1,10-Phenanthroline hydrate 1,10-菲咯啉水合物

CAS 5144-89-8 MFCD00149973

化学结构图

5144-89-8
SMILES: O.c1cnc2c(c1)ccc1cccnc12

化学属性

Mol. FormulaC12H10N2O
Mol. Weight198.22
Melting Point100-104°C
TSCAYes
Density1.1
SolubilitySoluble in water (3 mg/ml), ethanol (25 mg/ml), DMSO (100 mg/ml), acetone, and benzene (70 parts).
Stability对湿度敏感
Boiling Point365.1°C at 760 mmHg

别名和识别编码

Chemical Name1,10-Phenanthroline hydrate
Synonym o-Phenanthroline (monohydrate) {LY} o-Phenanthroline (monohydrate) {} {LY} o-Phenanthroline (monohydrate) {} {} {LY} o-Phenanthroline (monohydrate) {} {} {} {LY} o-Phenanthroline (monohydrate) {} {} {} {} {LY} o-Phenanthroline (monohydrate) {} {} {} {} {} {LY} o-Phenanthroline (monohydrate) {} {} {} {} {} {} {LY} o-Phenanthroline (monohydrate) {} {} {} {} {} {} {} {LY} o-Phenanthroline (monohydrate) {} {} {} {} {} {} {} {} {LY} o-Phenanthroline (monohydrate) {} {} {} {} {} {} {} {} {} {LY} o-Phenanthroline (monohydrate) {} {} {} {} {} {} {} {} {} {} {LY} o-Phenanthroline (monohydrate) {} {} {} {} {} {} {} {} {} {} {} {LY} o-Phenanthroline (monohydrate) {} {} {} {} {} {} {} {} {} {} {} {} {LY} o-Phenanthroline (monohydrate) {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} o-Phenanthroline (monohydrate) {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} o-Phenanthroline (monohydrate) {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
CAS Number5144-89-8
PubChem Substance ID21226
EC Number200-629-2
Beilstein Registry Number4008096
MDL NumberMFCD00149973
Merck Number7214
Chemical Name Translation1,10-菲咯啉水合物
Reaxys-RN4008096
LabNetwork Molecule IDLN00195517
InChIInChI=1S/C12H8N2.H2O/c1-3-9-5-6-10-4-2-8-14-12(10)11(9)13-7-1;/h1-8H;1H2
Canonical SMILESC12=C(N=CC=C3)C3=CC=C1C=CC=N2.O
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分类

  • {SNA} Analytical Reagents, Analytical/Chromatography, Indicators, Redox Indicators, Spectroscopy, Titration, UV/Vis Reagents, UV/Visible (UV/VIS) Spectroscopy
  • {SNA} A to C, Aminopeptidase N,
  • A to C, Aminopeptidase N, Bioactive Small Molecules, Biochemicals and Reagents,

产品应用

  • 光度分析测定铜,测定超微血糖。有机合成。
  • 氧化还原指示剂。亚铁试剂。生化研究。铂的萃取。重量法测定钯。掩蔽剂。比色测定二价铁、铂、钯等。
  • 与铜络合时,具有核酸酶活性,已被用于研究DNA-蛋白的相互作用

相关文献及参考

  • [2]. Zi-Qiang Liu, et al. The role of matrix metalloprotease (MMP) to the autolysis of sea cucumber (Stichopus japonicus). J Sci Food Agric. 2019 Oct;99(13):5752-5759.
  • , Beynon, R.J. and Bond, J.S., ed. Proteolytic Enzymes: A Practical Approach , (1989), 246
  • Chelating ligand for the determination of Fe, Pd and V.
  • Merck: 14,7214
  • Merck: 14,7214 Beilstein: 23,V,8,419
  • Redox indicator.
  • Santiago, T.C. et al., The relationship between mRNA stability and length in Saccharomyces cerevisiae . Nucleic Acids Res. 14 , 8347, (1986) 摘要
  • [1]. Guan NanMu, et al. Synergistic inhibition between o-phenanthroline and chloride ion on cold rolled steel corrosion in phosphoric acid. Materials Chemistry and Physics Volume 86
  • [1]. Guan NanMu, et al. Synergistic inhibition between o-phenanthroline and chloride ion on cold rolled steel corrosion in phosphoric acid. Materials Chemistry and Physics Volume 86, Issue 1, 15 July 2004, Pages 59-68.

安全信息

GHS Symbol
WGK Germany3
Hazard Codes 6.1 T,N
Hazard statements
  • H301 Toxic if swallowed 吞食有毒
  • H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
Personal Protective Equipment Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
RTECSSF8437000
Precautionary statements
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P301+P310
  • P301+P310+P330
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P330 Rinse mouth. 漱口
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Safety Statements
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
Packing GroupIII
UN Number 2811 UN 2811 6.1/PG 3
Risk Statements
  • R25 Toxic if swallowed 吞咽有毒
  • R50/53
Hazard Class6.1
Storage condition Store at room temperature, keep dry and cool {LY} Store at room temperature, keep dry and cool {} {LY} Store at room temperature, keep dry and cool {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store
TYPE OF TEST            : DNA inhibition
TEST SYSTEM             : Rodent - mouse Ascites tumor
DOSE/DURATION           : 5 umol/L
REFERENCE :
   CNREA8 Cancer Research. (Public Ledger Building, Suit 816, 6th & Chestnut
   Sts., Philadelphia, PA 19106)  V.1-    1941-  Volume(issue)/page/year:
   40,4092,1980

其他信息

  • 下游产品:4-乙烯基-1-环己烯二环氧化物,异构体混合物 --> 1,10-邻二氮杂菲-5,6-二酮
  • 用途一:用作氧化还原指示剂,测定亚钛铁的试剂
  • 邻菲啰啉价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 30141512 1,10-菲啰啉 5g 13.4元 2011/04/16 P1826 1,10-菲罗啉一水合物[用于生化研究] 1,10-Phenanthroline Monohydrate [for Biochemical Research] 5G 312元 2011/04/16 P0879 1,10-菲咯啉一水合物 1,10-Phenanthroline Monohydrate 25G 766元
  • Acros Organics:1,10-菲绕啉单水合物 1,10-Phenanthroline monohydrate, 99+%(5144-89-8)
  • Sigma Aldrich:5144-89-8(sigmaaldrich)
  • TCI Shanghai:1,10-邻二氮杂菲,一水合物 1,10-Phenanthroline Monohydrate,>;99.0%(T)(5144-89-8)
  • MSDS 信息:1,10-Phenanthroline hydrate(5144-89-8).msds
  • 海关编码:29339990
  • MOL 文件:5144-89-8.mol
  • Alfa Aesar:1,10-邻二氮杂菲一水合物ACS 1,10-Phenanthroline monohydrate, ACS(5144-89-8)
  • 1,10-菲罗啉(一水合物)价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 30141512 1,10-菲啰啉 5g 13.4元 2011/04/16 P1826 1,10-菲罗啉一水合物[用于生化研究] 1,10-Phenanthroline Monohydrate [for Biochemical Research] 5G 312元 2011/04/16 P0879 1,10-菲咯啉一水合物 1,10-Phenanthroline Monohydrate 25G 766元
  • 有刺激性。
  • 易溶于乙醇、正戊醇、异戊醇、正己醇、氯仿和苯,微溶于冷水。 有刺激性。

系列性分类


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