Sodium chlorate 氯酸钠(易制爆)

CAS 7775-09-9 MFCD00003479

化学结构图

7775-09-9
SMILES: [Na+].[O-][Cl+2]([O-])[O-]

化学属性

Mol. FormulaClO3.Na
Mol. Weight106.44
Melting Point248-261 °C(lit.)
Density2.49
SolubilitySoluble in water.
TSCAYes

别名和识别编码

Chemical NameSodium chlorate
CAS Number7775-09-9
PubChem Substance ID516902
EC Number231-887-4
MDL NumberMFCD00003479
Merck Number14,8598
Synonym drexeldefol {uni_hamburg} Natriumchlorat Sodium chlorate 氯酸碱 氯酸曹达 b-herbatox CHLORATE ION chlorateofsoda Shed-A-leaf Leafex 2 氯酸鈉 Evau-Super Chloric acid, sodium salt Hibar C 落差,塌落 Tumbleaf Rasikal Shed-A-Leaf Natriumchloraat Agrosan Sodium chlorate (NaClO3) Desolet NaClO3 asex Chlorate salt of sodium dropleaf Chloricacid,sodiumsalt Atratol 白药钠,氯酸碱 dervan chloratesaltofsodium 氯化鈉(食鹽) B-Herbatox VAL-DROP 氯酸钠, 99% MIN atlacide 氯酸钠 Atlacide CHLORATE Soda chlorate SODIUM CHLORATE Sodium(chlorate de) Drexel defol defol Travex Kusa-tohru chlorsaure Asex chloratedesodium 氯酸碱,氯酸曹达,白药钠 Sodio (clorato di) Chloricacidsodiumsalt Grain sorghum harvest-aid 白药钠 evau-super Chlorate de sodium Oxycil Sodakem Granex O Harvest-aid Ortho C-1 defoliant & weed killer Chloric acid sodium salt desolet 氯酸鲁达 United Chemical Defoliant No. 1 CHLORATE IC STANDARD 氯酸钠, ACS, 99.0% MIN Kusatol STOCK SODIUM CHLORATE, 25G/L Evau-super 氯酸碱;氯酸曹达;白药钠
Chemical Name Translation氯酸钠(易制爆)
Wiswesser Line NotationNA G-O3
InChIInChI=1S/ClHO3.Na/c2-1(3)4;/h(H,2,3,4);/q;+1/p-1
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分类

  • {SNA} ACS Grade, Chemical Synthesis, Essential Chemicals, Inorganic Salts,
  • {SNA} Chemical Synthesis, Essential Chemicals, Inorganic Salts, Research Essentials, Salts, Sodium, Sodium Salts, Synthetic Reagents
  • Analytical Reagents, Analytical Reagents for General Use, Analytical Standards, Analytical/Chromatography, Chromatography, Environmental Standards, Herbicides, Inorganics, Pesticides & Metabolites, Puriss p.a., Q-S, Puriss p.a.
  • {SNA} Analytical Reagents for General Use, Analytical Standards, Essential Chemicals, Inorganics,
  • {SNA} Analytic

产品应用

  • A sulfation biosynthesis inhibitor.

