CAS 111-83-1 MFCD00000276-1-Bromooctane 1-溴代正辛烷 TAO{mole}

1-Bromooctane 1-溴代正辛烷

CAS 111-83-1 MFCD00000276

化学结构图

SMILES: CCCCCCCCBr

化学属性

Mol. Formula	C8H17Br
Mol. Weight	193.12
Density	1.118
Refractive index	1.4520 to 1.4550
Vapor Density	6.7 (vs air)
Boiling Point	201 °C at 760 mmHg
Vapor Pressure	0.34 mmHg ( 25 °C)
Melting Point	-55 °C
Flash Point	92°C(lit.)
TSCA	Yes
Solubility	不溶于水，与乙醇、乙醚混溶。
Stability	对光敏感

别名和识别编码

Chemical Name	1-Bromooctane
MDL Number	MFCD00000276
CAS Number	111-83-1
EC Number	203-912-9
Beilstein Registry Number	1733136
Synonym	1-Bromooctane {LY} 1-Bromooctane {} {LY} 1-Bromooctane {} {} {LY} 1-Bromooctane {} {} {} {LY} 1-Bromooctane {} {} {} {} {LY} 1-Bromooctane {} {} {} {} {} {LY} 1-Bromooctane {} {} {} {} {} {} {LY} 1-Bromooctane {} {} {} {} {} {} {} {LY} 1-Bromooctane {} {} {} {} {} {} {} {} {LY} 1-Bromooctane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Bromooctane {} {} {} {} {} {} {} {} {} {} {LY} 1-Bromooctane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Bromooctane {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Bromooctane {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Bromooctane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Bromooctane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Bromooctane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-Bromooctane
PubChem Substance ID	8140
Merck Number	6764
Chemical Name Translation	1-溴代正辛烷
Reaxys-RN	1733136
Wiswesser Line Notation	E8
LabNetwork Molecule ID	LN00193622
InChI	InChI=1S/C8H17Br/c1-2-3-4-5-6-7-8-9/h2-8H2,1H3
Canonical SMILES	BrCCCCCCCC

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品牌质保精细包装现货库存一流品牌服务

产品应用

有机合成中间体。

安全信息

Signal word

GHS Symbol

WGK Germany3

Safety Statements

S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；

Risk Statements

R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
R50/53

Precautionary statements

P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P501 Dispose of contents/container to..… 处理内容物/容器.....
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P305+P351+P338
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
P332+P313
P302+P352+P332+P313+P362+P364
P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
P305+P351+P338+P337+P313
P273 Avoid release to the environment. 避免释放到环境中。
P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。

Hazard statements

H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
H227 Combustible liquid 可燃液体
H400 Verytoxictoaquaticlife 对水生生物毒性非常大。

Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

RTECSRG8575000

Packing GroupIII

UN Number UN3082

Hazard Codes

Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

Hazard Class9

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 8 mL/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-  Volume(issue)/page/year:
   30,470,1969

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 4490 uL/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-  Volume(issue)/page/year:
   30,470,1969

其他信息

可燃性危险特性:热分解排出有毒溴化物烟雾
检测方法:GC,MS
毒性分级:低毒
储运特性:库房通风低温干燥; 密闭存储
图谱信息:1-溴辛烷(111-83-1)红外图谱(IR1) 1-溴辛烷(111-83-1)核磁图( 1 HNMR) 1-溴辛烷(111-83-1)Raman光谱 1-溴辛烷(111-83-1)质谱(MS) 1-溴辛烷(111-83-1)核磁图( 13 CNMR)
MSDS 信息:1-Bromooctane(111-83-1).msds
Alfa Aesar:1-溴辛烷,98+% 1-Bromooctane, 98+%(111-83-1)
海关编码:29033036
Sigma Aldrich:111-83-1(sigmaaldrich)
蒸气压:0.34 mm Hg ( 25 °C)
用途一:主要用于有机合成
类别:自燃物质
1-溴辛烷价格(试剂级):更新日期产品编号产品名称包装价格 2011/08/23 30027926 1-溴代辛烷 100ml 112.3元 2011/04/16 B0626 1-溴辛烷 1-Bromooctane 500ML 328元 2011/04/16 B0626 1-溴辛烷 1-Bromooctane 25ML 124元
急性毒性:口服-大鼠 LD50: 5020 毫克/公斤
下游产品:2-已基十一酸 --> 3',4'-（二辛氧荃）苯甲醛 --> 4-辛基苯甲醛 --> 辛烷磺酸钠 --> 1-辛烷磺酸钠 --> 正-午基醚 --> 1-辛硫醇 --> 2-甲基苯硼酸
用途二:用于有机合成。菌毒清的中间体。 #EndEditable "Content"
不溶于水，和醇、醚混溶。
外观:无色透明液体。
上游原料:正辛醇 --> 菌毒清
Acros Organics:1-溴辛烷 1-Bromooctane, 99%(111-83-1)
MOL 文件:111-83-1.mol
用途三:1-溴辛烷是生产2,7-二溴-9,9-二辛基芴的原料药。
灭火剂:水,干粉、干砂、二氧化碳、泡沫、1211灭火剂
蒸气密度:6.7 (vs air)
常规方法:100ml玻璃瓶包装，外用木箱或纸箱保护。贮存于阴凉、干燥、通风的库房内。
方法一:由辛醇与氢溴酸反应而得。用硫酸将溴化钠完全溶解后，加入正辛醇，加热回流7-8h，冷后用水稀释，分出有机相，依次用水、浓硫酸，水、10%碳酸钠溶液洗涤，用无水硫酸钠干燥。蒸馏196-200℃，或91-93℃（2.93kPa）馏分，即为成品。产率90%以上。用途：用于有机合成。菌毒清的中间体。 #EndEditable "Content"
TCI Shanghai:1-溴辛烷 1-Bromooctane,>;98.0%(GC)(111-83-1)