1,10-Phenanthroline 邻菲罗啉
CAS 66-71-7 MFCD00011678
化学结构图
SMILES: c1cnc2c(c1)ccc1cccnc12
化学属性
| Mol. Formula | C12H8N2 |
|---|---|
| Mol. Weight | 180.21 |
| Melting Point | 114-117 |
| TSCA | Yes |
| Boiling Point | >330° |
| Solubility | 溶于醇和丙酮。 |
| Flash Point | >330°C |
| Appearance | 一水物为白色结晶性粉末。熔点93-94℃，无水物熔点为117℃，溶于300份水，70份苯，溶于醇和丙酮。 |
| Stability | 对湿度敏感 |
别名和识别编码
| Chemical Name | 1,10-Phenanthroline |
|---|---|
| CAS Number | 66-71-7 |
| Alfabeta Name | PHENANTHROLINE 110-, |
| MDL Number | MFCD00011678 |
| Synonym | ORTHOPHENANTHROLINE 1,10-Phenanthroline Base, 38% 1,10 PHENANTHROLINE BASE 3 8% 无水 1,10邻二的氮杂菲, 99% 邻菲罗啉 o-Phenanthroline monohydrate Activ-8 in hexylene glycol 1,10-Phenanthroline anhydrous(o-phenanthroline, phenantholine) beta-Phenanthroline 邻菲罗啉, 1,10-菲罗啉 1,10-Fenanthrolin 1,10-菲咯啉 1,10-Phenanthroline amhydrous O-PHENANTHROLINE 1,10-邻二氮杂菲 1,10-PhenanthrolineAnhydrous97%Min 1,10-PHENANTHROLINE R. G., REAG. ACS, RE DOX INDICATOR 盐酸邻菲罗啉 无水 1,10邻二的氮杂菲 Solution forms containing 1,10-phenanthroline 菲羅琳 鄰啡啉 邻菲罗啉;邻啡啰啉;1,10-菲啰啉,邻二氮杂菲;2,9-二甲基啉菲罗啉;新铜试剂 邻菲咯啉 AKOS 92891 1,10-菲罗啉 1,10-Phenanthroline,97% 1,10-邻二氮杂菲(无水) Orthophenanthroline 1,10-菲啰啉 o-Phenanthroline 1,10-菲咯啉(无水) 1,10-PHENANTHROLINE 4,5-Diazaphenanthrene 1,10-Phenanthroline,anhydrous,99% 1,10-二氮杂菲 1,10-PHENANTHROLINE, 99+% 1,10-菲罗啉,盐酸盐 1,10-o-Phenanthroline 1,10-啡啉 4,5-Phenanthroline 1,10-菲罗啉/邻二氮杂菲 |
| EC Number | 200-629-2 |
| Merck Number | 7214 |
| Beilstein Registry Number | 126461 |
| PubChem Substance ID | 1318 |
| Chemical Name Translation | 邻菲罗啉 |
| InChIKey | DGEZNRSVGBDHLK-UHFFFAOYSA-N |
| Wiswesser Line Notation | T B666 CN NNJ |
| LabNetwork Molecule ID | LN00008170 |
| Reaxys-RN | 4008096 |
| InChI | InChI=1S/C12H8N2/c1-3-9-5-6-10-4-2-8-14-12(10)11(9)13-7-1/h1-8H |
信息真实价格透明
资金保障
专业采购外包团队在线服务
信息真实价格透明
资金保障
专业采购外包团队在线服务
品牌质保精细包装
现货库存
一流品牌服务
分类
- {SNA} Building Blocks, Chemical Synthesis, Heterocyclic Building Blocks, N-Containing, Others
- {SNA} Bioactive Small Molecules, Building Blocks, Cell Biology, Chemical Synthesis, Heterocyclic Building Blocks, N-Containing, Others, P
- {SNA} Building Blocks, Chemical Synthesis, Heterocyclic Building Blocks, N-Containing, Other Heterocyclic Building Blocks
- {SNA} Bioactive Small Molecules, Building Blocks, Chemical Synthesis, Heterocyclic Building Blocks, N-Containing, Others, P, 细胞生物学
产品应用
- 光谱测定金属和光谱分析CO2还原的常用配体。用于Cu(II)催化的有机硼酸的交联反应等等。
相关文献及参考
- [2]. Zi-Qiang Liu, et al. The role of matrix metalloprotease (MMP) to the autolysis of sea cucumber (Stichopus japonicus). J Sci Food Agric. 2019 Oct;99(13):5752-5759.
