Glycidyl methacrylate 甲基丙烯酸缩水甘油酯

CAS 106-91-2 MFCD00005137

化学结构图

106-91-2
SMILES: C=C(C)C(=O)OCC1CO1

化学属性

Mol. FormulaC7H10O3
Mol. Weight142
Density1.042
Refractive index1.4470 to 1.4520
Boiling Point189 °C at 760 mmHg
Flash Point84°C(lit.)
TSCAYes
Melting Point-52 °C
Solubility0.5-1.0 G/100 ML AT 20 ºC
Appearance 无色液体。沸点189℃,相对密度1.073(25/4℃),折光率1.4494,闪点76℃。可溶于有机溶剂,不溶于水。
Stability对热敏感

别名和识别编码

Chemical NameGlycidyl methacrylate
CAS Number106-91-2
EC Number203-441-9
Beilstein Registry Number2506
MDL NumberMFCD00005137
Synonym Glycidyl methacrylate {LY} Glycidyl methacrylate {} {LY} Glycidyl methacrylate {} {} {LY} Glycidyl methacrylate {} {} {} {LY} Glycidyl methacrylate {} {} {} {} { {} {} {} {} {LY} Glycidyl methacrylate {} {} {} {} {} {LY} Glycidyl methacrylate {} {} {} {} {} {} {LY} Glycidyl methacrylate {} {} {} {} {} {} {} {LY} Glycidyl methacrylate {} {} {} {} {} {} {} {} {LY} Glycidyl methacrylate {} {} {} {} {} {} {} {} {} {LY} Glycidyl methacrylate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Glycidyl methacrylate {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {LY} Glycidyl methacrylate {} {} {} {} {} {} {} {} {} {} {} {} {LY} Glycidyl methacrylate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Glycidyl methacrylate {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Glycidyl methacrylate {} {} {} {} {} {} {} {} {}
PubChem Substance ID87572617
Chemical Name Translation甲基丙烯酸缩水甘油酯
Reaxys-RN2506
Wiswesser Line NotationT3OTJ B1OVY1&U1
LabNetwork Molecule IDLN00223762
InChIInChI=1S/C7H10O3/c1-5(2)7(8)10-4-6-3-9-6/h6H,1,3-4H2,2H3
Canonical SMILESCC(C(OCC1CO1)=O)=C
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分类

  • {SNA} Acrylic Monomers, Building Blocks, Chemical Synthesis, Epoxides, Materials Science, Methacrylate, Monomers, Organic Building Blocks, Oxygen Compounds, Polymer Science
  • {SNA} Acrylic Monomers, Building Blocks, Chemical Synthesis, Development

产品应用

  • 主要用于粉末涂料,也用于热固性涂料、纤维处理剂、粘合剂、抗静电剂、氯乙烯稳定剂、橡胶和树脂改性剂、离子交换树脂和印刷油墨的粘合剂。

相关文献及参考

  • Beilstein: 17,V,3,35

安全信息

Signal word Danger Warning
GHS Symbol
WGK Germany1
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后,立即用大量…(由生产厂家指定)冲洗;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S53 Avoid exposure - obtain special instructions before use 避免接触,使用前获得特别指示说明;
Risk Statements
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R34 Causes burns 会导致灼伤
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
  • R39/26 Very Toxic: danger of very serious irreversible effects through inhalation 剧毒:吸入会产生十分严重的不可逆危险
  • R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
  • R45 May cause cancer 可能致癌
  • R60 May impair fertility 可能降低生殖能力
  • R68 Possible risk of irreversible effects 可能有不可挽回的作用的危险
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前,切勿操作。
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331+P310
  • P303+P361+P353+P310+P363
  • P304+P340+P310
  • P305+P351+P338
  • P305+P351+P338+P310
  • P308+P311
  • P308+P313
  • P370+P378
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H311 Toxic in contact with skin 皮肤接触中毒
  • H350 May cause cancer 可能致癌
  • H341 Suspected of causing genetic defects 怀疑导致遗传性缺陷
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H360 May damage fertility or the unborn child 可能对生育能力或未出生婴儿造成伤害
  • H302+H332
  • H370 Causes damage to organs 导致器官损伤
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H302+H312+H332
  • H332 Harmful if inhaled 吸入有害
  • H302 Harmful if swallowed 吞食有害
  • H312 Harmful in contact with skin 皮肤接触有害
  • H227 Combustible liquid 可燃液体
RTECSOZ4375000
Packing GroupIII
UN Number 2922
Hazard Codes 6.1 8 T+ Xn Xn,T
Storage condition 2-8°C, stored under nitrogen {LY} 2-8°C, stored under nitrogen Refrigerator {} {LY} 2-8°C, stored under nitrogen {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored
Hazard Class8/6.1
TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1400 mg/m3/6H
TOXIC EFFECTS :
   Lungs, Thorax, or Respiration - other changes
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: OTS0530684

