Diphenylphosphinic chloride 二苯基次膦酰氯

CAS 1499-21-4 MFCD00002077

化学结构图

1499-21-4
SMILES: O=P(Cl)(c1ccccc1)c1ccccc1

化学属性

Mol. FormulaC12H10ClOP
Mol. Weight236.63
Density1.24
Refractive indexn20/D 1.609(lit.)
Boiling Point222°C/16mmHg(lit.)
Flash Point26°C(lit.)
TSCANo
Melting Point20°C
Solubility分解
Stability对湿度敏感
Appearance 二苯基次膦酰氯(1499-21-4)为无色至浅黄色透明液体，沸点222℃，熔点 20℃，密度 1.24 ;g/mL ;at 25 ;°C，折光系数 n 20/D 1.609

别名和识别编码

Chemical NameDiphenylphosphinic chloride
Synonym Chlorodiphenylphosphine oxide {LY} Chlorodiphenylphosphine oxide DIPHENYLPHOSHINIC CHLORIDE DIPHENYLPHOSPHINYL CHLORIDE DPP-CL DPPC Diphenylchlorophosphine oxide Diphenylphosphinic acid chloride Diphenylphosphinoyl chloride Diphenylphosphinyl chloride Diphenylphosphorus oxychloride Ph2POCl 氯二苯基膦氧化物 Diphenylphosphinic Chloride PHOSPHINIC CHLORIDE, DIPHENYL- Ph2POCl diphenylphosphinous chloride {} {LY} Chlorodiphenylphosphine oxide {} {} {LY} Chlorodiphenylphosphine oxide {} {} {} {LY} Chlorodiphenylphosphine oxide {} {} {} {} {LY} Chlorodiphenylphosphine oxide {} {} {} {} {} {LY} Chlorodiphenylphosphine oxide {} {} {} {} {} {} {LY} Chlorodiphenylphosphine oxide {} {} {} {} {} {} {} {LY} Chlorodiphenylphosphine oxide {} {} {} {} {} {} {} {} {LY} Chlorodiphenylphosphine oxide {} {} {} {} {} {} {} {} {} {LY} Chlorodiphenylphosphine oxid
CAS Number1499-21-4
EC Number216-107-2
Beilstein Registry Number975191
MDL NumberMFCD00002077
PubChem Substance ID73910
Reaxys-RN975191
Chemical Name Translation二苯基次膦酰氯
LabNetwork Molecule IDLN00227216
InChIInChI=1S/C12H10ClOP/c13-15(14,11-7-3-1-4-8-11)12-9-5-2-6-10-12/h1-10H
Canonical SMILESO=P(C1=CC=CC=C1)(C2=CC=CC=C2)Cl
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分类

  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
  • {SNA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Phosphorus Compounds, Phosphorus Halides
  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Phosphine Compounds, Phosphorus Precursors

产品应用

  • 用于合成二齿配体，肽类偶联剂。

相关文献及参考

  • Beilstein:16(4)1038
  • Short: EINECS
  • Short: III/20b

安全信息

Signal word Danger
GHS Symbol
WGK Germany3
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
Risk Statements
  • R10 Flammable 易燃
  • R34 Causes burns 会导致灼伤
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P241+P242+P243
  • P242 Use only non-sparking tools. 只能使用无火花工具。
  • P243 Take precautionary measures against static discharge. 采取预防措施，防止静电放电。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331
  • P301+P330+P331+P310
  • P302+P361+P354
  • P303+P361+P353
  • P303+P361+P353+P310+P363
  • P304+P340
  • P304+P340+P310
  • P305+P351+P338
  • P305+P351+P338+P310
  • P305+P354+P338
  • P308+P313
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P316
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P370+P378
  • P403+P233
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Packing GroupII
UN Number 2920
Storage condition 2-8°C, stored under nitrogen {LY} 2-8°C, stored under nitrogen 4℃ Moisture Sensitive {} {LY} 2-8°C, stored under nitrogen {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Hazard Codes 8 C
Hazard Class8/3
Restrict 危险品

其他信息

  • Sigma Aldrich:1499-21-4(sigmaaldrich)
  • 遇水分解。
  • 海关编码:29310095
  • TCI Shanghai:二苯基次磷酰氯 Diphenylphosphinic Chloride,>;98.0%(T)(1499-21-4)
  • Hazard Note:Flammable/Corrosive
  • Alfa Aesar:二苯基膦酰氯,98% Diphenylphosphinic chloride, 98%(1499-21-4)
  • MOL 文件:1499-21-4.mol
  • 用途一:主要用于农药合成，用作阻燃剂等
  • 二苯基次膦酰氯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 C1415 二苯基次膦酰氯 Diphenylphosphinic Chloride 25G 1160元 2014/06/02 C1415 二苯基次膦酰氯 Diphenylphosphinic Chloride 10G 605元 2010/06/21 212960500 二苯基次膦酰氯 Diphenylphosphinyl chloride 98% 50 GR 2627元
  • F:10-21
  • MSDS 信息:Chlorodiphenylphosphine oxide(1499-21-4).msds
  • 敏感性:Moisture Sensitive
  • Acros Organics:二苯基氯氧膦 Diphenylphosphinyl chloride, 98%(1499-21-4)
  • 图谱信息:二苯基次膦酰氯(1499-21-4)质谱(MS) 二苯基次膦酰氯(1499-21-4)核磁图( 1 HNMR) 二苯基次膦酰氯(1499-21-4)红外图谱(IR1) 二苯基次膦酰氯(1499-21-4)核磁图( 13 CNMR)

系列性分类

  1. Life Science 生命科学
  2. Biochemicals and Reagents 生化试剂
  3. Peptides - Biochemicals and Reagents
  4. Peptide Synthesis 多肽合成
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Protection and Derivatization - Synthetic Reagents
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Phosphorus Compounds Catalysis 磷化合物催化剂
  4. Phosphine Ligands 膦配体
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Phosphorus Compounds Catalysis 磷化合物催化剂
  4. Phosphorus Precursors - Phosphorus Compounds
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Phosphorus Compounds Catalysis 磷化合物催化剂
  4. Phosphorus Precursors - Phosphorus Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Phosphorus Compounds 磷化合物
  5. Phosphorus Halides - Phosphorus Compounds
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Phosphorus Compounds
  4. Phosphite Ligands
  1. Life Science 生命科学
  2. Biochemistry / Glyco-Chemistry
  3. Peptide Synthesis
  1. Phosphine
  2. Phosphorus

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