚样气味,质重,具强折光性,在空气及光线下能游离碘,使溶液成黄色至红色(加入汞粒或银箔振摇可以除去颜色),久置变红。溶于乙醇、乙醚,能与大多数有机溶剂混溶,微溶于水并逐渐分解。
- 敏感性:Light Sensitive
- Alfa Aesar:碘乙烷,98+%,与铜稳定 Iodoethane, 98+%, stab. with copper(75-03-6)
- 方法一:由乙醇与三碘化磷反应而得。将工业乙醇和赤磷放入反应瓶内,在水浴上加热回流,缓缓加入碘粒。加毕,继续回流3h。然后将反应液蒸馏,蒸出黄色粗品,经洗涤,干燥而得成品。另外,由乙烯与碘化氢加成也可制取碘乙烷。
- MOL 文件:75-03-6.mol
- 可燃性危险特性:明火、高热可燃; 高热分解或与水、氧化剂反应生成有毒碘化物气体
- 碘乙烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 80062616 碘乙烷;乙基碘 100ml 156元 2011/08/23 80062780 碘乙烷;乙基碘 25ml 138.1元 2011/04/16 I0058 碘乙烷(含稳定剂铜屑) Iodoethane (stabilized with Copper chip) 500G 1280元
- 用途二:在有机合成中广泛用作乙基化试剂,医药工业中用作助诊剂
- 蒸气压:100 mm Hg ( 18 °C)
- 储运特性:库房通风低温干燥; 与氧化剂、食品添加剂分开存放
- 急性毒性:腹腔- 大鼠 LD50: 330 毫克/ 公斤; 腹腔- 小鼠 LD50: 560 毫克/ 公斤
- 毒性分级:高毒
- F:1-8
- Sigma Aldrich:75-03-6(sigmaaldrich)
- 用途三:用作化学试剂、医药用助渗剂(测定心血液输出量)。也用于有机合成和用作试剂。甲状腺肿治疗药,植物生长刺激素等。
- Acros Organics:Iodoethane, stabilized with silver, 99%(75-03-6)