Hydrogen Bromide 溴化氢(易涉毒)

CAS 10035-10-6 MFCD00011323

化学结构图

10035-10-6
SMILES: Br

化学属性

Mol. FormulaHBr
Mol. Weight81
Density1.48
TSCAYes
Flash Point65°(149°F)
Vapor Density2.71 (20 °C, vs air)
Boiling Point126-128
Vapor Pressure334.7 psi ( 21 °C)
Melting Point-11
Solubility易溶于水、乙醇。
Stability对光敏感

别名和识别编码

Chemical NameHydrogen Bromide
Synonym Anhydrous hydrobromic acid Bromowodor Bromwasserstoff Bromwasserstoff (Gas) Bromwasserstoffsäure >= 40% Bromwasserstoffsäure <10% Bromwasserstoffsäure 10 - 40% Bromwasserstoffsäure 30% in Propionsäure Bromwasserstoffsäure 48% Bromwasserstoffsäure 62% Broomwaterstof HBr (hydrogen bromide) Hydrobromic acid Hydrogen bromide Hydrogen bromide (H2Br2) Hydrogen bromide (HBr) Hydrogen bromide, 30% solution in propionic acid hydrobromic acid <10% hydrobromic acid 10 - 40% hydrobromic acid 48% hydrobromic acid 62% hydrogen bromide 氢溴酸
CAS Number10035-10-6
PubChem Substance ID87570615
EC Number233-113-0
Beilstein Registry Number3587158
MDL NumberMFCD00011323
Reaxys-RN3587158
Merck Number4778
Chemical Name Translation溴化氢(易涉毒)
InChIKeyCPELXLSAUQHCOX-UHFFFAOYSA-N
Wiswesser Line NotationH E
LabNetwork Molecule IDLN00162855
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分类

  • {SNA} 48% aqueous HBr
  • {Chemicalbook} 无机化工产品: 无机盐: Cc溴化合物
  • {uni_hamburg} no charge; 1fragment
  • {SNA} Acids, Acids & Bases, Chemical Synthesis, Inorganic Acids, Specialty Gases, Synthetic Reagents

产品应用

  • 用作分析试剂。测定硫和硒,从砷和锑中分离锡,测定铋、锌和铁,烷化催化剂

相关文献及参考

  • Short: II/24C
  • Merck:14,4778
  • Short: II/24A

安全信息

GHS Symbol
WGK Germany1
Hazard Codes 8 C
Hazard statements
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H280 Contains gas under pressure; may explode if heated 内含高压气体,遇热可能爆炸。
  • H290 May be corrosive to metals 可能腐蚀金属。
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H331 Toxic if inhaled 吸入中毒
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P234 Keep only in original container. 只保留在原来的容器中。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241+P242+P243
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331+P310
  • P303+P361+P353+P310+P363
  • P304+P340+P310
  • P305+P351+P338
  • P305+P351+P338+P310
  • P308+P311
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P390 Absorb spillage to prevent material damage. 吸收溢出物,防止重大损害。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
RTECSMW3850000
Storage condition 0-10 Air Sensitive 避光、密封保存。 0-10°C
UN Number 1788 2920 2924
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S7/9 Keep container tightly closed and in a well-ventilated place 保持容器严格密闭,置于通风良好的场所;
Risk Statements
  • R34 Causes burns 会导致灼伤
  • R35 Causes severe burns 会导致严重灼伤
  • R37 Irritating to respiratory system 刺激呼吸道
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US) Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Packing GroupII
Warnings 危化品目录(2015)
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 76 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 41(1),105,1976

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 2858 ppm/1H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: PB214-270

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 814 ppm/1H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: PB214-270

Hazard Class8/3
Restrict 危险品

其他信息

  • 为溴化氢气体的水溶液,微发烟,对皮肤和眼有腐蚀作用,吸人体内有毒,在126ºC蒸馏液比重为1.49。露于空气及日光中因溴游离,色渐变暗,为强酸性,微发烟。易溶于氯苯、二乙氧基甲烷有机溶剂,能与水、醇 或乙酸混溶。溅于皮肤上发痒,甚致发炎

系列性分类


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