相关文献及参考

  • Short: III/20a
  • Short: III/20b
  • Merck: 14,8598

安全信息

GHS Symbol
WGK Germany2
Hazard Codes O;Xn;N O,Xn,N
Hazard statements
  • H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
  • H302 Harmful if swallowed 吞食有害
  • H271 May cause fire or explosion; strong oxidizer 可能会引起火宅或爆炸;强氧化剂。
Personal Protective Equipment Eyeshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
RTECSFO0525000
Precautionary statements
  • P220 Keep/Store away from clothing/…/combustible materials. 保持远离/贮存远离服装/....../可燃材料。
  • P273 Avoid release to the environment. 避免释放到环境中。
Signal word Danger
Safety Statements
  • S46 If swallowed, seek medical advice immediately and show this container or label 食入时,立即求医并出示容器/标签;
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
  • S13 Keep away from food, drink and animal foodstuffs 远离食品、饮料和动物饲料保存;
  • S17 Keep away from combustible material 远离可燃物料;
UN Number UN1495 1495 UN 1495 5.1/PG 2
Risk Statements
  • R22 Harmful if swallowed 吞咽有害
  • R9 Explosive when mixed with combustible material 与易燃物混合会爆炸
  • R51/53
Packing GroupII
Storage condition 密封阴凉保存.本品与有机物、硫磺及易氧化物接触摩擦易引起煅烧。
Hazard Class5.1
Restrict 易制爆危险化学品
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Unreported
SPECIES OBSERVED        : Human - child
DOSE/DURATION           : 185 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GUCHAZ Guide to the Chemicals Used in Crop Protection.  (Information Canada,
   171 Slater St., Ottawa, Ont., Canada)  Volume(issue)/page/year: 6,461,1973

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 596 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   COREAF Comptes Rendus Hebdomadaires des Seances, Academie des Sciences.
   (Paris, France)  V.1-261, 1835-1965.  For publisher information, see CRASEV.
    Volume(issue)/page/year: 257,791,1963

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 8350 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   UZBZAZ Uzbekskii Biologicheskii Zhurnal.  Uzbek Biological Journal.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  No.1-    1958-
   Volume(issue)/page/year: (1),40,1986

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Mammal - dog
DOSE/DURATION           : 700 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   HBAMAK "Abdernalden's Handbuch der Biologischen Arbeitsmethoden." (Leipzig,
   Ger. Dem. Rep.)  Volume(issue)/page/year: 4,1289,1935

TYPE OF TEST            :

TYPE OF TEST            : LDLo - Lowest published lethal

TYPE OF TEST            : LD

TYPE OF TEST            : DNA inhibition
ROUTE OF EXPOSURE       : Oral
TEST SYSTEM             : Rodent - rat
DOSE/DURATION           : 84 mg/kg/12W (Continuous)
REFERENCE :
   JEPOEC Journal of Environmental Pathology, Toxicology and Oncology.
   (Chem-Orbital, POB 134, Park Forest, IL 60466)  V.5(4)-    1984-
   Volume(issue)/page/year: 6(1),105,1985

TYPE OF TEST            : Sex chromosome loss and nondisjunction
ROUTE OF EXPOSURE       : Oral
TEST SYSTEM             : Insect - Drosophila melanogaster
DOSE/DURATION           : 250 mmol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 90,91,1981

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 40 umol/plate
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 90,91,1981