- For use as bidentate nitrogen ligands in Heck type reactions as an alternative to phosphine ligands, see: Synlett., 11, 871 (1992).
- Indicator for titration of organolithium reagents, giving red charge-transfer complexes, and also in the titration of Grignard reagents: J. Organomet. Chem., 9, 165 (1967); Org. Synth. Coll., 9, 350, 653, 733 (1998).
- Merck: 14,7214
- Merck: 14,7214 Beilstein: 23,227
- Reviews: 1,10-Phenanthroline: a versatile ligand: Chem. Soc. Rev., 23, 327 (1994); Coordination compounds as synthetic building blocks: Synlett, 1043 (2002).
- [1]. Guan NanMu, et al. Synergistic inhibition between o-phenanthroline and chloride ion on cold rolled steel corrosion in phosphoric acid. Materials Chemistry and Physics Volume 86, Issue 1, 15 July 2004, Pages 59-68.
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安全信息
GHS Symbol
- P301+P310+P330
- P301+P310
- P273 Avoid release to the environment. 避免释放到环境中。
- H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
- H301 Toxic if swallowed 吞食有毒
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intraperitoneal SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 75 mg/kg TOXIC EFFECTS : Kidney, Ureter, Bladder - other changes in urine composition Kidney, Ureter, Bladder - other changes REFERENCE : JPETAB Journal of Pharmacology and Experimental Therapeutics. (Williams & Wilkins Co., 428 E. Preston St., Baltimore, MD 21202) V.1- 1909/10- Volume(issue)/page/year: 196,478,1976
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intravenous SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 18 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : JPETAB Journal of Pharmacology and Experimental Therapeutics. (Williams & Wilkins Co., 428 E. Preston St., Baltimore, MD 21202) V.1- 1909/10- Volume(issue)/page/year: 137,1,1962
TYPE OF TEST : DNA inhibition
TEST SYSTEM : Human Leukocyte
DOSE/DURATION : 5 mg/L
REFERENCE :
ONCOBS Oncology. (S. Karger AG, Postfach CH-4009 Basel, Switzerland) V.21-
1967- Volume(issue)/page/year: 46,193,1989TYPE OF TEST : TDLo - Lowest published toxic dose ROUTE OF EXPOSURE : Intraperitoneal SPECIES OBSERVED : Rodent - mouse DOSE : 30 mg/kg SEX/DURATION : female 8 day(s) after conception TOXIC EFFECTS : Reproductive - Specific Developmental Abnormalities - musculoskeletal system REFERENCE : JPMSAE Journal of Pharmaceutical Sciences. (American Pharmaceutical Assoc., 2215 Constitution Ave., NW, Washington, DC 20037) V.50- 1961- Volume(issue)/page/year: 66,1755,1977
其他信息
- 用途一:电镀添加剂，分析试剂。
- 下游产品:1,10-邻二氮杂菲-5,6-二酮
- 图谱信息:1,10-菲罗啉(66-71-7)质谱(MS)
- Acros Organics:1,10-菲罗啉/邻二氮杂菲 1,10-Phenanthroline, 99+%(66-71-7)
- 1,10-菲罗啉价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 157530250 1,10-菲罗啉 1,10-Phenanthroline 99+% 25 GR 1095元 2010/06/21 157530050 1,10-菲罗啉 1,10-Phenanthroline 99+% 5 GR 329元 2010/06/21 157531000 1,10-菲罗啉 1,10-Phenanthroline 99+% 100 GR 3251元
- 方法一:将邻苯二胺与甘油、硝基苯及浓硫酸一起加热，或改用8-氨基喹啉为原料，都可制备该品。
- Alfa Aesar:无水1,10邻二的氮杂菲,99% 1,10-Phenanthroline, anhydrous, 99%(66-71-7)
- 溶于醇和丙酮。
- 海关编码:29339990
- 上游原料:1,2-苯二胺 --> 8-氨基喹啉
- 敏感性:Hygroscopic
- MOL 文件:66-71-7.mol
- MSDS 信息:o-Phenanthroline(66-71-7).msds
- 检测方法:HPLC,NMR
- Sigma Aldrich:66-71-7(sigmaaldrich)
