4-Cyanophenylboronic acid 4-氰基苯硼酸
CAS 126747-14-6 MFCD01318968
化学结构图
SMILES: N#Cc1ccc(B(O)O)cc1
化学属性
| Mol. Formula | C7H6BNO2 |
|---|---|
| Mol. Weight | 147 |
| Melting Point | >350 |
| TSCA | No |
| Density | 1.25 |
别名和识别编码
| Chemical Name | 4-Cyanophenylboronic acid |
|---|---|
| CAS Number | 126747-14-6 |
| Alfabeta Name | CYANOPHENYLBORONICACID 4- |
| MDL Number | MFCD01318968 |
| Synonym | (p-Cyanophenyl)boronic acid 4-Cyanobenzeneboronic acid 4-Cyanophenylboric acid 4-Boronobenzonitrile 4-Cyanobenzeneboronic Acid 4-Cyanobenzeneboronic Acid (contains varying amounts of Anhydride) 4-Cyanobenzeneboronic acid 4-Cyanophenylboric acid 4-氰基苯硼酸 |
| PubChem Substance ID | 87566735 |
| Reaxys-RN | 6593772 |
| Beilstein Registry Number | 6593772 |
| EC Number | 250-023-7 |
| Chemical Name Translation | 4-氰基苯硼酸 |
| LabNetwork Molecule ID | LN00005152 |
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分类
- {SNA} Aryl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Monosubstituted Aryl Boronic Acids, Organometallic Reagents
- Aryl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Monosubstituted Aryl Boronic Acids, Organometallic Reagents
产品应用
- 用于Suzuki-type交叉偶联反应。
相关文献及参考
- 1. K. Inamoto, et al., Chem. Commun. 47 , 11775-11777, (2011)
- 2. C. Zhang, et al., Chem. Commun. 47 , 9516-9518, (2011)
- 3. T. Matsuda, et al., Adv. Synth. Catal. 353 , 1923-1926, (2011)
- 4. Y. Ni, et al., Bioorg. Med. Chem. Lett. 21 , 5952-5956, (2011)
- 5. J. J. Matasi, et al., Bioorg. Med. Chem. Lett. 21 , 3805-3808, (2011)
- J. Med. Chem. 47 , 3658-3664, (2004) 摘要
- Tetrahedron Lett. 45 , 3233-3236, (2004)
- Tetrahedron Lett. 48 , 721, (2007)
- Sartori, G.; et al., Highly effective synthesis of C-5-substituted 2'-deoxyuridine using Suzuki-Miyaura cross-coupling in water Synthesis 5th ed., 44 , 767-772, (2012)
- Dastbaravardeh, N.; Schnuerch, M.; Mihovilovic, M. D. , Ruthenium(0)-Catalyzed sp3 C-H Bond Arylation of Benzylic Amines Using Arylboronates Org. Lett. 7th ed., 14 , 1930-1933, (2012) 摘要
- Zhang, J.; et al. , Ligand-free copper-catalyzed coupling of nitroarenes with arylboronic acids Green Chem. 4th ed., 14 , 912-916, (2012)
- Li, F-B.; et al. , Fullerenyl Boronic Esters: Ferric Perchlorate-Mediated Synthesis and Functionalization Org. Lett. 7th ed., 14 , 1800-1803, (2012) 摘要
- Chelliah, M. V.; et al. , Discovery of nor-seco himbacine analogs as thrombin receptor antagonists Bioorg. Med. Chem. 7th ed., 22 , 2544-2549, (2012)
- Cobo, I.; et al. , Phosphine-Free Suzuki-Miyaura Cross-Coupling in Aqueous Media Enables Access to 2-C-Aryl-Glycosides Org. Lett. 7th ed., 14 , 1728-1731, (2012) 摘要
- Daze, K. D.; et al. , Synthesis of New Trisulfonated Calix[4]arenes Functionalized at the Upper Rim, and Their Complexation with the Trimethyllysine Epigenetic Mark Org. Lett. 6th ed., 14 , 1512-1515, (2012) 摘要
安全信息
- H301+H311+H331
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛，皮肤或衣服。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P304+P340+P311
- P305+P351+P338
- P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
- P332+P313
- P337+P313
- P403+P233
- P405 Store locked up. 上锁保管。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- S22 Do not breathe dust 不要吸入粉尘；
- S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- R22 Harmful if swallowed 吞咽有害
GHS Symbol