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 390 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 50(2),67,1985

TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 1400 mg/m3/6H
TOXIC EFFECTS :
   Lungs, Thorax, or Respiration - other changes
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: OTS0530684

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 597 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 50(2),67,1985

TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : In

TYPE OF TEST            : Mutation test systems - not otherwise specified
TEST SYSTEM             : Bacteria - Escherichia coli
DOSE/DURATION           : 300 umol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 231,205,1990

TYPE OF TEST            : Sister chromatid exchange
TEST SYSTEM             : Rodent - hamster Lung
DOSE/DURATION           : 78 umol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 249,55,1991

TYPE OF TEST            : Cytogenetic analysis
ROUTE OF EXPOSURE       : Intraperitoneal
TEST SYSTEM             : Rodent - rat
DOSE/DURATION           : 300 mg/kg
REFERENCE :
   BJPCAL British Journal of Pharmacology and Chemotherapy.  (London, UK)
   V.1-33, 1946-68.  For publisher information, see BJPCBM.
   Volume(issue)/page/year: 6,235,1951

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Klebsiella pneumoniae
DOSE/DURATION           : 200 umol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 89,269,1981

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 33 ug/plate
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 172,105,1986

其他信息

  • 方法一:由甲基丙烯酸钠与环氧氯丙烷反应而得。原料消耗定额:甲基丙烯酸780kg/t、环氧氯丙烷690kg/t、氢氧化钠330kg/t。
  • 甲基丙烯酸缩水甘油酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 K6416101 甲基丙烯酸缩水甘油酯 100ml 469元 2011/08/23 TM059001 甲基丙烯酸缩水甘油 500g 502元 2011/04/16 M0590 甲基丙烯酸缩水甘油酯(含稳定剂MEHQ) Glycidyl Methacrylate (stabilized with MEHQ) 25G 167元
  • Acros Organics:甲基丙烯酸缩水甘油酯 Glycidyl methacrylate, stabilized, 97%(106-91-2)
  • MSDS 信息:2,3-Epoxypropyl methacrylate(106-91-2).msds
  • 海关编码:29161490
  • 和大多数常规有机溶剂混溶,不溶于水。
  • TCI Shanghai:甲基丙烯酸缩水甘油酯(含稳定剂甲氧基氢醌) Glycidyl Methacrylate (stabilized with MEHQ),>;95.0%(GC)(106-91-2)
  • 上游原料:氢氧化钠 --> 环氧氯丙烷 --> 2-甲基丙烯酸 --> 甲基丙烯酸钠
  • 用途二:主要用于粉末涂料,也用于热固性涂料、纤维处理剂、粘合剂、抗静电剂、氯乙烯稳定剂、橡胶和树脂改性剂、离子交换树脂和印刷油墨的粘合剂。
  • Alfa Aesar:甲基丙烯酸缩水甘油酯,95%,与100ppm4-甲氧基苯酚稳定 Glycidyl methacrylate, 97%, stab. with 100ppm 4-methoxyphenol(106-91-2)
  • 图谱信息:甲基丙烯酸缩水甘油酯(106-91-2)红外图谱(IR2) 甲基丙烯酸缩水甘油酯(106-91-2)质谱(MS) 甲基丙烯酸缩水甘油酯(106-91-2)红外图谱(IR1) 甲基丙烯酸缩水甘油酯(106-91-2)核磁图( 13 CNMR) 甲基丙烯酸缩水甘油酯(106-91-2)Raman光谱
  • MOL 文件:106-91-2.mol
  • 用途一:主要用于丙烯酸粉末涂料、乳胶涂料、纺织皮革整理剂、胶粘剂、医药等
  • 下游产品:水溶性有机硅柔软剂
  • 单分散甲基丙烯酸环氧丙酯微球,具有粒径分布均一,纯度高的特点,亲水性强,环氧基基团丰富,方便进行表面化学修饰。可应用于显微学、细胞测量学、生物医学、过滤检测和流动原理研究等领域。
  • Sigma Aldrich:106-91-2(sigmaaldrich)

系列性分类


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