Warnings 危化品目录(2015) 危险化学品

其他信息

  • 类别:氧化剂
  • 无气味。约300℃时释放出氧,较高温度全部分解。溶于约ml冷水、0.5ml沸水、约130ml乙醇、50ml沸乙醇、4ml甘油,水溶液呈中性,氯化钠能降低其水中溶解度。有强氧化性。与有机物或还原性物质摩擦或撞击能引起燃烧或爆炸。低毒,半数致死量(大鼠,经口)12000mg/kg。
  • 毒性:粉尘能刺激皮肤、黏膜和眼睛。如不慎氯酸钠溅人眼睛或溅到皮肤上,应立刻用大量水冲洗干净。吸入氯酸钠粉尘,因积累在体内而引起中毒,会出现恶心、大量呕吐、下泻、呼吸困难、肾损害等症状。误食时,要立即饮服食盐水或温肥皂水使其吐出,然后速送医院治疗。致死量为10g。 生产人员工作时应穿工作服,戴防护口罩、乳胶手套、塑料或橡皮围裙,穿长统胶靴等劳保用品,以保护呼吸器官和皮肤。生产设备要密闭,车间通风应良好。下班后要洗淋浴。
  • {Chem
  • 方法一:氯酸钠生产主要采用电解法,使用的电解槽主要有3种:石墨阳极电解槽现已淘汰;二氧化铅阳极电解槽和旧式金属阳极电解槽日趋淘汰;新型金属阳极电解槽正在被迅速推广。金属阳极电解槽又分为复极式电解槽和单极电解槽。 电解法将食盐加水于40~45℃下溶解,使其达到饱和,在精制槽中加入纯碱、烧碱、氯化钡以除去钙、镁和硫酸根等杂质,再送入调液器调酸并加入红矾钠,使盐水符合下列要求:NaCI≥280 g/L;Na2Cr2O72~3 g/L;Ca 2+ +Mg 2+ ≤1×10 -5 ;SO4 2+ <5 g/L。然后送去电解,通过化学反
  • 灭火剂:雾状水
  • 毒性分级:中毒
  • 外观性质:无色无臭结晶,味咸而凉,有潮解性。
  • 下游产品:二氧化锰 --> 氰化亚铜 --> 苯乙醇 --> 间苯氧基苯甲醛 --> 富马酸 --> 氨茴酸甲酯 --> N-氯代丁二酰亚胺 --> 糠酸 --> 次氯酸钙 --> 铂 --> 高氯酸 --> 乙基麦芽酚 --> 普鲁士兰 --> 二氧化氯 --> 亚氯酸钠 --> 5-叔丁基-2-甲基呋喃-3-碳酰氯 --> 还原深蓝BO --> 偶氮二甲酰胺 --> 氯化铜 --> 氧化苯乙烯 --> 硫化蓝CV --> 1,1-二甲基肼 --> 磺胺甲恶唑 --> 碘酸钙 --> 1-氯蒽醌 --> 高氯酸钾 --> 颜料绿 18 --> 还原黄4 --> 柠檬酸铁铵 --> N-叔丁基-2-苯并噻唑次磺酰胺 --> 虫胶 --> N,N-二异丙基-2-苯并噻唑次磺酰胺 --> 2-(4-吗啉基二硫代)苯并噻唑 --> 士林棕3GR --> 稳定性二氧化氯 --> 漂白淀粉 --> 氯化磷酸钠 --> 还原棕 3 --> 6-氯间甲酚 OR 3-甲基-6-氯苯酚
  • Sigma Aldrich:7775-09
  • 用途四:氧化剂。除草剂。
  • Alfa Aesar:氯酸钠,ACS,9
  • 常规方法:用内衬聚乙烯塑料袋的铁桶包装,桶口密封牢固,每桶净重50kg。包装上应有明显的“氧化剂”和“有毒品”标志。 属一级无机氧化剂,危规编号:21014。应贮存在阴凉、通风、干燥的库房内。注意防潮。严防粉末散落在地上,如有散落,必须立刻用湿黄砂拌和后扫干净。不得与糖类、油类、木炭等有机物、硫黄、赤磷、还原剂、硝酸盐、酸类(尤其是硫酸)和一切易燃物品共贮混运。运输过程中要防雨淋和日晒,注意防潮。装卸时要轻拿轻放,防止摩擦,严禁撞击。 失火时,先用砂土,再用雾状水和各种灭火器扑救,但不可用高压水。
  • 用途二:用于制造二氧化氯、亚氯酸钠及高氯酸盐,用作除草剂、印染氧化剂和媒染剂、纸浆漂白剂,还用于鞣革、烟火等
  • Alfa Aesar:氯酸钠,ACS,99.0%min Sodium chlorate, ACS, 99.0% min(7775-09-9)
  • 可燃性危险特性:遇有机物、还原剂、硫、磷等易燃物可燃; 燃烧产生有毒氯化物烟雾
  • Sigma Aldrich:7775-09-9(sigmaaldrich)
  • 刺激数据:皮肤- 兔子 500 毫克/ 24小时 轻度; 眼- 兔子 10 毫克 轻度
  • 水中溶解度(g/100ml):不同温度(℃)时每100毫升水中的溶解克数: 79.6g/0℃;87.6g/1

系列性分类